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RESEARCH PAPER · Small · 2025

Improving the Performance of Birefringent Crystals by Molecular Assembly Strategy in the Solar‐Blind UV Region

Guangsheng Xu, Chenhui Hu, Huimin Li, Juanjuan Lu, Zhihua Yang, Jian Wei Han, Shilie Pan

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Improving the Performance of Birefringent Crystals by Molecular Assembly Strategy in the Solar‐Blind UV RegionOriginalStructural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning1A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5Triple Integration of π‐Conjugated Building Blocks: Unprecedented Assembly for Large Optical Anisotropy11Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence3A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O0Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups0Halide anion-mediated crystal structure engineering in guanidinoacetic acid halides for tunable birefringence0Suppressing antiparallel dipole alignment: A molecular engineering strategy toward sem-organic UV NLO crystals0Boosting Ultraviolet Phase‐Matching Performance of B 3 O 7 ‐Based Systems via Synergistic Fluorination and Organic Modification Strategy1Local Conformational Confinement and Dipole Engineering for Phase-Matchable Solar-Blind Ultraviolet Nonlinear Optical Crystals11Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps2Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps1NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications0

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  1. Structural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning

    Dalton Transactions · 2025-01-01

    Yunxiao Zhang, Guangsheng Xu, Ke Li, Wei Jia, Xiaoyu Dong

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  2. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-08-15

    Zhiyuan Zhang, Yabo Wu, Luyong Zhang, Xu Liu, Qiuyuan Feng, Lihan Deng, Jin Li, Shujuan Han

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  3. Triple Integration of π‐Conjugated Building Blocks: Unprecedented Assembly for Large Optical Anisotropy

    Small · 2025-10-07

    Ruyi Niu, Xiaona Li, Zhihua Yang, Juanjuan Lu, Xueling Hou, Shujuan Han, Shilie Pan, Miriding Mutailipu

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  4. Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence

    Crystal Growth & Design · 2025-12-25

    Han Bing Luo, Siyu Chen, Bailiang Li, Liling Cao, Xuehua Dong, Ling Huang, Guohong Zou

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  5. A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations

    Materials Chemistry Frontiers · 2026-01-01

    Zhi Fang, G Xu, Wenhu Wang, Huanhuan Wang, Jian Wei Han

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  6. Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O

    Dalton Transactions · 2026-01-01

    Zong-Jie Zhao, Yu-Zheng Yan, Jia-Jian Fu, Hongyan Wu, Jian‐Han Zhang

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  7. Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups

    Dalton Transactions · 2026-01-01

    Haowen Li, X Y Wang, Hui Chai, Fangfang Zhang

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  8. Halide anion-mediated crystal structure engineering in guanidinoacetic acid halides for tunable birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Wenjing Zhang, Yaozu Li, Chenyang Li, Wenjing Tan, Mingye Han, Bingbing Zhang, Ying Wang

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  9. Suppressing antiparallel dipole alignment: A molecular engineering strategy toward sem-organic UV NLO crystals

    The Innovation Materials · 2026-01-01

    Guangsheng Xu, Xue Bai, Zhihua Yang, Xueling Hou, Jian Han, Shilie Pan

    Read original paper ↗ ·

  10. Boosting Ultraviolet Phase‐Matching Performance of B 3 O 7 ‐Based Systems via Synergistic Fluorination and Organic Modification Strategy

    Advanced Optical Materials · 2026-04-01

    Xueli Du, Haoran Liu, Wenhu Wang, Haoran Wang, Xueyan Wu, Min Zhang

    Read original paper ↗ ·

  11. Local Conformational Confinement and Dipole Engineering for Phase-Matchable Solar-Blind Ultraviolet Nonlinear Optical Crystals

    Journal of the American Chemical Society · 2026-04-13

    Guangsheng Xu, Junwei Feng, Luyong Zhang, Zhihua Yang, Jian Wei Han, Shilie Pan

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  12. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie International Edition · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  13. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  14. NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications

    Advanced Optical Materials · 2026-04-25

    Juhui Cui, Feng Yu, Minqiang Gai

    Read original paper ↗ ·
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