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RESEARCH PAPER · Chemical Reviews · 2025

Perovskite Type ABO 3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects

Muhammad Humayun, Zhishan Li, Muhammad Q. Israr, Abbas Khan, Wei Luo, Chundong Wang, Zongping Shao

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Perovskite Type ABO 3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future ProspectsOriginalAdvances in perovskite-based photocatalysts: Mechanisms, materials design, and applications0Experimental and theoretical studies on bifunctional Fe and Nb co-doped SrCoO3- δ perovskite electrocatalyst for oxygen/hydrogen evolving electrocatalysis0Nio Nanoparticle-Modified Composite Cathode with Improved Electrochemical Oxygen Reduction Kinetics for Protonic Ceramic Fuel Cells0Perovskite oxides for electrocatalytic nitrogen/carbon fixation16Rare earth metal-based oxygen electrocatalysts: insights from mechanisms and designs to applications14Research Advances in the Application of Non-Nickel-Based Perovskite Materials for Biogas Reforming0Superheated steam-induced surface-accelerated amorphous-to-crystalline transition in an aluminosilicate inorganic polymer0Synergistic Electronic Descriptors for BaMO₃ (M=Sc to Zn) Perovskite ORR/OER Electrocatalysis: Decoding Bond Strength, Orbital Hybridization, and Electron Transfer Synergy0Low-iridium/ruthenium perovskite oxides: An emerging family of material platforms for oxygen evolution reaction in acid36Correlation of Structure and Electrocatalytic Performance of Bulk Oxides for Water Electrolysis5A polymer derived bubble templates strategy towards perovskite oxides with tunable pore structure and rich surface-active sites for boosting aerobic oxidation of benzyl alcohol3Microemulsion synthesis of Ce and Fe doped LaCrO3 perovskite nanoparticles for improved conductivity and photocatalytic performance18Improving Electrocatalytic Activity and Durability of Cobalt‐Free Bismuth Ferrite‐Based Perovskite Oxygen Electrode for Reversible Solid Oxide Cells12Unlocking the potential of MXenes in electrocatalysis: A review from fundamentals to applications14Novel materials based on Ruddlesden–Popper phases for solid oxide fuel cells and oxygen separation membranes: Fundamentals of oxygen transport10Recent advances in sol–gel synthesis of oxide perovskites for energy and functional applications: a mini review13Design of ZnO/CuO Nanocomposite Derived From Metal‐Organic Framework with High‐Performance Photocatalytic Activity3Carbon-dots-mediated flexible inverse opal perovskite film featuring structural robustness and highly selective photocatalytic CO 2 reduction7Ultrahigh-sensitivity PtNPs@CsCu2I3/AlGaN van der Waals heterojunction self-powered photodetector enabling precision solar-blind UV photometric quantification3A comprehensive review of high entropy oxides electrocatalysts: Advances, challenges, and prospects57Oxygen‐Driven Reconstruction Activates Quasi‐Single Pd Sites in Hollow PdAg Nanotubes for Zinc–Air and Fuel Cells2Fluoride anion Engineering as a strategy to improve vacancy formation and electrochemical stability in La0.6Sr0.4Fe0.8Ti0.2O3- cathodes for CO2 electrolysis2Facile hydrothermal synthesis of SrCoxFeyO3@CoFeOOH for boosted oxygen evolution reaction in alkaline electrolysis1Overcoming Acidic Challenges in Hematite Photoanodes: Charge Transport Engineering and Catalytic Interface Optimization15Joule Heating for Metal Oxide Electrocatalyst Fabrication: A Fast‐Track Strategy for Water Electrolysis22Multifunctional Screen-Printed Conductive Inks: Design Principles, Performance Challenges, and Application Horizons42An efficient and stable protonic ceramic fuel cell cathode achieved by Yb-doping0ASnO3 (A = Ca, Sr, Ba) perovskites as new and efficient photocatalytic reductants for Cr (VI) remediation: Role of vacancies, pH and D-fructose2Design of single atom coupled nitrogen doped graphene/molybdenum sulfide interface significantly improves water splitting property13Multifunctional copper organic framework barium titanate nanocomposite for synergistic photocatalytic, antibacterial, and hydrogen production applications5Strategies of modulating the microenvironment of catalytic sites for enhanced C–C coupling in photo–/electro–catalytic CO2 reduction21Amorphous/crystalline interface‐triggered electron redistribution on Rh(OH) 3 /NiMoO 4 for high‐efficient overall water and urea electrolysis at industrial current densities14Unveiling and boosting the catalytic activity of LaBO3 (B= Mn, Fe, Co, Ni) perovskites: d-p band center distance as a descriptor11Cerium-Doped Strontium Ferrate Perovskite Oxides: Sustainable Materials to Face Energy and Environmental Challenges3Nanoconfinement-engineered hollow perovskites boost non-radical pathways for efficient degradation of emerging contaminants2Hierarchical carbon electrocatalysts with atomic Co-N/Pyridinic-N synergy for efficient bifunctional oxygen reactions4Enhanced photocatalytic oxygen evolution performance of Ba3NF3: A first‑Principles DFT study of biaxial Strain–Tuned electronic and optical properties3Engineering SrTiO3 Nanostructures for Enhanced Photocatalytic Performance: Unveiling the Influence of Titanium Precursors and Synthesis Temperature8Delicately Tailoring Morphology of Silver Phosphate Crystals with High‐Gravity0Enhanced photoresponse and stability in graphene/silicon Schottky photodetectors modified with perovskite nanoparticles12Rising stars for sustainable future: Functionalized MXene and its heterostructure for CO2 photoreduction2UV-shielding and charge-transfer enhanced interface via amphoteric molecule for stable, high-efficiency solar cells0Ball Milling Approaches for Biomass‐Derived Nanocarbon in Advanced Sustainable Applications8Carbon materials in halide perovskite solar cells and photoelectrochemical water splitting3Design Rule for Highly Stable Efficient High‐Entropy Metal Oxide Electrocatalysts: Complementary Roles of 3d Transition Metal Ions5Data-Driven Perovskite Design via High-Throughput Simulation and Machine Learning10Frontiers in electrocatalytic water splitting: Mechanistic pathways, catalytic engineering, and kinetic challenges33Past, present, prospect: AI‐driven evolution of low‐dimensional material design for sustainable environmental solutions16Surface‐engineered perovskite oxides enabling dual activation of lattice and adsorbed oxygen for CO oxidation2Efficient overall water splitting electrode regulated by Pt nanodots modified NiCo-carbonate hydroxide nanowires on porous rGO matrix4Perovskite Anode-Based Gel Polymer Electrolytes for High-Performance Sodium-Ion Batteries: Design, Electrochemical Performance and Stability Analysis: A Review1CuFeS2 nanocrystals for sustainable photocatalysis: A comprehensive review1First-principles insights into band gap engineering and thermophysical properties of La-based perovskite oxides for solar-driven water splitting6Developing Oxygen Vacancy Rich Perovskite for Broad‐Spectrum‐Responsive Photothermal Assisted Photocatalytic Dehydrogenation of MgH 216DFT investigations on optoelectronic, mechanical, radiation shielding and magnetic insights in TMs-based perovskite oxides for energy applications1Mn-doped MgFeO3 for UV–visible optoelectronics: A combined experimental and DFT study2TiO2-mediated photoreforming of glycerol to formic acid in acetonitrile-free aqueous solutions: mechanism of crystal phase-regulated oxygen radicals influencing photoreforming4Hofmann-type MOFs derived small-sized Pt nanoparticles embedded in S, N codoped carbon matrix for enhanced oxygen reduction reaction0Optimizing water dissociation through doping fluorine into La2CuO4 to enhance multicarbon generation in CO2 electroreduction4High-entropy perovskites as new photocatalysts for cocatalyst-free water splitting25La3+-activated BaZrO3 nanophosphors: A promising blue-light emitting material for optoelectronic application2An active high-entropy air electrode for enhanced reversible solid oxide cell performance and stability6Engineering Spatially Adjacent Sites with Synergistic Spin Polarization Effect to Promote Sulfur Redox Kinetics in Lithium‐Sulfur Batteries3Perovskite materials for multifaceted energy applications: From fundamental properties to industrialization challenges4Lignocellulosic biomass conversion into CO and H2 via sunlight-enhanced lattice oxygen recycling in perovskite oxides2Synthesis of metal-supported SrFexZr1-xO3-δ catalysts: Study on the reaction mechanism of photo-Fenton synergistic catalytic degradation of m-cresol1Synergistic effect of perovskite LaNiO3 nanosphere/2D layered rGO for enhanced electrochemical evaluation of synthetic phenolic antioxidant detection in food additives3Doping effects on the structural and electrochemical properties of cathode materials for solid oxide fuel cells: a technical perspective10Alkaline earth Hafnate/carbon nanofiber hybrid composites for hydroxychloroquine sensing1Pivotal Role of A-Site Cation Intercalation in Reconstructed Perovskites for Enhanced Water Splitting6Recent advances of Zn3In2S6-based photocatalysts for photosynthesis, environmental and energy applications7Dual-heterojunction engineering in hierarchical Au-modified NiO/CeO2 core-shell nanofibers for enhanced photocatalytic degradation and antibacterial action2Perovskite Oxides for Electrosynthesis of Value‐Added Products by Gas‐Involving Cathodic Reduction Reactions11Hydrogen storage efficiency of pristine carbon allotropes1Laser-Based Crystallization of Chemical Solution Deposited Proton-Conducting Thin Films0Synthesis of Ni-doped perovskite LaFeO3 nanofibers and their gas-sensing performance for ethanolamine10Layered Perovskite Materials for Photocatalytic Overall Water Splitting: Recent Advances, Enhanced Strategies, and Future Challenges12A Review of Advanced Nanomaterials for Electrochemical Nitrate Reduction to Ammonia27High specific capacitance and stability of CuZrO3/PANI hybrid electrodes synthesized via Hydrothermal–Polymerization strategy3Rapid and sensitive electrochemical detection of paracetamol using EuZrO3-modified carbon paste electrode4Derived SmFeO3 nanoparticles exhibiting optical, magnetic, and ferroelectric coupling for multifunctional applications2Machine Learning Unveils Ce–O–Co Motifs in Perovskite with Lewis Acidic–Basic Microenvironment for Dual-Site Intramolecular Oxygen Evolution in Saline Water8Synergistic electronic descriptors for BaMO3 (M=Sc to Zn) perovskite ORR/OER electrocatalysis: Decoding bond strength, orbital hybridization, and electron transfer synergy5Recent advancements and future challenges of perovskite-based supercapacitors17Co-based bifunctional OER/ORR Electrocatalysts: From nanostructure engineering to catalytic mechanism innovation for cutting-edge research in empowering energy conversion systems45Rational Design of Metal–Organic Framework Hybrids via Metal and Ligand Engineering for Enhanced Oxygen Evolution Reaction Catalysis7Rational Electronic Regulation and Surface Reconstruction in Fe‐Doped La 0.5 Ba 0.5 CoO 3–δ Perovskite for High‐Current‐Density Hydrogen Evolution Reaction and Efficient Oxygen Evolution Reaction7High-entropy strategies transforming solid oxide cells: Progress and perspectives6Molten Salt‐Assisted Facet Control of Metal Compounds for Photocatalysis6The Anionically All‐Boron‐Based Anti‐ Perovskites Cs 3 [BH 4 ][B 12 H 12 ] and Cs 3 [BF 4 ][B 12 H 12 ]0K-promoted perovskite-derived iron-based catalysts for selective hydrogenation of CO2 to light olefins4Dual heterogeneous interface of CNT-SO3H/Eu/PbO2 electrode for highly efficient degradation of organic pollutants: Experimental and computational studies4First-principles investigation on optoelectronic, mechanical and thermoelectric properties of CaZrO3−xSex (x=0,1,2,3) perovskites0Structural, morphological, and functional characterization of LaMnO3 nanoparticles synthesized via the reverse micelle method1Strategic material engineering of BiFeO3-based piezo-photocatalysts for environmental and energy applications7Development of perovskite (MgZrO3) decorated polyaniline for supercapacitors0Strategic advances in perovskite oxide photocatalysts for efficient CO2 reduction: Challenges and future outlook11A novel perovskite aerogel catalyst boosting electron transfer-mediated reactive oxygen species generation in catalytic ozonation4Boosting the covalency of FeS via a built-in electric field in FeS/MnS heterojunctions for durable oxygen electrocatalysis in zinc-air batteries5First principles study of CsTiO3 for structural, electronic, mechanical, and optical properties with Zr and In doped for optoelectronic applications1La‐Doped Mullite Bi 2 Fe 4 O 9 Chemiresistive Gas Sensor for Ultra‐Highly Selective Detection of Ethylene Glycol9Modulating Metal‐Oxygen Bonds in BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3‐δ to Enhance Oxygen Adsorption and Proton Conduction for High‐Performance Protonic Ceramic Fuel Cell Air Electrodes1Conductive Cation Traps for Synthesizing Efficient and Stable Perovskite Catalysts4Optimized multifunctional TbCrO3/graphene oxide nanocomposites for synergistic photocatalytic dye degradation and electrocatalytic water splitting6Perovskite Oxide for Photoelectrochemical Water Splitting and Purification: Polarization Field Engineering2Robust FeCo alloy aerogels for industrial-grade water oxidation Electrocatalysis0A 24/7 perovskite catalyst through oxygen vacancy engineering for the rapid catalytic degradation of azo dyes under dark and ambient light conditions4A bifunctional S-scheme CuInS 2 /hollow porous tubular carbon nitride van der Waals heterojunction with a reinforced interfacial electric field for photocatalytic hydrogen evolution and antibiotic degradation0Advancements and prospects of perovskite materials for catalytic combustion of light alkanes1Concave-pore defective BiOCl applied to photodegradation of Rhodamine B: mechanism, degradation pathway and toxicity analysis2Constructing a P–N Homojunction in BiFeO₃ Thin Films via La Doping for Improved Photoelectrochemical Water Oxidation0Crafting double perovskites/hollow conjugated microporous polymer heterostructure for dual-channel H 2 O 2 production0Divergent A-site regulation mechanisms in rare-earth and alkaline-earth nickelates for unlocking bifunctional oxygen electrocatalysis1Effects of A-site alkaline earth doping on CO 2 adsorption and electrical conductivity in La 2 CuO 40Elucidating the O 2 reduction reaction on 2D monolayer LaMnO 3 perovskite1Enhancing the ORR activity of Fe-based perovskite cathodes for intermediate-temperature solid oxide fuel cells: alternative strategies and performance optimization3Enlarged transition metal-oxygen covalency and improved oxygen adsorption/dissociation in LaNi0.5- x Cu x Co0.5O3- δ perovskite oxides for electrocatalytic oxygen reduction reaction0Etching engineering for high-performance photocatalysts: from mechanistic insights to strategic design and practical applications0High-entropy-cooperated single-atom catalysis: an emerging paradigm bridging configurational complexity and atomic precision for catalytic applications5In situ synthesis of an S-scheme COF-5@CsPbBr 3 heterojunction for efficient photocatalytic CO 2 reduction3IndirecttoDirect Bandgap Transition in AgDoped BaTiO₃ Thin Films: Combined Experimental and DFT Insights1Lattice oxygen activation enabled by Fe doping in double perovskite oxides for efficient zinc–air batteries1Layered-to-cubic reconstruction and accelerated oxygen transport in A-site high-entropy perovskite cathodes for high-performance solid oxide fuel cells0Mechanism of molecular oxygen adsorption and desorption on the defective YCrO 3 (100) surface: a DFT study0Neodymium-based B-site high-entropy perovskite oxide nanoparticles as an efficient electrocatalyst for water splitting and methanol oxidation0Optimizing nickel and cobalt-based water oxidation electrocatalysts via iron post-modification1Oxygen-vacancy-enabled charge separation in distorted orthorhombic YFeO 36Perovskite oxides for electrochemical small-molecule oxidation: advances and mechanisms5Polyvinylpyrrolidone-Assisted Synthesis of Metal-organic Framework-Derived Hierarchically Porous Carbon for Bifunctional Electrocatalysis0Recent advances in spinel FeCo 2 O 4 nanomaterials: synthesis, structure–property relationships and multifunctional applications0Shining light on oxygen vacancies in SrTiO 3 for photocatalytic hydrogen production0Single-Atom La-Mediated Modulation of Interfacial Water Networks over Ni Single Atoms for Efficient Acidic CO2 Electroreduction to CO0Stoichiometry-Controlled Surface Reconstructions in Epitaxial ABO3 Perovskites for Sustainable Energy Applications2Strain effect on photocatalytic oxygen evolution activity in Sr 3 NF 3 mixed anion perovskite using first-principles density functional theory (DFT)2Synergistic effect of A-site deficiency and exsolved Fe particles in Sr 1− x FeO 3− δ cathodes for enhanced CO 2 electroreduction in solid oxide electrolysis cells2Temperature- and atmosphere-driven phase evolution in sol–gel synthesized barium nickelate powders0The Investigation of S-Scheme GdCrO3@ZnO Hetero-structured Composite for Enhanced Photocatalytic and Electrocatalytic Efficiencies0The Investigation of S-Scheme GdCrO3@ZnO Hetero-structured Composite for Enhanced Photocatalytic and Electrocatalytic Efficiencies0Ultrafast solution-processed Zr surface coating for stabilizing LSCF oxygen electrodes0Boosting the Solar Energy Conversion Efficiency of Photoelectrochemical Cells via p-BiFeO3/n-TiO2 Heterojunctions0Reconstructed Perovskite Layers Regulate Surface-Oxygen Dimerization States Enabling Reversible Anionic Redox in Li-Rich Layered Oxides6S-scheme Bi4TaO8Cl/g-C3N4 heterostructure accelerates photocatalytic CO2 reduction to CH3OH4Strategic vanadium-mediated ion exchange to introduce Al3+ effective doping in SrTiO3 for the enhancement of photocatalytic overall water splitting2Photo-enhanced reaction engineering for advanced lithium–sulfur batteries: From mechanisms and materials to system design7Tuning the electrocatalytic activity and durability of perovskite type La0.5Ba0.5CoO3-δ electrode by Pr doping1In situ reconstruction of perovskite oxides during electroreduction of nitrate to ammonia1Sustainable Ceramics: Materials for Energy, Environment and the Circular Economy0Synergistic Dual‐Site Modulation Enabling High‐Performance Cobalt‐Free Perovskite Cathodes for Intermediate‐Temperature Solid Oxide Fuel Cells1Simultaneous coating of benzotriazole and polyvinyl chloride on Cu for improved CO2 electroreduction toward C2 products9Effect of Atomic Layer Deposition of Ultra‐Thin Oxide on Reactivity and Durability of Perovskite Oxygen Electrodes2

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