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RESEARCH PAPER · Chemical Communications · 2025

Advances in accessing rare oxidation states of nickel for catalytic innovation

Aankhi Khamrai, Sudipta Kumar Ghosh, Venkataraman Ganesh

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Advances in accessing rare oxidation states of nickel for catalytic innovationOriginalSynthesis of 1,1-bis(indolyl)alkenes via nickel-catalyzed selective alkynylation of indoles with haloalkynes3Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals6Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals1Structural and spectroscopic insights of medium-entropy Na2-uNi2+2-xNi3+x(Cr3+1-yCr4+y)1-wFe3+w(PO4)3 cathodes with sodium-ion insertion0Targeted Design of Ni(II)–Hydrazide Complexes for Biomedical Relevance: Synthesis, Cytotoxicity, and DFT Perspectives1An octahedral Ni(III)-thiosemicarbazone complex with cytotoxic potential3Titanium dioxide nanotubes modified with nickel oxide and nickel nanoparticles for improved polysulfide anchoring and redox kinetics in lithium–sulfur batteries0Recent Developments in the Field of Air‐Stable Nickel(0) Precatalysts for Cross‐Coupling Reactions4Mononuclear, Homo- and Heterodinuclear Nickel(I) and Palladium(I) Carbonyl Complexes1Arene fluorination and trifluoromethylation enabled by tetravalent group 10 metals ('formally' NiIV, PdIV, PtIV)1Nickel-Catalyzed Hydroalkynylation of Unactivated Alkenes: Synthesis of Substituted Alkynes1Radical Carbonylation of Aryl Bromides Enabled by Decoupling Nickel–CO Binding1Harnessing Thermally Labile Tethered Tetraynes to Access para -Diethynylbenzenes: A Ni(0)-Catalyzed Cocyclotrimerization Strategy0Highly Active cis -Diphosphinoalkenyl-Nickel Catalysts for Suzuki–Miyaura Cross-Coupling Reaction of Aryl Chlorides and Aryl Boronic Acids0Electrochemical asymmetric transformations enabled by transition metal catalysis0

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  1. Synthesis of 1,1-bis(indolyl)alkenes via nickel-catalyzed selective alkynylation of indoles with haloalkynes

    Organic Chemistry Frontiers · 2025-01-01

    Shuqi Guo, Xinni Qiu, Huanfeng Jiang, Shaorong Yang, Wanqing Wu

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  2. Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals

    Angewandte Chemie International Edition · 2025-09-04

    Tim Bruckhoff, Vincenz J. Kohler, Felix Braun, Joachim Ballmann, Lutz H. Gade

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  3. Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals

    Angewandte Chemie · 2025-09-04

    Tim Bruckhoff, Vincenz J. Kohler, Felix Braun, Joachim Ballmann, Lutz H. Gade

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  4. Structural and spectroscopic insights of medium-entropy Na2-uNi2+2-xNi3+x(Cr3+1-yCr4+y)1-wFe3+w(PO4)3 cathodes with sodium-ion insertion

    Journal of Solid State Chemistry · 2025-09-20

    Rihab Trimech, Khalifa Souiwa, Bo Song, Zhanhua Wei, Mourad Hidouri, Brahim Ayed, Ruqin Ma, Yong Yang, Gregorio F. Ortiz

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  5. Targeted Design of Ni(II)–Hydrazide Complexes for Biomedical Relevance: Synthesis, Cytotoxicity, and DFT Perspectives

    ChemistrySelect · 2025-10-30

    G. Devagi, A. Shanmugapriya, S. Ponnusamy, Werner Kaminsky, S. Ruba, G. Sathiyaraj

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  6. An octahedral Ni(III)-thiosemicarbazone complex with cytotoxic potential

    Inorganic Chemistry Communications · 2025-11-11

    Sourav Nath, Sourav Singha Roy, Susanta Ghanta, Somnath Bej, Bilash Chandra Roy, Koushik Saha, Ray John Butcher, Akalesh Kumar Verma, Tufan Singha Mahapatra, Suman Adhikari

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  7. Titanium dioxide nanotubes modified with nickel oxide and nickel nanoparticles for improved polysulfide anchoring and redox kinetics in lithium–sulfur batteries

    Nanoscale Advances · 2026-01-01

    Emmanuel Siaw, Dias Bekeshov, Alas Alaskhanov, Aishuak Konarov, Zhumabay Bakenov, Nurzhan Baikalov, Stavros G. Poulopoulos

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  8. Recent Developments in the Field of Air‐Stable Nickel(0) Precatalysts for Cross‐Coupling Reactions

    European Journal of Inorganic Chemistry · 2026-01-23

    Franziska Flecken, Schirin Hanf

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  9. Mononuclear, Homo- and Heterodinuclear Nickel(I) and Palladium(I) Carbonyl Complexes

    Inorganic Chemistry · 2026-02-26

    Tim Bruckhoff, Felix Braun, Vincenz J. Kohler, Joachim Ballmann, Lutz H. Gade

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  10. Arene fluorination and trifluoromethylation enabled by tetravalent group 10 metals ('formally' NiIV, PdIV, PtIV)

    Coordination Chemistry Reviews · 2026-03-11

    Luca Demonti, Hana Tabikh, Noel Nebra

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  11. Nickel-Catalyzed Hydroalkynylation of Unactivated Alkenes: Synthesis of Substituted Alkynes

    The Journal of Organic Chemistry · 2026-03-16

    Ankita Kar, Masilamani Jeganmohan

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  12. Radical Carbonylation of Aryl Bromides Enabled by Decoupling Nickel–CO Binding

    ACS Catalysis · 2026-05-05

    Peipei He, Hua-Wei Liu, Tianshuai Zhu, Zupeng Chen, Zupeng Chen, Zhen Chen, Zhen Chen

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  13. Harnessing Thermally Labile Tethered Tetraynes to Access para -Diethynylbenzenes: A Ni(0)-Catalyzed Cocyclotrimerization Strategy

    Organic Letters · 2026-06-05

    Rajesh Chakrabortty, Tamal Ballav, Venkataraman Ganesh

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  14. Highly Active cis -Diphosphinoalkenyl-Nickel Catalysts for Suzuki–Miyaura Cross-Coupling Reaction of Aryl Chlorides and Aryl Boronic Acids

    The Journal of Organic Chemistry · 2026-06-22

    X James Li, M C Wang, Chaoyin Zhu, Zhongxian Li, Yanchun Guo, Junliang Wu

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  15. Electrochemical asymmetric transformations enabled by transition metal catalysis

    Molecular Catalysis · 2026-07-28

    Shibo Lin, Fangqing Xie, Yiwen Chu, Junfeng Deng, Lifeng Zhao

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