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RESEARCH PAPER · Journal of the American Chemical Society · 2025

Photoelectrochemical Tandem Chlorination of sp3 C–H Bond in Seawater/Chloroform Two-Phase Electrolyte System by Ti-Doped Fe2O3 Photoanode

Sang Youn Chae, Adeel Mehmood, Eun Duck Park

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Photoelectrochemical Tandem Chlorination of sp3 C–H Bond in Seawater/Chloroform Two-Phase Electrolyte System by Ti-Doped Fe2O3 PhotoanodeOriginalTwo-step coupled photoelectrochemical chlorination and oxygenation of C(sp 3 )–H bonds mediated by chlorine radicals over a modified BiVO 4 photoanode9Operando XAFS Reveals Dynamic Structural Evolution of Pt Single‐Atom Catalysts for Efficient Chlorine Electrosynthesis2Operando XAFS Reveals Dynamic Structural Evolution of Pt Single‐Atom Catalysts for Efficient Chlorine Electrosynthesis15Recent Progress on Photoelectrochemical Organic Upgrading: A Review from Direct and Indirect Charge Transfer Pathway10Accelerated charge transport of Ti and Zr co-doped Fe2O3 photoanodes by a super-hydrophilic metal-phytate coating for efficient photoelectrochemical water oxidation7Chlorine Radical‐Driven, Oxygen‐Independent Afterglow Nanoplatform for Tumor Microenvironment—Adaptive Imaging and Therapy5Chlorine Radical‐Driven, Oxygen‐Independent Afterglow Nanoplatform for Tumor Microenvironment—Adaptive Imaging and Therapy16Novel gallium oxynitride thin film photoanodes for photoelectrochemical water oxidation0Synergistically engineering bulk and surface charge transfer in Zn-doped BiVO 4 photoanodes with amorphous NiFeO x cocatalyst for efficient water oxidation1Dynamic Semiconductor Interface for Scalable Photoelectrochemical Synthesis of Chlorine Disinfectants from Natural Seawater0Dynamic Semiconductor Interface for Scalable Photoelectrochemical Synthesis of Chlorine Disinfectants from Natural Seawater18Synergistic Ti-doping and Co-MOF modification on α-Fe2O3 photoanodes for efficient and stable photoelectrochemical seawater splitting3Co-Catalytic Effect and Mechanism of Ni/Co Codoped Prussian Blue and Zr Doping on the Photoelectrochemical Water Splitting of α-Fe 2 O 34Photoelectrochemical Heterogeneous Catalysis: From Single Molecule Oxidation Toward C─X Bond Formation5Photoelectrochemical Heterogeneous Catalysis: From Single Molecule Oxidation Toward C─X Bond Formation3A comprehensive review on the mechanism, applicability and selection of chlorinating agents5In-situ (001) crystal plane derived C, N-FeNbO4 microrods on Ni foam for alkaline water/seawater oxidation0Field-channel synergistic engineering in gradient-doped 2D overlayers for high-efficiency solar water splitting0Hemin Molecular Catalyst with Axial Cl–Fe Coordination for Selective and Stable Acidic Chlorine Evolution2Photoelectrocatalytic seawater splitting for sustainable hydrogen production: Catalysts, challenges and future directions2Bias‐Free Photoelectrochemical Co‐Production of Active Chlorine and Hydrogen Peroxide From Seawater on a Pt‐WO 3 Interface0Photoelectrochemical oxidation of amines to imines coupled with H 2 production0Heteroanion-engineered asymmetric coordination breaking the activity-stability trade-off in amorphous NiCr2O4 for photoelectrochemical alkaline seawater oxidation1Recent Advances in Photoelectrochemical Synthesis of Value-added Chemicals0Mimicking Natural Photosynthesis: Bromide-Mediated Photocatalysis for Spatially Decoupled Olefin Epoxidation and Hydrogen Evolution0Co2+-doped spindle-like Fe2O3 derived from metal-organic framework: Enhanced energy storage for high-performance asymmetric supercapacitors1d-p orbital hybridization constructs Fe-S-Cu hole transport pathway in hematite photoanode for enhanced water oxidation0Application of Single-Atom Synergistic Catalysts in Multifield Coupling Reactions0Chloride‐Mediated Photoelectrochemical Selective Oxidation of Polyols Coupled With Hydrogen Evolution0Phase-Transition-Induced Co–Fe2O3 Nanosheets from Upcycling Spent LiFePO4 for Oxygen Evolution0

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  1. Two-step coupled photoelectrochemical chlorination and oxygenation of C(sp 3 )–H bonds mediated by chlorine radicals over a modified BiVO 4 photoanode

    Chemical Science · 2025-01-01

    Weijian Yang, Pengju Li, Yiming Han, Zijian Zhao, Limei Tian, Zhenghao Zhang, Mark Graeme Humphrey, Chi Zhang, Ke Hu

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  2. Operando XAFS Reveals Dynamic Structural Evolution of Pt Single‐Atom Catalysts for Efficient Chlorine Electrosynthesis

    Angewandte Chemie · 2025-08-25

    Qing Wang, Yun‐Bin Liao, Bingbao Mei, Jie Zhang, Daiki Kido, Weiren Cheng, Guangbo Chen, Tierui Zhang, Yitao Cao, Shun‐Li Li, Yong Yan, Ya‐Qian Lan

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  3. Operando XAFS Reveals Dynamic Structural Evolution of Pt Single‐Atom Catalysts for Efficient Chlorine Electrosynthesis

    Angewandte Chemie International Edition · 2025-08-25

    Qing Wang, Yun‐Bin Liao, Bingbao Mei, Jie Zhang, Daiki Kido, Weiren Cheng, Guangbo Chen, Tierui Zhang, Yitao Cao, Shun‐Li Li, Yong Yan, Ya‐Qian Lan

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  4. Recent Progress on Photoelectrochemical Organic Upgrading: A Review from Direct and Indirect Charge Transfer Pathway

    Advanced Energy Materials · 2025-09-21

    Cheng Lin, Yoonjun Cho, Kan Zhang, Jong Hyeok Park

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  5. Accelerated charge transport of Ti and Zr co-doped Fe2O3 photoanodes by a super-hydrophilic metal-phytate coating for efficient photoelectrochemical water oxidation

    Journal of Colloid and Interface Science · 2025-10-01

    Longjiang Jiang, Kaikai Ba, Yanhong Lin, Dejun Wang, Meng Cui, Tengfeng Xie

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  6. Chlorine Radical‐Driven, Oxygen‐Independent Afterglow Nanoplatform for Tumor Microenvironment—Adaptive Imaging and Therapy

    Angewandte Chemie · 2025-10-04

    Liang Gui Peng, Baoli Yin, Zhe Dong, Zhe Li, Xinlin Liu, Yong Tan, Hui Cao, Jinxue Xiang, Hanlin Wei, Dingyou Lu, Xiaobing Zhang, Guosheng Song

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  7. Chlorine Radical‐Driven, Oxygen‐Independent Afterglow Nanoplatform for Tumor Microenvironment—Adaptive Imaging and Therapy

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    Liang Gui Peng, Baoli Yin, Zhe Dong, Zhe Li, Xinlin Liu, Yong Tan, Hui Qun Cao, Jinxue Xiang, Hanlin Wei, Dingyou Lu, Xiaobing Zhang, Guosheng Song

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  8. Novel gallium oxynitride thin film photoanodes for photoelectrochemical water oxidation

    Applied Surface Science · 2025-12-11

    Sang Youn Chae, Jung Hun Maeng, Oh‐Shim Joo, Sungju Yu, Eun Duck Park

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  9. Synergistically engineering bulk and surface charge transfer in Zn-doped BiVO 4 photoanodes with amorphous NiFeO x cocatalyst for efficient water oxidation

    Journal of Materials Chemistry A · 2026-01-01

    Qiankun Deng, Yaying Li, Runsen Li, Bin Zhang, Jingsan Xu, Huilin Fan, Qi Xiao, Wei Luo

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  10. Dynamic Semiconductor Interface for Scalable Photoelectrochemical Synthesis of Chlorine Disinfectants from Natural Seawater

    Angewandte Chemie · 2026-01-04

    Zehua Gao, Rui‐Ting Gao, Limin Wu, Lei Wang

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  11. Dynamic Semiconductor Interface for Scalable Photoelectrochemical Synthesis of Chlorine Disinfectants from Natural Seawater

    Angewandte Chemie International Edition · 2026-01-04

    Zehua Gao, Rui‐Ting Gao, Limin Wu, Lei Wang

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  12. Synergistic Ti-doping and Co-MOF modification on α-Fe2O3 photoanodes for efficient and stable photoelectrochemical seawater splitting

    Journal of Alloys and Compounds · 2026-01-26

    Lindong Liu, Lindong Liu, Rufeng Tian, Haochen Xie, Yanmei Xue, Xingzhou Hou, Wanggang Zhang, Zonglin Yi, Jian Wang, Yiming Liu

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  13. Co-Catalytic Effect and Mechanism of Ni/Co Codoped Prussian Blue and Zr Doping on the Photoelectrochemical Water Splitting of α-Fe 2 O 3

    Inorganic Chemistry · 2026-02-11

    Yuan Guan, Zheng Shen, Chengye Huang, Shaomang Wang, zhongyu Li, Shicheng Yan, Zhigang Zou

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  14. Photoelectrochemical Heterogeneous Catalysis: From Single Molecule Oxidation Toward C─X Bond Formation

    Angewandte Chemie International Edition · 2026-02-22

    Jinghao Wang, Jian Li, Li‐Zhu Wu, Zhiyong Tang

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  15. Photoelectrochemical Heterogeneous Catalysis: From Single Molecule Oxidation Toward C─X Bond Formation

    Angewandte Chemie · 2026-02-25

    Jinghao Wang, Jian Li, Li‐Zhu Wu, Zhiyong Tang

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  16. A comprehensive review on the mechanism, applicability and selection of chlorinating agents

    Journal of environmental chemical engineering · 2026-03-03

    Dehao Dou, Huan Tian, Tu Hu, Baocheng Zhou, Guo Lin, Libo Zhang (641759), Jianwei Song, Junkui Shi, Yanfen Yang

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  17. In-situ (001) crystal plane derived C, N-FeNbO4 microrods on Ni foam for alkaline water/seawater oxidation

    Chemical Engineering Journal · 2026-03-12

    Hongliang Fu, Qiaowei Wang, Shaocong Zhan, Guanjie Xue, Yue Lian, Yongfeng Hu, Jing Zhao, Huaihao Zhang

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  18. Field-channel synergistic engineering in gradient-doped 2D overlayers for high-efficiency solar water splitting

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    Yang Cao, Xin Ding, Keng Chen, Hengjun Xie, Tongxin Tang, WenHao Zou, Huashu Sun, Shuang Xiao, Shanqing Zhang, Teng-Xiang Huang, Kai‐Hang Ye, Shihe Yang

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  19. Hemin Molecular Catalyst with Axial Cl–Fe Coordination for Selective and Stable Acidic Chlorine Evolution

    Inorganic Chemistry · 2026-04-13

    Mengjun Xiao, Yu Peng. Gui, Andraž Mavrič, Yao Nie, W. L. Zhang, Peng Chen, Pengpeng Wang, Yi Wang

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  20. Photoelectrocatalytic seawater splitting for sustainable hydrogen production: Catalysts, challenges and future directions

    MRS Energy & Sustainability · 2026-04-15

    Shi‐Tian Xiao, Touraj Karimpour, Si-Ming Wu, Sanjay Mathur, Xiao-Yu Yang

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  21. Bias‐Free Photoelectrochemical Co‐Production of Active Chlorine and Hydrogen Peroxide From Seawater on a Pt‐WO 3 Interface

    Advanced Sustainable Systems · 2026-05-01

    Lei Sun, Qiang Luo, Yating Wen, Yi Wang, Qiang Su, Yi Yang, Tao Liu, Ning Wang

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  22. Photoelectrochemical oxidation of amines to imines coupled with H 2 production

    AIChE Journal · 2026-05-08

    Wangsong Chen, Shanshan Zhang, Hongwu Chen, Jiangrong Yang, Nenghui Pan, Lan Luo, R K Li, Zhenhua Li, Mingfei Shao

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  23. Heteroanion-engineered asymmetric coordination breaking the activity-stability trade-off in amorphous NiCr2O4 for photoelectrochemical alkaline seawater oxidation

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    Xu Sun, Hongyu Zhao, Shibin Zhang, Yanxin Li, Hui Li, Bohua Dong, Chenghui Xia, Junjie Qin, Lixin Cao

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  24. Recent Advances in Photoelectrochemical Synthesis of Value-added Chemicals

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  25. Mimicking Natural Photosynthesis: Bromide-Mediated Photocatalysis for Spatially Decoupled Olefin Epoxidation and Hydrogen Evolution

    Journal of the American Chemical Society · 2026-06-29

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  26. Co2+-doped spindle-like Fe2O3 derived from metal-organic framework: Enhanced energy storage for high-performance asymmetric supercapacitors

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  27. d-p orbital hybridization constructs Fe-S-Cu hole transport pathway in hematite photoanode for enhanced water oxidation

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  28. Application of Single-Atom Synergistic Catalysts in Multifield Coupling Reactions

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  29. Chloride‐Mediated Photoelectrochemical Selective Oxidation of Polyols Coupled With Hydrogen Evolution

    Advanced Energy Materials · 2026-10-08

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  30. Phase-Transition-Induced Co–Fe2O3 Nanosheets from Upcycling Spent LiFePO4 for Oxygen Evolution

    Inorganic Chemistry · 2026-10-12

    Chang Wang, Liuyang Zha, Q Liu, Xiangkai Kong

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