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RESEARCH PAPER · Science China Materials · 2025

A strategy to achieve giant optical anisotropy via integrating linear pseudohalogen and stereochemical active lone pair cation

Xu Liu, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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A strategy to achieve giant optical anisotropy via integrating linear pseudohalogen and stereochemical active lone pair cationOriginalKTeOPO 4 and NH 4 SnClSO 4 : two new KTiOPO 4 derivatives as birefringent crystals featuring enhanced optical anisotropy0Minimizing Oscillator Strength: A Strategy for Engineering Deep-Ultraviolet Nonlinear Optical Crystals with Optimized Refractive-Index Dispersion0From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals4Giant optical anisotropy in the edge surfaces of layered crystals: unveiled by direct measurements of out-of-plane optical constants0Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. KTeOPO 4 and NH 4 SnClSO 4 : two new KTiOPO 4 derivatives as birefringent crystals featuring enhanced optical anisotropy

    Journal of Materials Chemistry C · 2026-01-01

    Ruo-Nan Zhang, Xuping Shi, Abudukadi Tudi, Wenbin Zhang, Zhihua Yang, Fangfang Zhang, Shilie Pan, Shujuan Han

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  2. Minimizing Oscillator Strength: A Strategy for Engineering Deep-Ultraviolet Nonlinear Optical Crystals with Optimized Refractive-Index Dispersion

    Chemistry of Materials · 2026-04-13

    Paipai Zhang, Fh Li, Wenhu Wang, Zhihua Yang

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  3. From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals

    Journal of the American Chemical Society · 2026-05-04

    Congcong Jin, Yang Li, Chong‐An Chen, Wei Zeng, S. D. Lee, Kang Min Ok

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  4. Giant optical anisotropy in the edge surfaces of layered crystals: unveiled by direct measurements of out-of-plane optical constants

    Science China Materials · 2026-07-07

    Jiao Dong, Xinhui Hao, Yimeng Shi, Dahuai Zheng, Wei Xin, Jian‐Guo Tian, X D Yan

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  5. Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation

    Chinese Chemical Letters · 2026-09-01

    Xiangyuan Li, Wei Liu, Xuehua Dong, Ling Huang, Liling Cao, Guohong Zou

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  6. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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