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RESEARCH PAPER · ACS Catalysis · 2025

Unconventional Parahydrogen-Induced Hyperpolarization Effects in Chemistry and Catalysis: From Photoreactions to Enzymes

Andrey N. Pravdivtsev, Ben. J. Tickner, Stefan Glöggler, Jan‐Bernd Hövener, Gerd Buntkowsky, Simon B. Duckett, Clifford R. Bowers, Vladimir V. Zhivonitko

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Unconventional Parahydrogen-Induced Hyperpolarization Effects in Chemistry and Catalysis: From Photoreactions to EnzymesOriginalHighly active iron catalysts for olefin hydrogenation enable para -hydrogen induced hyperpolarisation of 1 H and 19 F NMR resonances at 1.4 Tesla2Photoswitchable, metal-free parahydrogen-induced polarization enabled by a phosphorus biradicaloid1Heteronuclear Parahydrogen‐Induced Hyperpolarization via Side Arm Hydrogenation7Revisiting the Spin–Lattice Relaxation of Homonuclear In-Phase and Antiphase NMR Magnetization0Upscaling the Hyperpolarization Sample Volume of an Automated Hydrogenative Parahydrogen-Induced Polarizer1Advances in Parahydrogen‐Induced Polarization for Nuclear Magnetic Resonance of Peptides, Proteins, and Biopolymers0Biocompatible SABRE Hyperpolarization of [1‐ 13 C]Ketoleucine for Cellular Metabolic Flux Sensing3Harnessing dynamic recognition for enhanced NMR-based detection5Pairwise hydrogenation of styrene catalyzed by Grubbs-type ruthenium catalysts: parahydrogen-induced polarization evidence and DFT mechanistic study0Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen1Hyperpolarization of Molecular Deuterium0Hyperpolarization of Molecular Deuterium0Why Fundamental Research Matters: Lessons from Nuclear Magnetic Resonance0Intermolecular Nuclear Spin Hyperpolarization Transfer via Cross‐Relaxation Triggers RASER of Solute Molecules0Intermolecular Nuclear Spin Hyperpolarization Transfer via Cross‐Relaxation Triggers RASER of Solute Molecules0Dynamic Mechanism Switching in Butene Isomerization on PdAu Nanocatalysts Revealed by Parahydrogen-Induced Polarization Nuclear Magnetic Resonance Spectroscopy0Hyperpolarization of Pyridine 15 N ‐Oxide Molecular Probes Enabled by Parahydrogen0Hyperpolarization of Pyridine 15 N ‐Oxide Molecular Probes Enabled by Parahydrogen0

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18 direct citing papers saved.

  1. Highly active iron catalysts for olefin hydrogenation enable para -hydrogen induced hyperpolarisation of 1 H and 19 F NMR resonances at 1.4 Tesla

    Chemical Communications · 2025-01-01

    Julianna S. Doll, Jan Kergassner, Bingyu Zhang, Christina Marie Thiele, Gerd Buntkowsky, Markus Enders, Torsten Gutmann, Dragoş‐Adrian Roşca

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  2. Photoswitchable, metal-free parahydrogen-induced polarization enabled by a phosphorus biradicaloid

    Physical Chemistry Chemical Physics · 2025-01-01

    Vladimir V. Zhivonitko, Karolina Konsewicz, Jonas Bresien, Axel Schulz

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  3. Heteronuclear Parahydrogen‐Induced Hyperpolarization via Side Arm Hydrogenation

    ChemPhysChem · 2025-04-11

    Oleg G. Salnikov, Nikita V. Chukanov, Andrey N. Pravdivtsev, Дудари Баировна Буруева, Sergey V. Sviyazov, Kolja Them, Jan‐Bernd Hövener, Igor V. Koptyug

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  4. Revisiting the Spin–Lattice Relaxation of Homonuclear In-Phase and Antiphase NMR Magnetization

    The Journal of Physical Chemistry A · 2025-09-23

    Lauren M. Kehoe, Zachary G. Mayes, Kelsey E. Brakensiek, Emma L. Ellis, Adam J. Alderfer, Lingyu Chi, Klaus Woelk

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  5. Upscaling the Hyperpolarization Sample Volume of an Automated Hydrogenative Parahydrogen-Induced Polarizer

    ACS Measurement Science Au · 2025-10-06

    Yenal Gökpek, Jan‐Bernd Hövener, Andrey N. Pravdivtsev

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  6. Advances in Parahydrogen‐Induced Polarization for Nuclear Magnetic Resonance of Peptides, Proteins, and Biopolymers

    ChemistryEurope · 2025-11-19

    Gerd Buntkowsky

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  7. Biocompatible SABRE Hyperpolarization of [1‐ 13 C]Ketoleucine for Cellular Metabolic Flux Sensing

    Chemistry - A European Journal · 2025-11-30

    Patrick M. TomHon, Joseph N. Gyesi, Abubakar Abdurraheem, Stephen J. McBride, Anna Samoilenko, Clementinah Oladun, Erica Curran, Megan Pike, Sydney D. Welch, Sydney Scofield, Boyd M. Goodson, Marianna Sadagurski, Thomas Theis, Eduard Y. Chekmenev

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  8. Harnessing dynamic recognition for enhanced NMR-based detection

    Coordination Chemistry Reviews · 2025-12-11

    Guangxing Gu, Zhenchuang Xu, Nijia Yu, Yanchuan Zhao

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  9. Pairwise hydrogenation of styrene catalyzed by Grubbs-type ruthenium catalysts: parahydrogen-induced polarization evidence and DFT mechanistic study

    Catalysis Science & Technology · 2026-01-01

    Heelim Chae, Md Al Mamunur Rashid, Hoonseok Kang, Sohyun Kwon, Dahun Ryu, Sungbong Kim4, Yonggoon Jeon, Eunsung Lee, Hye Jin Jeong, Keunhong Jeong

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  10. Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen

    Journal of the American Chemical Society · 2026-02-12

    Julius Frederik Matz, Lukas Kaltschnee, Sara Ida Mozzi, Gonzalo Gabriel Rodriguez, Anton Römer, Ricardo A. Mata, Ilya Kuprov, Franc Meyer, Stefan Glöggler

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  11. Hyperpolarization of Molecular Deuterium

    Angewandte Chemie International Edition · 2026-03-08

    Theresa L. K. Hune, Anakin Aden, Julius Frederik Matz, Denis Moll, Ilya Kuprov, Stefan Glöggler

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  12. Hyperpolarization of Molecular Deuterium

    Angewandte Chemie · 2026-03-09

    Theresa L. K. Hune, Anakin Aden, Julius Frederik Matz, Denis Moll, Ilya Kuprov, Stefan Glöggler

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  13. Why Fundamental Research Matters: Lessons from Nuclear Magnetic Resonance

    ACS Central Science · 2026-03-10

    Kirk S. Schanze

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  14. Intermolecular Nuclear Spin Hyperpolarization Transfer via Cross‐Relaxation Triggers RASER of Solute Molecules

    Angewandte Chemie International Edition · 2026-03-26

    Ivan A. Trofimov, Anna P. Yi, Oleg G. Salnikov, Andrey N. Pravdivtsev, Henri de Maissin, Eduard Y. Chekmenev, Jan‐Bernd Hövener, Andreas B. Schmidt, Igor V. Koptyug

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  15. Intermolecular Nuclear Spin Hyperpolarization Transfer via Cross‐Relaxation Triggers RASER of Solute Molecules

    Angewandte Chemie · 2026-03-27

    Ivan A. Trofimov, Anna P. Yi, Oleg G. Salnikov, Andrey N. Pravdivtsev, Henri de Maissin, Eduard Y. Chekmenev, Jan‐Bernd Hövener, Andreas B. Schmidt, Igor V. Koptyug

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  16. Dynamic Mechanism Switching in Butene Isomerization on PdAu Nanocatalysts Revealed by Parahydrogen-Induced Polarization Nuclear Magnetic Resonance Spectroscopy

    ACS Catalysis · 2026-05-28

    Weiyu Wang, Bintian Lu, Richard J. Lewis, Yueying Chu, Qiang Wang, Graham John Hutchings, J Q Xu, Feng Deng

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  17. Hyperpolarization of Pyridine 15 N ‐Oxide Molecular Probes Enabled by Parahydrogen

    Angewandte Chemie International Edition · 2026-07-09

    Ruhuai Mei, Lisa M. Fries, Gonzalo Gabriel Rodriguez, Charlotte von Petersdorff‐Campen, Leander Konstantin May, Julius Frederik Matz, Sergey E. Korchak, Grysette Daher, Stefan Glöggler

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  18. Hyperpolarization of Pyridine 15 N ‐Oxide Molecular Probes Enabled by Parahydrogen

    Angewandte Chemie · 2026-07-13

    Ruhuai Mei, Lisa M. Fries, Gonzalo Gabriel Rodriguez, Charlotte von Petersdorff‐Campen, Leander Konstantin May, Julius Frederik Matz, Sergey E. Korchak, Grysette Daher, Stefan Glöggler

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