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RESEARCH PAPER · Laser & Photonics Review · 2025

Record Second‐Harmonic Generation in a Lead‐Free 2D Hybrid Halide Perovskite

Chang‐Chun Fan, Chengdong Liu, Jili Wu, Wei Qiang Wang, Yuhang Zhao, Chun‐Li Hu, Bingxuan Li, Bei‐Dou Liang

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Record Second‐Harmonic Generation in a Lead‐Free 2D Hybrid Halide PerovskiteOriginalSilver–bismuth perovskite-inspired materials: chemistry, optoelectronic properties, and emerging applications in photovoltaics and beyond17Stable 3D lead bromide hybrid ferroelectric semiconductor enabled by halogen-substitution-induced confinement effect2Alkyl chain length modulates coordination modes, phase transition behavior, and luminescence in Tb 3+ -based hybrid complexes0B′-site NH 4 + induces ferroelasticity in 2D rare-earth hybrid double perovskites0Epimeric cation stereocontrol enables tunable phase transition enthalpy and polar ferroelectric frameworks3High-temperature biferroicity in a chiral 3D hybrid rare-earth-based double perovskite1Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate6Polarity‐Gated Anti‐Thermal Luminescence in a Reentrant Luminescent Ferroelectric: (3,3‐difluoropyrrolidinium) 2 SbCl 5 with Dual Curie Points0Chiral Nonlinear Optical Response in Achiral Quasi‐2D Perovskite Ferroelectric Featuring Unusually Large A‐Site Cation8Chiral Nonlinear Optical Response in Achiral Quasi‐2D Perovskite Ferroelectric Featuring Unusually Large A‐Site Cation2Chiral Dion‐Jacobson Silver/Antimony‐Based Double Perovskite Ferroelectrics Enable Ultralow Dose n ‐Type X‐Ray Detection6Intralayer Hydrogen Bonds from Coordinated Water and X-ray Detection Performance in a Large-Sized 2D Rare-Earth Hybrid Perovskite Single crystal0

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  1. Silver–bismuth perovskite-inspired materials: chemistry, optoelectronic properties, and emerging applications in photovoltaics and beyond

    Journal of Materials Chemistry A · 2025-10-20

    G. Krishnamurthy Grandhi, Noolu Srinivasa Manikanta Viswanath, Marcello Righetto, Sara Domenici, Krishnaiah Mokurala, Marco Moroni, Adriana Pecoraro, Ana Belen Muñoz-García, Michele Pavone, Lorenzo Malavasi, Teresa Gatti, Paola Vivo

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  2. Stable 3D lead bromide hybrid ferroelectric semiconductor enabled by halogen-substitution-induced confinement effect

    Inorganic Chemistry Communications · 2025-10-30

    Chang‐Chun Fan, Wan-Ning Wang, Z. N. Gu, Jin Xu, Wei Qiang Wang, Chengdong Liu, Chao Yi Shi

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  3. Alkyl chain length modulates coordination modes, phase transition behavior, and luminescence in Tb 3+ -based hybrid complexes

    CrystEngComm · 2026-01-01

    Zheng-Hui Hu, Hong-Fei Zhao, Ze-Yu Jia, Ting Hai, Yi Wu, Yu‐Hui Tan, Chao Yi Shi

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  4. B′-site NH 4 + induces ferroelasticity in 2D rare-earth hybrid double perovskites

    Dalton Transactions · 2026-01-01

    Ting Hai, Zheng-Hui Hu, Yi Wu, Hongfei Zhao, Ze-Yu Jia, Chang‐Chun Fan, Chao Shi

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  5. Epimeric cation stereocontrol enables tunable phase transition enthalpy and polar ferroelectric frameworks

    Inorganic Chemistry Frontiers · 2026-01-01

    Zheng-Hui Hu, Chang‐Chun Fan, Hongfei Zhao, Ze-Yu Jia, Ting Hai, Yu‐Hui Tan, Dong-Lan Zhang, Chao Yi Shi

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  6. High-temperature biferroicity in a chiral 3D hybrid rare-earth-based double perovskite

    Inorganic Chemistry Frontiers · 2026-01-01

    Li-ping WANG, Chang‐Chun Fan, Zheng-Hui Hu, Hongfei Zhao, Jian‐Rong Li, Chao Shi

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  7. Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications

    Chemical Society Reviews · 2026-01-01

    Puxin Cheng, Yue Wang, Peihan Wang, Mingyang Xin, Dahui Hu, Mengyu Liu, Yongshen Zheng, Jialiang Xu

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  8. Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate

    Chemistry of Materials · 2026-01-20

    Lan Wang, Shu‐Fang Li, Jingjing Zhao, Xin-Ran Hao, Ru‐Ling Tang, Chu Chu, Bingbing Zhang, Dong Yan

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  9. Polarity‐Gated Anti‐Thermal Luminescence in a Reentrant Luminescent Ferroelectric: (3,3‐difluoropyrrolidinium) 2 SbCl 5 with Dual Curie Points

    Laser & Photonics Review · 2026-03-09

    Shulin Jiao, Zilong Zhou, Xiaolei Li, Peng Chen, Yilin Cao, Xicheng Zhang, Dianmeng Dong, Fan Zhang, Zhenping Wu, Hong‐Ling Cai, Xiaoshan Wu

    Read original paper ↗ ·

  10. Chiral Nonlinear Optical Response in Achiral Quasi‐2D Perovskite Ferroelectric Featuring Unusually Large A‐Site Cation

    Angewandte Chemie International Edition · 2026-03-15

    Chang‐Chun Fan, Shulin Jiao, Qiang-Qiang Bi, Jili Wu, Hai‐Luo Fu, Cheng‐Dong Liu, Guo‐Wei Du, Zhi‐Chao Huang‐Fu, Wei Wang

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  11. Chiral Nonlinear Optical Response in Achiral Quasi‐2D Perovskite Ferroelectric Featuring Unusually Large A‐Site Cation

    Angewandte Chemie · 2026-03-16

    Chang‐Chun Fan, Shulin Jiao, Qiang-Qiang Bi, Jili Wu, Hai‐Luo Fu, Cheng‐Dong Liu, Guo‐Wei Du, Zhi‐Chao Huang‐Fu, Wei Wang

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  12. Chiral Dion‐Jacobson Silver/Antimony‐Based Double Perovskite Ferroelectrics Enable Ultralow Dose n ‐Type X‐Ray Detection

    Advanced Functional Materials · 2026-05-27

    Chang‐Chun Fan, Zheng-Hui Hu, Jin Xu, Qiang-Qiang Bi, W Wang, Jia-Hang Wu, Cheng‐Dong Liu, W Wang, Chao Shi

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  13. Intralayer Hydrogen Bonds from Coordinated Water and X-ray Detection Performance in a Large-Sized 2D Rare-Earth Hybrid Perovskite Single crystal

    Inorganic Chemistry · 2026-08-20

    Hongfei Zhao, Zheng-Hui Hu, Dong-Lan Zhang, Ze-Yu Jia, Ting Hai, Jian‐Rong Li, Chang‐Chun Fan, Chao Yi Shi

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