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RESEARCH PAPER · Chemical Reviews · 2025

Single Crystals of Vanadium Oxides as a Lens for Understanding Structural and Electronic Phase Transformations, Ion Transport, Chemo-Mechanical Coupling, and Electrothermal Neuronal Emulation

John D. Ponis, Shruti Hariyani, George Agbeworvi, S. Chakraborty, Victor H. Balcorta, James Pérez-Vázquez, Benjamin L. Rogers, Yu-Hsiang Chiang, A.M. Jessel, Timothy D. Brown, Richard Stanley Williams, Matt Pharr, Xiaofeng Qian, Sarbajit Banerjee

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Single Crystals of Vanadium Oxides as a Lens for Understanding Structural and Electronic Phase Transformations, Ion Transport, Chemo-Mechanical Coupling, and Electrothermal Neuronal EmulationOriginalImplications of crystallite dimensions on electrochemistry—mechanics coupling in metastable ζ-V 2 O 5 insertion electrodes1Alkali-Metal Interlocking of 2D V 4 O 10 Sheets Defines Discretized Interlayer Shear Relationships5Perovskite oxide catalysts: Molecular-level design, structure–activity relationships, and reaction mechanisms0An Atom-Precise Approach to Damp First-Order Phase Transitions and Its Implications for Neuromorphic Signal Processing1Multiband electronic structure and ultraviolet plasmonic response of layered Bm(CoAs)2 (Bm = K, Rb, Cs): A first-principles study of thermoelectric anisotropy1Chemo-Mechanics of α-V2O5 During Lithiation and Implications for Rechargeable Battery Cathodes1Modulating Mid-Gap Electronic States Through Site-Selective Modification in β-Pb x /β′-Cu y V 2 O 5 /CdS Heterostructures for Photocatalytic Hydrogen Evolution0Vanadium as a Blueprint for Critical Mineral Resilience0Intercalation of Ag ions into ammonium vanadate toward high-performance and long-lifespan aqueous zinc-ion battery cathodes0Deciphering oxygen-induced surface segregation of Pt3V alloy using ambient pressure XPS0A Synthetic Perspective of Strategies for Accessing Metastable Polymorphs: Lessons Learned from Hafnium(IV) Oxide0NiFe LDH-VO2/rGO/N-doped carbon heterostructure for a bifunctional electrocatalyst for alkaline water splitting applications3Na-Ion Interstitial Site Filling and Structural Evolution in a Tunnel-Structured Vanadium Oxide Insertion Host0

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  1. Implications of crystallite dimensions on electrochemistry—mechanics coupling in metastable ζ-V 2 O 5 insertion electrodes

    Journal of Materials Chemistry A · 2026-01-01

    Yu-Hsiang Chiang, Ireshika Wickramasuriya, Victor H. Balcorta, Kriti Choudhary, Harris E. Kohl, Anindya Pakhira, Grigory Yu. Smolentsev, Оlga V. Safonova, Maarten Nachtegaal, Mohammed Al‐Hashimi, Yuwei Zhang, Mario El Kazzi, Matt Pharr, Beth S. Guiton, Sarbajit Banerjee

    Read original paper ↗ ·

  2. Alkali-Metal Interlocking of 2D V 4 O 10 Sheets Defines Discretized Interlayer Shear Relationships

    Journal of the American Chemical Society · 2026-02-19

    John D. Ponis, Kenna Ashen, S. Chakraborty, George Agbeworvi, Michelle A. Smeaton, Chengdong Wang, A.M. Jessel, Douglas H. Fabini, Fanni Jurànyi, Diana Lucia Quintero-Castro, Nick A. Shepelin, Dariusz Jakub Gawryluk, Katherine Jungjohann, Shruti Hariyani, Xiaofeng Qian, Sarbajit Banerjee

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  3. Perovskite oxide catalysts: Molecular-level design, structure–activity relationships, and reaction mechanisms

    Molecular Catalysis · 2026-03-05

    M. Hjiri, Nazir Mustapha

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  4. An Atom-Precise Approach to Damp First-Order Phase Transitions and Its Implications for Neuromorphic Signal Processing

    Journal of the American Chemical Society · 2026-05-13

    George Agbeworvi, Nitin Kumar, John D. Ponis, Shruti Hariyani, Nicholas Jerla, Fatme Jardali, Jialu Li, Wasif Zaheer, Joseph V. Handy, Jaime R. Ayala, Cherno Jaye, Conan R. Weiland, Daniel A. Fischer, Patrick J. Shamberger, Jinghua Guo, R. Stanley Williams, G. Sambandamurthy, Sarbajit Banerjee

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  5. Multiband electronic structure and ultraviolet plasmonic response of layered Bm(CoAs)2 (Bm = K, Rb, Cs): A first-principles study of thermoelectric anisotropy

    Micro and Nanostructures · 2026-05-14

    Mohammed A. Jowhari, Sana Ullah Asif, Raed Hamed Althomali, Muhammad Tauqeer, Hussein Alrobei, Saja A. Althobaiti

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  6. Chemo-Mechanics of α-V2O5 During Lithiation and Implications for Rechargeable Battery Cathodes

    Experimental Mechanics · 2026-05-22

    Victor H. Balcorta, J. Ponis, R. Lee, D. A. Kang, C. C. Walker, Sarbajit Banerjee, M. Pharr

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  7. Modulating Mid-Gap Electronic States Through Site-Selective Modification in β-Pb x /β′-Cu y V 2 O 5 /CdS Heterostructures for Photocatalytic Hydrogen Evolution

    ACS Applied Materials & Interfaces · 2026-06-19

    Karoline E. García-Pedraza, Jaime R. Ayala, Alice R. Giem, Udani K. Wijethunga, Ashrumochan Gouda, Anindya Pakhira, Megan Minassian, Nicholas J. Reilly, George Agbeworvi, John D. Ponis, Michelle A. Smeaton, David F. Watson, Sarbajit Banerjee

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  8. Vanadium as a Blueprint for Critical Mineral Resilience

    ACS Energy Letters · 2026-06-24

    Benjamin L. Rogers, Sejal Sanjay Shanbhag, Leonardo Gobbato, Manish K. Dixit, Sarbajit Banerjee

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  9. Intercalation of Ag ions into ammonium vanadate toward high-performance and long-lifespan aqueous zinc-ion battery cathodes

    Research Square · 2026-07-03

    Yu Zhao, Xiu Wang, Yue Wang, Hongwei Wang

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  10. Deciphering oxygen-induced surface segregation of Pt3V alloy using ambient pressure XPS

    Applied Surface Science · 2026-07-17

    Minsik Seo, Moonjung Jung, Dongwoo Kim, Hojoon Lim, Hyunsuk Shin, Hervé Cruguel, Fabrice Bournel, Iradwikanari Waluyo, Adrian H. Hunt, Ki-jeong Kim, Jean‐Jacques Gallet, L. Dudy, Jeongjin Kim, Bongjin Simon Mun

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  11. A Synthetic Perspective of Strategies for Accessing Metastable Polymorphs: Lessons Learned from Hafnium(IV) Oxide

    ACS Materials Letters · 2026-08-04

    S. Chakraborty, James Pérez-Vázquez, Guan-Wen Liu, Sarbajit Banerjee

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  12. NiFe LDH-VO2/rGO/N-doped carbon heterostructure for a bifunctional electrocatalyst for alkaline water splitting applications

    Journal of Alloys and Compounds · 2026-08-04

    Aash Mohammad, Amit Kumar Gomey, Mohammad Kashif, Tae-Hwan Oh

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  13. Na-Ion Interstitial Site Filling and Structural Evolution in a Tunnel-Structured Vanadium Oxide Insertion Host

    ACS Materials Au · 2026-09-30

    James Pérez-Vázquez, S. Chakraborty, Yu-Hsiang Chiang, Aysan A. Yilmaz, Victor Alexander Gomez, Yuting Luo, Leonardo Gobbato, David A. Santos, Cade Alaniz, Denis V. Sheptyakov, Grigory Yu. Smolentsev, Оlga V. Safonova, Maarten Nachtegaal, Mohammed Al‐Hashimi, Sarbajit Banerjee, Diana Lucia Quintero-Castro, Dominika Baster

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