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RESEARCH PAPER · Dalton Transactions · 2025

Near-infrared luminescent materials: a review of their practical applications and prospective advancements

Shuaishuai Zhang, Shuohao Qin, Yuhao Xiao, Zhaoyi Liu, Xiaorui Hu, Zongliang Xiao, Decai Huang, Lei Han, Xinyu Ye

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Near-infrared luminescent materials: a review of their practical applications and prospective advancementsOriginalSubgrid cage confinement engineering enabled ultra-efficient near-infrared Cr 3+ –Ln 3+ co-doped phosphors8Highly efficient and thermal stable near-infrared-emitting glass ceramic by optimizing Na2SrXGe5O14: Cr3+ (X = Si, Ge, Ti) phosphors4Synthesis and Photoluminescent Properties of Dy3+-Doped and Dy3+/Eu3+ Co-Doped 50ZnO:40B2O3:5WO3:Nb2O5 Glass3Ionic substitution combined with flux doping triggered near-unity efficiency and thermally stable NIR luminescence in Al6Ge2O13: Cr3+, Si4+ phosphor for NIR spectroscopy applications6Wideband near-infrared luminescence in Al5BO9: Cr3+, Ga3+ phosphor for near-infrared spectroscopy application4Experimental study of the effectiveness of cutting out a skin-fat flap under the control of luminescent spectroscopy0Tunable Blue-to-Orange-Red Emission in LaPO4: Sb3＋/Mn2＋ Phosphors: Multiple emission centers for LED applications6Achieving near-unity efficiency and exceptional stability luminescence in Ca3Sc2Ge3O12: Cr3+, Si4+ phosphor through ion exchange and flux doping strategies for NIR spectroscopy applications2Engineering broadband near-infrared emission via the strategic assembly of Cr 3+ ion pairs in aluminum-based spinels41Optical tuning and dual luminescence behavior of MgGa2O4:Dy3+ for optoelectronic and dosimetric applications5Strong Emissions from Er/Tm/Yb Codoped Monoclinic YNbO 4 Single Crystals under 980 nm Excitations6Cr³⁺/Ni²⁺ codoped LiGaSiO4: A thermally stable broadband NIR-II phosphor for non-invasive spectroscopic sensing of organic and aqueous systems1Calcium Vacancy Generated Luminescence Improvement of the Ca 3 Sc 2 Si 3 O 12 :Ce 3+ Phosphor for WLED1Neutron‐Resolved Double Spinel Host Engineering for Ultra‐Broadband NIR Luminescence and Cr 3+ , Ni 2+ Energy Transfer13Strategies to achieve Mn5 + -activated highly efficient phosphor for near infrared-II LED light source2Infrared window properties of AB₂C₄ (A=Zn; B In, Ga; C Te, Se) materials via machine learning and density functional theory4Cr3+ sensitized thermal enhanced near-infrared emission in negative thermal expansion Sc2Mo3O12:Cr/Yb/Er phosphor12D Stranski–Krastanov growth of planar AuAg nano-dendrimers for enhanced visible-light plasmonic catalysis0Ca2+/Sn4+ pair and Ga3+ incorporation for thermodynamic stabilization and luminescence modification toward achieving broadband near-infrared emitting Gd3Al5O12-based garnet phosphor0Far Apart but Still Bright: the First Observation of Efficient Sensitizing the solid state NIR Luminescence of Yb3+ Ions via the Outer-Sphere Antennas0Luminescent coordination polymers based on [{Mo 6 I 8 }(CN) 6 ] 2− clusters and Ag( i ) complexes: structural design of bright red to NIR scintillating materials0NIR-responsive upconversion nanoplatforms: an anionic drug carrier for ROS amplification induced by β-amyloid fibrils2Triazolium analogues of tetraphenylethylene as AIEgens with tunable red-to-NIR emission: from fundamental understanding to bioimaging applications0Investigation on the fluorescence detection mechanism of NIR fluorescent probes based on intramolecular spiro cyclization0Synthesis, characterization and properties of a series of rare earth 3,5-dichlorobenzoate complexes including 4,4′-dimethyl-2,2′-bipyridine1Pt(II)-Cu(I) and Au(I)-Cu(I) complexes based on a bis(1,10-phenanthrolin-2-yl)phosphine: synthesis, near-IR luminescence and cytotoxic activity0Recent developments in near-infrared phosphors for broad-band light-emitting diodes light sources9Thermally reversible NIR-excited NIR emission of CaMoO4:Yb3 + phosphors for anti-counterfeiting security fibers0Synthesis and Structure of Heterometallic {Eu–M} (M = Na, K) Complexes with Monocarboxylic Acid Anions0A novel Cr3+ -activated Rb2KWO3F3 oxyfluoride phosphor with enhanced broadband near-infrared emission via energy transfer engineering0Structure and Luminescence Regulation in Y 3 Al 5 O 12 :Cr 3+ via Cation Substitution to Achieve Broadband Near-Infrared Emitting Garnet Phosphor6NIRGB‐GS: Near‐Infrared Assisted Low‐Light Scene Reconstruction and Enhancement via Gaussian Splatting0Unraveling the Lattice Dynamics and Inherent Emission of NaGdMgTeO 6 Double Perovskite Phosphor1La 3+ Vacancy Mediated Enhancement of Near‐Infrared Emission in Cr 3+ ‐Activated La 2 MgTiO 6 Phosphors for Multifunctional Applications2Thermodynamic Stabilization and Cr 3+ Luminescence Tuning in Gd 3 Al 5 O 12 Garnet Phosphor via Multi‐Cation Incorporation4Small-molecule near-infrared fluorescent probes for peroxynitrite: Design, mechanisms, and bioimaging applications1Near-infrared emitting MgGa2O4:Fe3+, Li+ phosphors for level III fingerprint imaging and anti-counterfeiting applications0Mn4+ and Fe3+ co-doped near-infrared dual-emission ratio thermometry for biosensing applications1Nonstoichiometric Strategy for Enhancing Luminescence Performance of Cr 3+ ‐Activated Ca 3 Ga 2 Ge 3 O 12 Broadband NIR Phosphors0When the crucible contributes: serendipitous formation, flux reactivity, and crystal and electronic structures of two aluminium-bearing mixed-metal oxides, Ba 2.1 Pb 0.9 Al 8.8 In 2.2 O 20 and BaAl 1.6 Ga 0.4 O 40Garnet-structured Y2CaGa4ZrO12:Cr3+ NIR phosphor with combined high efficiency and thermal stability toward constructing high-performance pc-NIR-LED1Achieving ultra-broadband tunable near-infrared luminescence in Cr3+-doped Li2Mg3SnO6 phosphor for bioimaging and night vision0Comparative study on the photoluminescence properties of Eu3 +/Nd3+/Yb3+ co-doped monoclinic YTaO4, YNbO4, and cubic yttria-stabilized zirconia single crystals0Far apart but still bright: The first observation of sensitizing the solid state NIR luminescence of Yb3+ ions via the outer-sphere antennas0Dual-site Fe3+ emission in Ba3ScB3O9 borate enables broadband near-infrared luminescence for flexible film applications0Near-infrared phosphor development and broad-range regulation of Cr3+ luminescence via Ca2+/Si4+ incorporation in Y3Ga3Al2O12 garnet0Energy Transfer Engineering Enables Efficient Near‐Infrared Luminescence and Zero‐Thermal‐Quenching in GAGG: Fe 3+ , Yb 3+ Phosphors0

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  9. Engineering broadband near-infrared emission via the strategic assembly of Cr 3+ ion pairs in aluminum-based spinels

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