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RESEARCH PAPER · Progress in Materials Science · 2025

A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs

Xiaoyuan Shawn Chen, Xiaoyong Huang

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A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDsOriginalPhotoluminescence and energy transfer studies of Ce 3+ -sensitized BaF 2 :Tb 3+ :latent fingerprint detection and anti-counterfeit applications3Multisite occupancy, intense narrow band 5D0→7F2, and atypical 5D1→7F1 and 5D2→7F1 emission in NUV excited trigonal Sr3Ca3(PO4)4:Eu3+ phosphor7Single-phase white-emitting phosphors based on Eu2+-activated apatite-type Ba5(PO4)3Cl induced by (BO3)3− diadochic substitution3Novel garnet phosphor Tb3Ga5O12:Cr3+: High-efficiency near-infrared luminescence for near-infrared light source applications5Hybrid Carbon Quantum Dot/NaBiF4:Eu3+ Nanophosphors for White Light-Emitting Diode1Non‐Stoichiometric Strategy Induced Luminescence Improvement of the Cyan‐Emitting Phosphor Ca 3 Sc 2 Si 3 O 12 :Ce 3+ for WLED2Ba3EuGa2O7.5 red-emitting phosphor combining anti-thermal quenching with high efficiency for white light-emitting diodes and latent fingerprint1Eu3+- doped lead-free Cs2ZnCl4 perovskite for LED applications2Tunable color emission is achieved in Lu3Al5O12: Tb3+, Eu3+ phosphors for multimode anti-counterfeiting5Aqua Complexes of Rare Earth Metals (Ce3+, Eu3+, Gd3+, and Yb3+) with closo-Dodecaborate Anion: Synthesis, Structure, and Properties0For high-power laser lighting: Transparent YAG: Ce3+ phosphor-in-glass with high performance fabricated by low-temperature sintering7Blue-light-excited SrLu2Al2GaScSiO12:Ce3 + cyan-emitting garnet phosphor for high color rendering index full-spectrum WLEDs8Photoluminescence characteristics of Eu3+ and Tb3+ doped NaMg30SiO32 phosphor for WLED application0Eu3+ activated Sr3La2B4O12 phosphors: high colour purity red emission and thermal stability for solid-state lighting1Preparation and photoluminescence of high-monochromaticity green-emitting Ca9Tb(PO4)5(SiO4)F2:Ce3+ phosphor with high quantum efficiency and excellent thermal stability for WLEDs application1High-efficiency far-red emission from Eu3 + -doped CaGdGa3O7 phosphor: Photophysical properties and multifunctional applications1Efficient green emission via energy transfer in CaLuAlO4:Ce3+,Tb3+ phosphors for high-quality warm white lighting4Co-substitution of Zn 2+ /Ge 4+ in Er 3+ -activated garnet phosphors to enhance luminescence properties and optical thermometry0Decoupling luminescence kinetics in GAGG:Ce,Mg via defect engineering for ultrafast time resolution0Structural engineering of α-BaEuBO 3 F 2 borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor0Quantum cutting behavior in NaX(MoO4)2: Tb3+/Yb3+(X=Gd, Y) phosphors1Photoluminescence and Energy Transfer Analysis for Thermally Stable Dy3+/Tb3+-Doped Sr2ZnSi2O7 Phosphors1An efficient blue Ca3(Gd,Y)2B4O12:Ce3+ phosphor for near ultraviolet-excited white LEDs5Multifunctional Er(III)‐Activated Ca 2 SrWO 6 Double Perovskite for Ratiometric Thermometry and Lighting Devices0Unveiling the effect of Eu2+ and Ce3+ activation on the first rare-earth oxonitridolithosilicate LiGd2Si3N5O2: Crystal structure and luminescence properties0Photoluminescence properties of Sm3+-doped CaAl4O7-based phosphor-in-glass for high-power orange light applications4Harnessing multicolour photoluminescence from Dy3+/Tb3+/Eu3+ doped LaAlO3 for high-performance white LEDs and dye-sensitized solar cells6Ce3+-activated BaAlSi5N7O2: A novel cyan-emitting phosphor with superior thermal stability for full-visible-spectrum LED lighting2Phase-diagram-guided design of Ce3 + -Activated Sr–Lu–Ge–O phosphors with tunable broadband and white-light emission1A Novel Eu2+-Doped θ-Al2O3 Cyan-Emitting Phosphor for Bridging the Cyan Gap in High-Performance White Light-Emitting Diodes0Crystal‐Field‐Driven Modulation of Temperature‐Dependent Photophysics in Ce 3+ ‐Activated Transparent Ceramics1Development of a high-accuracy optical model of red phosphor and its application in improving the color rendering index of phosphor converted white laser lighting applications0Anomalous concentration anti-quenching of Eu3+ red luminescence based on novel rare-earth borate K7SrLu2B15O302Structure–luminescence correlation and Judd–Ofelt analysis of red-emitting TiO₂:Eu3⁺ nanostructures2Bi3+ and Eu2+ co-doped BaAl4Sb2O12 phosphor for excitation-dependent muti-color emission3Implications of the Stern-Volmer and Inokuti-Hirayama models on the luminescence quenching of Sm3+ doped silica-phosphate nanocomposite glasses for solid-state lighting1A tunable monophasic white light phosphor Ca8ZnIn(PO4)7: Eu2+, Dy3+ exhibits high stability and high-efficiency luminescence0Far-red emission garnet-type NaGd2Ga2InGe2O12:Eu3+ phosphors with 5D0→7F4 transition and thermal stability for plant-growth lighting and latent fingerprint visualization0Effects of Dy3+ ion concentration on the local structure and luminescence properties of Y4Al2O9:Tb3+ phosphors1Europium-activated silicate-based phosphors with enhanced far-red light emission for plant growth and WLEDs2Ultra-broadband visible ZnO:Mn phosphors: Photoluminescence properties and Warm-WLED applications0Ultra‐Bright Far‐Red Tribo‐Mechanoluminescent Composite Based on Work‐Function‐Mediated Charge Transfer and Dielectric Polarization for Human‐Machine Interfaces0Broadband‐Emitting NaGdSiO 4 :Eu 2+/3+ Phosphor for White Light‐Emitting Diodes0Synthesis of Red‐Emitting MgSrB 2 O 5 :Eu 3+ Phosphor for w‐LEDs and Beta Radiation Dosimetry0Broad-band sensitization and luminescence behavior in Bi3+ activated Eu3+-Er3+ co-doped Y2O3 phosphors1Modeling and design optimization of phosphor converted white light emitting diodes (pc-WLEDs)0Fabrication, morphology control and fluorescence properties of CaGdAl3O7:Tb3+ nanostructures with excellent green light emission via electrospinning0Synergistic role of oxygen vacancies and Ce4+/Ce3+ centers in SrCoO3-δ perovskites for advanced luminescent devices0Novel double perovskite Cs2Na0.7Ag0.3InCl6: Mn2+ for deep UV chip-based high color-rendering WLEDs0Color-tunable Ce3+/Tb3+ co-doped Sr5MgLa2(BO3)6 phosphor for high-quality WLEDs and non-contact optical thermometry0Spectroscopic investigation of Sr1−xCaxLiAl3N4:Eu2+ phosphor involving structural characterization, luminescence mechanism and potential LED applications0Synthesis and photoluminescent mechanisms of Ce3+-Activated KSr6ScSi4O16 blue-emitting phosphors for advanced solid-state lighting0A novel yellow-green garnet phosphor to narrow the cyan gap for high-color-rendering full-spectrum WLEDs0Structural characterization and photocatalytic activity of cerium-doped TiO2/Al2TiO5 heterostructure coatings synthesized by plasma electrolytic oxidation0Excitation‐Dependent Thermal Behavior of a New Type of Phosphors Ba 1‐x Sr 1+x Y 4 O 8 :Ce 3+0Heavy-element substitution simultaneously boosts comprehensive photoluminescence performance of Ce3+-activated garnets toward multifunctional optical applications0Luminescence of individual strontium vanadate nano-islands for white light0Dual-functional tetrakis Eu(III) aromatic carboxylate complexes for red emission and optical thermometry0Giant luminescence enhancement in Li2MSiO4:Eu2+ (M = Sr, Ba) via two-step synthesis and charge compensation0Unexpected Quenching in Luminescence With Smaller‐Ion Substitution: Structural and Phononic Insights Into a Trigonal Phosphor1Photoluminescence Properties of Sm 3+ ‐Activated Na 3 Ba 2 Ca(PO 4 ) 3 Orange‐Red Phosphor With High Color Purity for White LEDs0Solid Solution Engineering for Enhanced NIR Luminescence: Lattice Modulation and Performance Optimization0Tailoring the Ce³⁺ emission via crystal field engineering to achieve high thermal stability0Boosting luminescence efficiency via La3+-mediated crystal field engineering in thermostable Cs2CaBi2(PO4)2(P2O7):Tb3+ phosphors0Orange-red-emitting Sm3+-doped borate phosphors with high color purity and thermal stability for white LEDs0Photoluminescence properties of Tb3+- and Ce3+-doped Li6Ln(BO3)3 (Ln = Gd, Y) in the UV/VUV region0A Study on Correlation Between EPR-Derived Local Symmetry and Photoluminescence in Co-precipitated Sr2P2O7:Eu2+ Phosphors for Solid State Lighting0Cost-Effective β-SiAlON/Yb2+ Green Phosphors: From Synthesis to Characterization of Optical, Crystallographic, and Microstructural Properties0Optimizing the microstructure and luminescence of GdYAG:Ce: A study of the pH and annealing temperature cross-effect0Double Down-Shifting Films Including High-EQE Deep Red K0.5La0.5SrMgW0.7Te0.3O6:1.5%Mn4+, 3%Lu3+ Phosphor for Improving Silicon Solar Cell0The Anti‐Thermal Quenching Phosphor Landscape: Mechanisms, Materials, and Applications0Eu 3+ ‐Activated Ba 2 LaMoO 6 Red‐Emitting Phosphors for UVB/Blue‐Driven Solid‐State Lighting0Compositional tuning of thermally-induced charge transfer band edge red-shift triggering anomalous thermal quenching in Dy3+-doped niobate phosphors0Synthesis, luminescence properties, and thermal stability of novel Ca2GdTaO6:Sm3+ double-perovskite orange-red phosphors for near-UV-pumped white LEDs0Synthesis, structural, and optical characterization of Eu3+, Ce3+, and Dy3+ activated Ca0.6Li0.4Al0.6Si1.4N3 phosphors by microwave-assisted solution combustion synthesis for solid-state lighting applications0Differentiated thermal quenching behavior enabling high-performance FIR optical thermometry in Bi3+-Eu3+ garnet phosphors0Ce3+ sensitized Tb3+ delayed emission and short persistent luminescence in NaBa3Y3Si6O20 silicate phosphors for time-resolved anticounterfeiting0Effect of defect structure of YAG lattice on luminescent properties of Y3Al5O12:Ce nanoparticles prepared by co-precipitation synthesis0Dual-functional Tb3Al5O12:Ce3+/Mg2+ transparent ceramics enabled by tailored local distortion for X-ray tomography and magneto-optical applications0Low-temperature blade-coated CaAlSiN₃:Eu²⁺ phosphor-in-glass films on sapphire for thermally stable amber optoelectronic conversion0

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  17. Efficient green emission via energy transfer in CaLuAlO4:Ce3+,Tb3+ phosphors for high-quality warm white lighting

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  35. Bi3+ and Eu2+ co-doped BaAl4Sb2O12 phosphor for excitation-dependent muti-color emission

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  38. Far-red emission garnet-type NaGd2Ga2InGe2O12:Eu3+ phosphors with 5D0→7F4 transition and thermal stability for plant-growth lighting and latent fingerprint visualization

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  39. Effects of Dy3+ ion concentration on the local structure and luminescence properties of Y4Al2O9:Tb3+ phosphors

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  43. Broadband‐Emitting NaGdSiO 4 :Eu 2+/3+ Phosphor for White Light‐Emitting Diodes

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  44. Synthesis of Red‐Emitting MgSrB 2 O 5 :Eu 3+ Phosphor for w‐LEDs and Beta Radiation Dosimetry

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  45. Broad-band sensitization and luminescence behavior in Bi3+ activated Eu3+-Er3+ co-doped Y2O3 phosphors

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  46. Modeling and design optimization of phosphor converted white light emitting diodes (pc-WLEDs)

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  47. Fabrication, morphology control and fluorescence properties of CaGdAl3O7:Tb3+ nanostructures with excellent green light emission via electrospinning

    Journal of Luminescence · 2026-06-24

    Jinzhan Li, Beibei Yang, Zhendong Jiang, Jiajia He

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  48. Synergistic role of oxygen vacancies and Ce4+/Ce3+ centers in SrCoO3-δ perovskites for advanced luminescent devices

    Inorganic Chemistry Communications · 2026-06-24

    Sushri Sangita Nanda, Priyanka Nayak, Anirban Pradhan, Bijaylaxmi Biswal

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  49. Novel double perovskite Cs2Na0.7Ag0.3InCl6: Mn2+ for deep UV chip-based high color-rendering WLEDs

    Materials Today Chemistry · 2026-06-27

    Yan Xu, Pengjun Zhang, Shuwei Hao, Chongqiang Zhu, Chunhui Yang

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  50. Color-tunable Ce3+/Tb3+ co-doped Sr5MgLa2(BO3)6 phosphor for high-quality WLEDs and non-contact optical thermometry

    Ceramics International · 2026-07-01

    Ruting Tu, Jin Wei Zhao, Funi Liu, Yongcheng Fu, Yue Wang, Shangjun Wang, Rui Bian, Yiming Li, Nazi Zhong

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