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RESEARCH PAPER · EnergyChem · 2025

Rational design and interfacial engineering of hierarchical S-scheme heterojunction and their photocatalytic applications

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Rational design and interfacial engineering of hierarchical S-scheme heterojunction and their photocatalytic applicationsOriginalInterface-Defect Synergy in PCN/WS2-Vs Heterostructures for Enhanced Photoelectrochemical Hydrogen Evolution0Interface-Defect Synergy in PCN/WS2-Vs Heterostructures for Enhanced Photoelectrochemical Hydrogen Evolution0Recent advances in interface engineering of bismuth-based materials for photocatalytic CO 2 reduction6Construction of NH2-MIL-125/Na-doped g-C3N4 composite S-scheme heterojunction and its performance in photocatalytic hydrogen peroxide production12Self-integrated black NiO clusters with ZnIn2S4 microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism45Atomic-scale vacancy engineering in NiPS₃/CdS S-scheme heterojunction for efficient photocatalytic hydrogen production34Interfacial charge transfer in 2D/2D S-scheme Bi2MoO6/MoS2 heterojunction for enhanced photocatalytic antibiotic degradation8Efficient photocatalytic conversion H2S over NiS2/twinned-Mn0.5Cd0.5S Schottky/S-scheme homojunction in Na2S/Na2SO3 solution12External field induced piezo-photocatalytic hydrogen evolution for BiFeO3@CdS heterojunction14Facile preparation of g-C3N4/ZnO S-scheme heterojunction for photocatalysis: insights from the DFT studies and radical scavenging experiments7Size-induced H-adsorption self-optimization of Au cocatalysts for robust photocatalytic H2 production2MXene‐Mediated Internal Electric Field in WO 3 /AgBr Nanocomposites Enhances Visible‐Light‐Driven Peroxymonosulfate‐Activation and Dual‐Mode Antibacterial Performance5Engineered dual-interface MXene-integrated CoAlLa-LDH/TiO₂ ternary heterojunctions for highly selective photoreduction of CO₂ into renewable fuels7Rapid charge transfer endowed by van der Waals S-scheme heterojunction for boosting photocatalytic activity8Construction of S-scheme heterojunction with interfacial chemical bonds for enhanced photocatalytic CO2 reduction71BiVO4/SnS2 S-scheme heterojunction for improved photocatalytic performance under visible light: charge carrier mechanism validation by DFT and electrochemical studies7Interface-engineered S-scheme 2D/1D heterojunction of Cs0.32WO3/WO3·2H2O for boosted CO2 photoreduction: Synergistic charge separation and activation16Na2CO3-assisted synthesis of Na-doped crystalline/amorphous g-C3N4 S-scheme homojunction photocatalyst for enhanced H2O2 production41Photocatalytic peroxymonosulfate activation over S-scheme Co1−xS/g-C3N4 heterostructure toward high-efficiency polyethylene terephthalate degradation11Rational design of durable metal sulfide photocatalysts for pollutant degradation and solar fuel production: Challenges and outlook17A review of MOF/ZnIn2S4 heterojunction photocatalysts: mechanisms, fabrication, modification, and applications44Recent Progress in MXene‐Based Derivatives: “Positions and Functions of MXenes in Photocatalytic”16Hollow nanostructured photocatalysts for eliminating emerging wastewater pollutants1Interface-defect synergy in PCN/WS2-Vs heterostructures for enhanced photoelectrochemical hydrogen evolution1Activating interfacial polarization via snowflake-sphere dual-vacancy heterostructures for efficient S-scheme photocatalytic hydrogen evolution2Enhanced photocatalytic degradation of Congo red by a BiVO 4 /ZnIn 2 S 4 composite: performance and mechanism6Integrating the bicrystalline monoclinic-tetragonal BiVO4 with g-C3N4 to form S-scheme heterojunction for bromocresol green dye degradation under visible light2Nanostructures for photoelectrochemical biosensing0Sunlight-assisted activation of peroxymonosulfate using NiFe 2 O 4 supported on a 2D g-C 3 N 4 nanosheet heterojunction for the degradation of methylene blue in wastewater0Upcycling sediment wastes into S-scheme heterojunctions for efficient photocatalytic tetracycline degradation: Performance, DFT calculations and toxicity assessment10A Dual‐Piezoelectric Metal–Organic Cage/COF Z‐Scheme Heterojunction for Solar‐Mechanical Water Splitting4Neem (Azadirachta indica) leaf extract-based green route to reduced graphene oxide towards reduction of oximes into amines2Fe-N chemical bond bridging g-C3N4/Fe2O3 with 2D/1D sheet-across-rod configuration for efficient S-scheme photocatalytic removal of antibiotic5BiOBr/g-C3N4 heterojunction for aqueous-visible photocatalytic recovery of palladium from waste palladium/carbon catalyst1Theory-guided engineering of borophene-based S-scheme heterojunctions for accelerated photocatalytic hydrogen evolution2Hydrothermal assisted in-situ growth of faceted titania on Ti3C2 surface: Exploration of photocatalytic mechanism for the removal of HAMLA-550 insecticide2Sulfur vacancies boosting C2H4 selectivity of 2D/2D In2.77S4/CuInS2 S-scheme heterojunction for CO2 photoreduction2Interface engineering-mediated CdS/ZnIn2S4 Z-scheme heterojunction for efficient photocatalytic hydrogen evolution1Lotus-Shaped CuO/ZnO Nanocomposites with Tunable Band Gap for UVA-Induced Photocatalytic Degradation of Organic Dyes3Transition metal sulfide quantum dots modified recyclable Bi2WO6 nanoreactors for efficient photocatalysis0Design and preparation of 1D-based S-scheme photocatalysts20Triazine-based COF/TiO2 S-scheme heterojunction with oxygen vacancies for efficient photocatalytic CO2 reduction12ZnO-based S-scheme heterojunction: Design principles, preparation methods and photocatalytic activity16Covalent organic framework-based S-scheme photocatalysts: mechanistic insights and emerging applications in energy and environment7Broad-spectrum responsive S-scheme heterojunction photocatalysts6Recent advances in COF-based S-scheme photocatalyst7Tailoring a dual s-scheme carrier transfer pathway via a Zr-MOF-based ternary heterojunction WO3/In2S3/PCN-224 for boosted photocatalytic decontamination of Cr(VI) and reactive dyes0Defect-enhanced charge separation in ZnCdS/WS2 S-scheme heterojunctions: Engineering sulfur vacancies to facilitate photocatalytic H2 production0D-π conjugated S-type ZnO-polydopamine heterojunctions with enzymatic cascade amplification for enhanced photoelectrochemical immunoassay0Bismuth-based S-scheme heterojunctions for efficient photocatalytic energy conversion and application1Vacancy-Mediated Nanostructured ZnIn 2 S 4 /CdS S-Scheme Heterojunctions for Enhanced Photocatalytic Hydrogen Production2Interface-engineered hierarchical MXene-derived In2S3/TiO2/Ti3C2 heterostructure with an S-scheme dual charge-transfer pathway for efficient decontamination of structurally diverse waterborne antibiotics0Boosting Interfacial Charge Transfer in 0D/2D FeCoS 2 /ZnCdS Schottky Junction for Wide Spectrum Photocatalytic Hydrogen Evolution1Construction of metal-free 2D/2D PI/g-C3N4 heterojunction for enhanced photocatalytic degradation of tetracycline: interfacial engineering and charge separation1Dual-wavelength laser-driven TCH degradation over ZnO/cu₁.₃₅O/g-C₃N₄ S-scheme heterojunctions: Charge-transfer dynamics, mineralization, and phytotoxicity assessment0Deciphering charge–intermediate coupling in 2D/2D In2S3/g-C3N4 S-scheme heterojunction for efficient photocatalytic H2O2 evolution4Construction of a CuO/Cd-MOF p-n heterojunction with enhanced internal electric field for visible-light-driven imine synthesis0Sodium chloride-intercalated carbon nitride: One-step synthesis and enhanced photocatalytic hydrogen peroxide production0Internal electric field regulated S-scheme 2D/1D violet phosphorus nanosheet/ZnO nanorod heterojunction films on flexible substrates toward efficient antibiotic wastewater photodegradation1Metal sulfide-based step-scheme heterojunctions: Rational design, interfacial engineering, and photocatalytic applications0Dual role of oxygen vacancies in Mn0.3Cd0.7S/WO3−x S-scheme heterojunctions for strengthening internal electric field and extending light harvesting toward efficient H2 evolution0A novel 1D/3D hierarchical heterojunction Bi4V2O11/In2S3 with the reinforced photocatalytic activity toward tetracycline: the synergistic modulation of S-scheme charge migration and multidimensional configuration02D Ag modified g-C3N4/1D CdS-diethylenetriamine S-scheme heterojunction with enhanced photocatalytic H2O2 production0

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