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RESEARCH PAPER · Coordination Chemistry Reviews · 2025

Recent advances in Fe-based metal-organic frameworks: Structural features, synthetic strategies and applications

Keaoleboga Mosupi, Mike Masukume, Guoming Weng, Nicholas Mulei Musyoka, Henrietta Wakuna Langmi

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Recent advances in Fe-based metal-organic frameworks: Structural features, synthetic strategies and applicationsOriginalDouble Cross-Linking Architectonics Membranes and the Mechanistic Investigation During the Contaminants Removing0Double Cross-Linking Architectonics Membranes and the Mechanistic Investigation During the Contaminants Removing0Phosphorus Removal Using Red Mud Based Al/Fe-MOFs Synthesized by Ultrasonic-Assisted Solvent Method: Performance and Mechanisms0Synthesis Derived Mil-101 Analogues of Red Mud for Phosphate Adsorption by Ultrasound-Assisted Solvent Method: Performance and Mechanisms0Synthesis of iron-based metal–organic frameworks and carbon derivatives via unconventional synthetic methods and waste precursors with potential for gas storage6Dose-dependent effects of MIL-88A(Fe) and MIL-101(Fe) on arsenic immobilization and phytoremediation using ramie (Boehmeria nivea L.)12Metal-organic framework composites for green catalysis: Coordination chemistry approaches to sustainable energy and environmental solutions32Hierarchical porous chromium metal-organic framework augmented with tungsten trioxide and carbon nanotubes as a binder-free electrode for asymmetric supercapacitors and hydrogen production3Development of a pH/Cellulase Dual-Responsive Fe-MOFs Delivery System for Targeted Control of Maize Fungal Diseases7Advanced three-dimensional porous materials for uranium extraction: Strategies for enhancing adsorption performance and optimizing reusability, anti-fouling property19Double cross-linking architectonics membranes for high-efficiency oil-water separation and the mechanistic investigation5Fe–Ce Bimetallic MOFs for Water Environment Remediation: Efficient Removal of Fluoride and Phosphate5Enhancing Industrial Oxygen Evolution Reaction Activity and Corrosion Resistance through Multielement Synergy of FeCoNiOx-MOF5Fe/Mn bimetal-doped ZIF-8-encapsulated chitosanase for highly efficient synthesis of chitosan oligosaccharide2II-scheme cage-on-MOF nanoreactor: Interfacial engineering for synergistic adsorption-catalysis of oxytetracycline8Selected sustainably synthesized metal–organic frameworks for hydrogen and carbon dioxide storage4Manufacturing strategies for metal organic framework-based membrane electrode assemblies in electrolyzers10Full title:Metal-organic frameworks (MOFs) for encapsulation of natural active substances in food applications: a review5High-temperature activity coefficient prediction: Thermodynamic-Machine learning synergistic modeling of binary Mg-based alloy system at 500 °C4Nano‐Mechanical DNA Devices Coupled With CRISPR‐Cas12a for CA15‐3 Detection2Applications of iron-based nanoenzymes in wound healing: antibacterial, anti-inflammatory, and wound-promoting effects0Evaluation of the influence of various metals in iron-rich acid mine drainage on crystallinity, morphology and textural properties of iron-based MIL-1010Molten-salt-mediated synthesis: Engineering Fe single-atom sites on HKUST-1 derivative derived carbon for efficient oxygen reduction reaction0Synergistic immobilization of Pb and Cd in soil by S-doped Cu-MOF functionalized biochar: Experimental and DFT insights0The future of MOFs0Tri-responsive multifunctional metal–organic framework (MuF-MOF) nanozyme-based sensors12Water induces crystal orientation during MIL-88A (Fe) growth: linking morphology with antibacterial activity0MOF-derived hierarchical Fe3O4@C cubes for enhanced lithium storage in lithium-ion batteries3Structurally Engineered Ferrous Metal–Organic Framework as a Chemodynamic Therapy Nanoagent for Concurrent Hydroxyl Radical and Singlet Oxygen Generation5Fabrication of Trimetallic Metal–Organic Frameworks for the Rapid Removal of Bisphenol A from Water1Sustainably Developed Iron-MOF for Water Softening and Efficient Removal of Organic Contaminants with Enhanced Antibacterial Activity1Electrocatalytic oxygen reduction reaction on single-cluster catalyst in 2D metal-organic frameworks: A density functional theory study0Fe metal–organic framework–derived heterojunction for metabolic diagnosis of thymic epithelial tumor4Recent advances in Ce-containing Ni, Fe, and Co catalysts for water/seawater electrolysis10Amplifying voltammetric signal for detection of tumor CD63-positive exosomes by amending biocatalysis capability of catechol oxidase-mimicking MOFzyme@aptamer2Comparative Evaluation of Fe-MOF, Cu-MOF, and Bimetallic Fe/Cu-MOF for Enhanced CO₂ Adsorption: Synthesis, Characterization, and Performance Analysis2Electron Transfer-Enhanced Bimetallic MOF Nanozymes Enabling a Self-Validating Dual-Mode Aptasensor for Aflatoxin B 111Photo-self-Fenton/peroxymonosulfate synergistic system based on hydrothermal carbonization carbon@MIL-88A(Fe) S-scheme heterojunction for efficient tetracycline degradation3Facile Synthesis of Iron-Based MIL-101 Metal-Organic Framework as a Potential Hydrogen Storage Material3Advances in Metal Organic Framework (MOF)–Integrated Smart Textiles5Simplified Assembly Process for Efficient Light‐Driven MOF‐Based Water Oxidation Catalysts in Acidic pH0Synthesis, functionalization, adsorption performance and mechanism of MIL-53(Fe)-based materials for wastewater treatment3Reimagining Textile Effluent Treatment Using Metal–Organic Framework-Based Hybrid Catalysts: A Critical Review5Toward next-generation PEM fuel cells: Recent progress in materials, design, and commercialization3Fluoride-regulated phase evolution in Fe-based metal–organic frameworks enables enhanced lithium adsorption1Metal–organic frameworks for pesticide remediation: From adsorption and photocatalysis to health‐relevant risk reduction2Metal organic frameworks as next-generation drug delivery platforms: Design principles, pharmaceutical applications, and translational challenges1PH‐Responsive Cu‐Fe‐MOF@Ag Nanocomposite Modulates Antibacterial and Anti‐Inflammatory Activity in Infected Wounds1Toward rational design of porous frameworks for CO2 capture: From POPs and MOFs to hybrid and derived materials0Reconstruction of Metal‐Organic Frameworks for Enhanced Electrocatalytic Performance11Bimetallic iron‑cobalt organic framework-functionalized graphene oxide for smartphone-assisted colorimetric sensing of glutathione in rat serum1Metal-organic frameworks for catalytic degradation of emerging dye contaminants in wastewater: A critical review of material design, reaction mechanisms, and engineering application12Synergistic effects of iron-based metal-organic frameworks on enhancing electron transfer and shaping microbial communities for ethanol-driven carboxylate chain elongation0Temporal engineering of MOF skeletons: Emerging opportunities in energy storage and molecular motors1MOF-derived layered-double-hydroxides (LDHs) for supercapacitors: a comprehensive review3A Porous and Amorphous Zn-Doped Fe Metal–Organic Framework for the Efficient Adsorptive Removal of Methylene Blue Dye from Wastewater Samples0Programmable Atomic Composition through Transmetalation for Isostructural Multimetallic Metal–Organic Frameworks0ZIF-8 synthesis in aqueous solution as a container for smart pH-sensitive release of corrosion inhibitor0Engineering iron MOFs as drug nanocarriers: strategies, capacities, toxicity, and horizons0Bridging Green Intelligent Fertilizers and Nutrient Intelligence for Climate-Smart Food Systems0Preparation of Multifunctional Hydrogel Loaded with Isochlorogenic Acid A/Fe3+ Co-Assembled Nanoparticles and Its Application in Skin Wound Repair1Next-generation hybrid membranes integrating MXene and MOF architectures for energy-efficient water treatment1Beyond synergy in MOF nanocomposites: Autocatalytic degradation, inhibition by magnetite, and reactivation within the “autocatalysis window”0Efficient Fenton-Like Degradation of Methylene Blue Using a Green-Synthesized MOF Catalyst0Semi‐Solid Flow Batteries: Fundamentals, Recent Advances, and Future Perspectives0Next-Generation Metal−Organic Framework-Based Nanocomposites for Integrated Energy Storage and Corrosion Protection: Mechanistic Insights and Future Perspectives0Green-Synthesized Nanomaterials for Fenton and Fenton-like Degradation of Pharmaceutical Pollutants in Water Treatment0Multifunctional ionic liquid@ZIF-67/polyethyleneimine@PAN fibrous nanocomposites for ultra-high iodine capture and recyclability0Temperature-dependent charge transport and photovoltaic performance of a hybrid Cu(II)–semicarbazone pyranoquinoline-based heterojunction0MIL-53(Fe)-mediated persulfate activation for the removal of pesticides-contaminated water: phytotoxicity evaluation, theoretical reactivity prediction and by-products degradation pathways0Synergistic Thermal Energy and Charge Carriers in an Fe‐MOF for Solar‐Driven Scalable and Selective Aniline Production0Cu2O-anchored amine-functionalized Ti-MOF heterojunctions for synergistic photoelectrochemical hydrogen evolution from water splitting0Order–disorder dynamics, wide-band-gap optical response, and dielectric relaxation in the hybrid tetrachloroferrate [(CH3)3N(CH2)2Cl]FeCl40Redox-assisted electrosorption pathways for nickel removal and recovery using carbon nanotubes modified iron based MOF in capacitive deionization0Molten-salt-mediated synthesis: Engineering Fe single-atom sites on HKUST-1-derived carbon for efficient oxygen reduction reaction0Resource utilization of steel slag for fabrication of Fe-MOF-based photothermal superwetting textiles with rapid viscous oil/water separation0Advanced Nanostructured Materials for Solar-Driven CO2 Photocatalytic Conversion: Progress, Mechanisms, and Future Perspectives0Synergistic catalysis via MIL‑101(Fe)/ZIF‑67 derived Fe2O3/C/Co3O4 ternary nanocomposite: a superior heterogeneous platform for accelerated Hantzsch and Biginelli reactions0

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