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RESEARCH PAPER · Inorganic Chemistry · 2025

Second-Harmonic Generation in Organic–Inorganic Hybrid Cadmium Thiocyanates Containing Terminal Amino Acids

Yue Zhou, Gangji Yi, Qinglan Zhong, Guohong Zou, Hongmei Zeng, Zhien Lin

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Second-Harmonic Generation in Organic–Inorganic Hybrid Cadmium Thiocyanates Containing Terminal Amino AcidsOriginalFrom poor-active to high performance via heteroleptic tetrahedra engineering: rational design of non-π-conjugated hybrids for phase-matchable ultraviolet nonlinear optics12Phase-Matching Second-Harmonic Generation in Zero-Dimensional Zinc Thiocyanates Ligated with Chiral Amino Acids6Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals10NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1Cd-Based Coordination Frameworks with Multiple Optical Properties: Tunable RTP, Photochromism, and SHG Efficiency12Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes6Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response7Remarkable Disparity of Second Harmonic Generation Response in Two Inorganic–Organic Hybrid Metal Thiocyanates5Amino Acid Modification in One-Dimensional Cadmium Thiocyanates for Enhancing Second-Harmonic Generation Response2Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3Metal-Directed Structural Diversity of Lactate-Based Coordination Polymers: From Pillared-layer Framework to Multi-Helical Interpenetrating Networks0Multilevel Helical Cd-based Coordination Polymers with Significant Second NLO Response Constructed from Lactic Acid Derivatives0Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine1[CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics5Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate6Nonlinear Optical Responses in One-Dimensional Zinc Thiocyanates Functionalized with Natural Amino Acids8Enantiomeric Cd-based coordination polymers with multilevel helical structures and significant second NLO response constructed from lactic acid derivatives2From central chirality to helical chirality: two chiral coordination polymers based on a lactic acid derivative and their SHG responses2Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Helical Cd‐Based Frameworks Based on Lactic Acid Derivatives and Their Second‐Order Nonlinear Optical Responses0

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  1. From poor-active to high performance via heteroleptic tetrahedra engineering: rational design of non-π-conjugated hybrids for phase-matchable ultraviolet nonlinear optics

    Journal of Materials Chemistry C · 2025-01-01

    Mingchang Wang, Mo-Fan Zhuo, Zhi Rong Lin, Jiajia Li, Miao‐Bin Xu, Yunxia Hu, Jia-Min Lian, Ke‐Zhao Du, Jin Chen

    Read original paper ↗ ·

  2. Phase-Matching Second-Harmonic Generation in Zero-Dimensional Zinc Thiocyanates Ligated with Chiral Amino Acids

    Inorganic Chemistry · 2025-04-17

    Qinglan Zhong, Gangji Yi, Juan Cheng, Xin Wang, Guohong Zou, Ling Huang, Zhien Lin

    Read original paper ↗ ·

  3. Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals

    Advanced Optical Materials · 2025-04-29

    Ziqi Chen, Changyou Liu, Chenxu Li, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  4. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

    Read original paper ↗ ·

  5. Cd-Based Coordination Frameworks with Multiple Optical Properties: Tunable RTP, Photochromism, and SHG Efficiency

    Inorganic Chemistry · 2025-06-06

    Xu Jing, Tong Liu, Yu-Ying Xia, Siyi Li, Yanjie Li, Song‐De Han, Zhen‐Zhen Xue, Jie Pan

    Read original paper ↗ ·

  6. Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes

    Materials Today Chemistry · 2025-07-24

    Kang Yang, Duanliang Wang, Chuanrui Zhu, Kui Wu, Guangxia Liu, Jiyang Wang, Chuanying Shen

    Read original paper ↗ ·

  7. Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and Second-Harmonic-Generation Response

    Inorganic Chemistry · 2025-09-17

    Mingchang Wang, Jiajia Li, Yan Chen, Ke‐Zhao Du, Jin Chen

    Read original paper ↗ ·

  8. Remarkable Disparity of Second Harmonic Generation Response in Two Inorganic–Organic Hybrid Metal Thiocyanates

    Inorganic Chemistry · 2025-09-19

    Xuemei Wen, Yue Zhou, Qinglan Zhong, Jing Li, Guohong Zou, Zhien Lin

    Read original paper ↗ ·

  9. Amino Acid Modification in One-Dimensional Cadmium Thiocyanates for Enhancing Second-Harmonic Generation Response

    Inorganic Chemistry · 2025-12-22

    Xuemei Wen, Yue Zhou, Caihong Guo, Guohong Zou, Zhien Lin

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  10. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

    The Journal of Physical Chemistry Letters · 2025-12-26

    Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Mengjiao Xu, Chao He, Qi Wei, Guo-Ming Wang

    Read original paper ↗ ·

  11. Metal-Directed Structural Diversity of Lactate-Based Coordination Polymers: From Pillared-layer Framework to Multi-Helical Interpenetrating Networks

    SSRN Electronic Journal · 2026-01-01

    Zhong‐Xuan Xu, Hong-Yuan Qin, Xue-Ling Liang, Q Chen, Juan Yan, Jia‐Hui Luo

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  12. Multilevel Helical Cd-based Coordination Polymers with Significant Second NLO Response Constructed from Lactic Acid Derivatives

    SSRN Electronic Journal · 2026-01-01

    Zhong‐Xuan Xu, Xiao-Ling Wang, Yuan Lu, Jia-Tin Zhang, Qian-Qian Chen, Fei Fei

    Read original paper ↗ ·

  13. Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine

    CrystEngComm · 2026-01-01

    Juan Cheng, Yingjie Wang, Qinglan Zhong, Ziyu Zhou, Hongmei Zeng, Guohong Zou, Zhien Lin

    Read original paper ↗ ·

  14. [CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics

    Inorganic Chemistry · 2026-01-06

    Qingwen Zhu, Jie Gou, Yunjie Wang, Yaolong Zhu, Qi Wu

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  15. Zn 4 S(C 2 H 2 N 3 ) 3 (NCS) 3 : Coordination-Driven Structural Distortion Engineering Triggers Exceptional NLO Effect in Mixed-Bonding Zinc Isothiocyanate

    Chemistry of Materials · 2026-01-20

    Lan Wang, Shu‐Fang Li, Jingjing Zhao, Xin-Ran Hao, Ru‐Ling Tang, Chu Chu, Bingbing Zhang, Dong Yan

    Read original paper ↗ ·

  16. Nonlinear Optical Responses in One-Dimensional Zinc Thiocyanates Functionalized with Natural Amino Acids

    Inorganic Chemistry · 2026-02-05

    Xuemei Wen, Qinglan Zhong, Guohong Zou, Jing Li, Zhien Lin

    Read original paper ↗ ·

  17. Enantiomeric Cd-based coordination polymers with multilevel helical structures and significant second NLO response constructed from lactic acid derivatives

    Journal of Molecular Structure · 2026-04-12

    Zhong‐Xuan Xu, Xiao-Ling Wang, Yuan Lu, Jia-Tin Zhang, Qian-Qian Chen, Hong-Yuan Qin, Fei Fei

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  18. From central chirality to helical chirality: two chiral coordination polymers based on a lactic acid derivative and their SHG responses

    Acta Crystallographica Section C Structural Chemistry · 2026-06-03

    Qian-Qian Chen, Hong-Yuan Qin, Juan Yan, Xue-Ling Liang, Chun-Gang Chen, Zhong‐Xuan Xu, Xiu-Ju Yin

    Read original paper ↗ ·

  19. Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures

    Inorganic Chemistry · 2026-07-02

    Yiwen Xu, Juan Cheng, Gangji Yi, Yingjie Wang, Guohong Zou, Jintong Song, Zhien Lin

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  20. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie International Edition · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  21. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

    Read original paper ↗ ·

  22. Helical Cd‐Based Frameworks Based on Lactic Acid Derivatives and Their Second‐Order Nonlinear Optical Responses

    Zeitschrift für anorganische und allgemeine Chemie · 2026-09-22

    Xue-Ling Liang, Juan Yan, Q Chen, Hong-Yuan Qin, Xiao-Ling Wang, Zhong‐Xuan Xu

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