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RESEARCH PAPER · Angewandte Chemie · 2025

Giant Birefringence and Solar‐Blind Ultraviolet Transmission by Coordination‐Induced Assembly of π‐Conjugated Pyridine–Carboxylate

Peng-Hui Guo, Xia Zhang, Yao Guo, Nan Zhang, Yi-Gang Chen, Xingxing Jiang, Zheshuai Lin, Xian‐Ming Zhang

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Giant Birefringence and Solar‐Blind Ultraviolet Transmission by Coordination‐Induced Assembly of π‐Conjugated Pyridine–CarboxylateOriginalHydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission0Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O0Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion6Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal2Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps1Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide0Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration0An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy0

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  1. Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission

    Advanced Optical Materials · 2025-12-10

    Zhenkai Cen, Z.-Y. Li, Guang Peng, Junbo Gong, Junbo Gong

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  2. Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O

    Dalton Transactions · 2026-01-01

    Zong-Jie Zhao, Yu-Zheng Yan, Jia-Jian Fu, Hongyan Wu, Jian‐Han Zhang

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  3. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

    Angewandte Chemie · 2026-01-05

    Meng‐Na Jing, Si‐Fan Lu, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  4. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  5. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  6. Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide

    Angewandte Chemie · 2026-05-26

    Yun‐Xia Hu, Huai Yu Wu, Jia‐jia Li, Ming‐Chang Wang, Jia‐Min Lian, Jin Yu Luo, Yiru Fu, Zi‐Yan Chen, Yang‐Hang Guo, Jin Chen, Ke‐Zhao Du

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  7. Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration

    Angewandte Chemie · 2026-09-11

    Ru‐Ling Tang, Bing-Wei Miao, Ling Wang, Zheng-Yu Yang, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo

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  8. An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy

    Energy & environment materials · 2026-09-15

    Xiliang Jiang, Hongyuan Sha, Xieming Xu, Chenrui Wang, Luying Zheng, Haotian Tian, Binwen Liu, Shuai‐Hua Wang, Guo‐Cong Guo

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