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RESEARCH PAPER · Applied Catalysis B: Environmental · 2024

Regulating spin state of Fe(III) by the Mo single atom anchored in the (001) crystal face of α-Fe2O3 to achieve efficient electrocatalytic nitrate to synthesize ammonia

Zhenyu Yan, Wenyu Gao, Chenkai Zhong, Qiangqiang Jiao, Shujie Tian, Jia Liu

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Regulating spin state of Fe(III) by the Mo single atom anchored in the (001) crystal face of α-Fe2O3 to achieve efficient electrocatalytic nitrate to synthesize ammoniaOriginalEnhanced Piezo-Fenton Synergies Enabled by Interface-Engineered 0d/3d Heterojunctions (Fe Qds@Bto): Investigation of Interfacial Behavior and Reaction Mechanism0Activating Surface Oxygen in Ce/Mo‐Doped Ni Oxyhydroxide for Synergistically Enhancing Furfural Oxidation and Hydrogen Evolution at Ampere‐Level Current Densities2Activating Surface Oxygen in Ce/Mo‐Doped Ni Oxyhydroxide for Synergistically Enhancing Furfural Oxidation and Hydrogen Evolution at Ampere‐Level Current Densities42Electron localization regulated by confined Co3O4 enhances electrocatalytic nitrate reduction to ammonia15Interface coupling induced electronic effect of NiCo-LDH/Cu2O heterojunction catalysts towards efficient electrochemical nitrate reduction to ammonia4Lattice-strained Pd nanoclusters embedded into NiMoO4 nanorods: Manipulating active hydrogen to intensify nitrite hydrogenation for ammonia production and electricity supply5Synergistic cobalt valence cycling and oxygen vacancy in Co(II)Co(III)Al(III)-layered double hydroxides enable efficient electrocatalytic nitrate-to-ammonia conversion1In‐Situ Electrochemical Reconstruction of Copper Single‐Sites to Dual‐Sites for Ambient Urea Synthesis7In‐Situ Electrochemical Reconstruction of Copper Single‐Sites to Dual‐Sites for Ambient Urea Synthesis24Cu nanoparticles as efficient co-catalysts significantly improve the photocatalytic activities of α-Fe2O3/NaTaO3 heterojunctions2Unveiling cutting‐edge developments on d‐block iron‐based materials for electrocatalytic ammonia synthesis3Enhanced piezo-Fenton synergies enabled by interface-engineered 0D/3D heterojunctions (Fe2O3 QDs@BTO): investigation of interfacial behavior and reaction mechanism0Dual-site cooperation for synergistic optimization of the band structure and spin state to facilitate C–N coupling reaction21Molybdenum-modified iron oxides mediated enhanced degradation of meropenem by peroxydisulfate3Exploring the Reaction Mechanism of Efficient Electrochemical Nitrate Reduction to Ammonia over Carbon Cloth-Supported α-Co(OH) 2 Nanosheets1Single‐Site Polyoxometalate Complexes with Engineered Electron Channels for Efficient Electrocatalytic Ammonia Synthesis from Nitrate8Molecular Weaving of Mixed‐Addenda Polyoxometalates into MOF Nanochannels as Electron‐Buffering Reservoirs for Enhanced Nitrate‐to‐Ammonia Electrocatalysis10Electrodeposited polyoxometalate–Cu 2+1 O hybrid on copper foam: synergistic electron transfer for efficient nitrate electroreduction to ammonia1Fe-assisted nitridation-induced reconstruction of Mo–Fe–Ni molybdates enables durable alkaline seawater oxygen evolution and Zn–air batteries1A Lewis acid-base dance in polyoxometalates confined within zirconium-porphyrin MOFs drives efficient nitrate-to-ammonia electrochemical conversion8Facet polarization electric field and Fe single-atom co-regulate bulk carriers separation for photocatalytic nitrogen fixation2Lattice‐Confined Ru Creates Electron‐Deficient Fe(II)─Ov─Ru Atomic Interface for Efficient Nitrate‐to‐Ammonia Electrosynthesis0Spin-State-Modulated Interfacial Fe 2+ in Solid-Solution Heterostructures Promotes H 2 O 2 Selectivity and Electro-Fenton Antibiotic Degradation1Spin‐State Modulation of Nickel Enables High‐Efficiency and Durable Nitrate Electroreduction to Ammonia3Boosting Electrochemical Ammonia Synthesis from Nitrate via Electrolyte Cation-Tuned NiFe-LDH Catalysts with Low-Spin Fe 3+ Active Sites1Synergistic Integration of Intermediate Adsorption and Hydrogen Supply to Boost Nitrate Electroreduction to Ammonia Performance via Anchoring Nickel on Monolithic Copper Nanocone Arrays0From Waste to Wealth: Single‐Atom Catalysts for Green Ammonia Synthesis via Nitrate Electroreduction0Light-induced dynamic oxygen vacancies for synchronized photocatalytic nitrate reduction and alcohol oxidation0Spin-State Engineering for Multi-Electron Reactions: Active Sites and Reaction Mechanisms0

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  1. Enhanced Piezo-Fenton Synergies Enabled by Interface-Engineered 0d/3d Heterojunctions (Fe Qds@Bto): Investigation of Interfacial Behavior and Reaction Mechanism

    SSRN Electronic Journal · 2025-01-01

    Shuai Liu, Xueyao Wang, Xuyang Hu, Lihui Huang, Ting Sun, Lingshuai Kong, Zhenhui Gao, Rongbing Fu, Xiao Yu

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  2. Activating Surface Oxygen in Ce/Mo‐Doped Ni Oxyhydroxide for Synergistically Enhancing Furfural Oxidation and Hydrogen Evolution at Ampere‐Level Current Densities

    Angewandte Chemie · 2025-05-07

    Tian Cao, Jia Cheng, Yang Xiang, Linping Hu, Xiaohua Hu, Li Li, Xun Huang, Zidong Wei

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  3. Activating Surface Oxygen in Ce/Mo‐Doped Ni Oxyhydroxide for Synergistically Enhancing Furfural Oxidation and Hydrogen Evolution at Ampere‐Level Current Densities

    Angewandte Chemie International Edition · 2025-05-07

    Tian Cao, Jia Cheng, Yang Xiang, Lingping Hu, Xiaohua Hu, Li Li, Xun Huang, Zidong Wei

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  4. Electron localization regulated by confined Co3O4 enhances electrocatalytic nitrate reduction to ammonia

    Journal of Hazardous Materials · 2025-06-21

    Qinan Song, Wenxin Dong, Junxiao Wang, Shuo Zhang, Miao Li, Daihan Qu, Yutong Shang, Junchun Chen, Shihao Zhang, Jinsuo Lu

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  5. Interface coupling induced electronic effect of NiCo-LDH/Cu2O heterojunction catalysts towards efficient electrochemical nitrate reduction to ammonia

    Science China Materials · 2025-06-27

    Lei Li, Qiuhan Cao, Xiaoyi Dong, Xin Yu, Yao Hu, Shiqi Zeng, Xiaohui Guo

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  6. Lattice-strained Pd nanoclusters embedded into NiMoO4 nanorods: Manipulating active hydrogen to intensify nitrite hydrogenation for ammonia production and electricity supply

    Applied Catalysis B: Environmental · 2025-07-02

    Jiayi Zhang, Qiyao Zeng, Lunhong Ai, Chenghui Zhang, Xinzhi Wang, Aike Liu, Jing Yang Jiang

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  7. Synergistic cobalt valence cycling and oxygen vacancy in Co(II)Co(III)Al(III)-layered double hydroxides enable efficient electrocatalytic nitrate-to-ammonia conversion

    Surfaces and Interfaces · 2025-07-03

    Yiwen Chen, Yajie Bai, Zhenyuan Fang, Kangkang Jia, Xianlei Jiang, Jianming Li, Weiqiang Fan

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  8. In‐Situ Electrochemical Reconstruction of Copper Single‐Sites to Dual‐Sites for Ambient Urea Synthesis

    Angewandte Chemie · 2025-07-29

    Jiafang Liu, Shengbo Zhang, Zhixian Mao, Wenyi Li, Meng Jin, Huajie Yin, Yunxia Zhang, Guozhong Wang, Haimin Zhang, Huijun Zhao

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  9. In‐Situ Electrochemical Reconstruction of Copper Single‐Sites to Dual‐Sites for Ambient Urea Synthesis

    Angewandte Chemie International Edition · 2025-07-29

    Jiafang Liu, Shengbo Zhang, Zhixian Mao, Wenyi Li, Meng Jin, Huajie Yin, Yunxia Zhang, Guozhong Wang, Haimin Zhang, Huijun Zhao

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  10. Cu nanoparticles as efficient co-catalysts significantly improve the photocatalytic activities of α-Fe2O3/NaTaO3 heterojunctions

    Journal of Physics and Chemistry of Solids · 2025-08-21

    Tingting Han, Yan Xia Guo, Hongru Han, Jianyu Xing, Yuefa Jia

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  11. Unveiling cutting‐edge developments on d‐block iron‐based materials for electrocatalytic ammonia synthesis

    Rare Metals · 2025-09-01

    Yihang Yu, Yifan Yuan, Wei Li, Mohamed Nawfal Ghazzal, Yi‐Bing Cheng, Jingwei Li, Ruchun Li, San Ping Jiang

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  12. Enhanced piezo-Fenton synergies enabled by interface-engineered 0D/3D heterojunctions (Fe2O3 QDs@BTO): investigation of interfacial behavior and reaction mechanism

    Chemical Engineering Journal · 2025-10-10

    Shuai Liu, Xueyao Wang, Xuyang Hu, Lihui Huang, Ting Sun, Lingshuai Kong, Zhenhui Gao, Rongbing Fu, Xiao Yu

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  13. Dual-site cooperation for synergistic optimization of the band structure and spin state to facilitate C–N coupling reaction

    Proceedings of the National Academy of Sciences · 2025-10-21

    Qizhu Qian, Qilong Liu, Mengxiang Wang, Jingjing Yang, Huiyi Li, Wei Yang Bai, Wentao Wang, Changzheng Wu, Chong Xiao, Yi Xie

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  14. Molybdenum-modified iron oxides mediated enhanced degradation of meropenem by peroxydisulfate

    Chemical Engineering Journal · 2025-10-21

    Gwangmin Kim, Ayoung Choi, Haesung Lee, Libor Machala, Minhee Kim, Pinelopi P. Falara, Michaela Polášková, Petr Novák, Nikolaos E. Ioannidis, George Mitrikas, Virender K. Sharma, Mallikarjuna N. Nadagouda, Bineyam Mezgebe, Changseok Han

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  15. Exploring the Reaction Mechanism of Efficient Electrochemical Nitrate Reduction to Ammonia over Carbon Cloth-Supported α-Co(OH) 2 Nanosheets

    Langmuir · 2025-11-04

    Xiaoru An, Xiaonan Du, Hong Li, Fei Gao, Yue Hua, Xiuling Zhang, Jingsen Zhang, Lanbo Di

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  16. Single‐Site Polyoxometalate Complexes with Engineered Electron Channels for Efficient Electrocatalytic Ammonia Synthesis from Nitrate

    Small · 2025-11-14

    Qiushuang Jiang, Xinming Wang, Gang Li, Nan Zhao, Haijun Pang, Huiyuan Ma

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  17. Molecular Weaving of Mixed‐Addenda Polyoxometalates into MOF Nanochannels as Electron‐Buffering Reservoirs for Enhanced Nitrate‐to‐Ammonia Electrocatalysis

    Advanced Science · 2025-12-25

    Gang Li, Xinming Wang, Haijun Pang, Huiyuan Ma

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  18. Electrodeposited polyoxometalate–Cu 2+1 O hybrid on copper foam: synergistic electron transfer for efficient nitrate electroreduction to ammonia

    Dalton Transactions · 2026-01-01

    Kaiqun Bai, Xinming Wang, Gang Li, Haijun Pang, Huiyuan Ma

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  19. Fe-assisted nitridation-induced reconstruction of Mo–Fe–Ni molybdates enables durable alkaline seawater oxygen evolution and Zn–air batteries

    Journal of Materials Chemistry A · 2026-01-01

    Hamza M. Haruna, Yanxiang He, Zhixiao Zhu, Hao Yang, Selvam Mathi, Guanhua Zhang, Zhongmin Wang, Muhammad‐Sadeeq Balogun

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  20. A Lewis acid-base dance in polyoxometalates confined within zirconium-porphyrin MOFs drives efficient nitrate-to-ammonia electrochemical conversion

    Applied Catalysis B: Environmental · 2026-04-02

    新铭 王, Nan Zhao, Jian Li, Qiushuang Jiang, G. H. Li, Haijun Pang, Huiyuan Ma, Qian Chen, Sitaramanjaneya Mouli Thalluri, Yury V. Kolen’ko, Zhipeng Yu

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  21. Facet polarization electric field and Fe single-atom co-regulate bulk carriers separation for photocatalytic nitrogen fixation

    Applied Catalysis B: Environmental · 2026-04-03

    Hao Du, Huihui Zhou, Behzad Hameed, Shengjie Xia, Chao Yang, Chenglin Zhong, Woon-Ming Lau, Guanhua Zhang

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  22. Lattice‐Confined Ru Creates Electron‐Deficient Fe(II)─Ov─Ru Atomic Interface for Efficient Nitrate‐to‐Ammonia Electrosynthesis

    Advanced Functional Materials · 2026-05-01

    Zhenxiao Wang, Xinhai Deng, Kangwei Cao, Siyuan Zhong, Liying Cao, Yangping Zhang, Yue Wang, Danhong Shang, Chao Yu, Fu Yang, Jie Yu, Min Liu

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  23. Spin-State-Modulated Interfacial Fe 2+ in Solid-Solution Heterostructures Promotes H 2 O 2 Selectivity and Electro-Fenton Antibiotic Degradation

    ACS Applied Materials & Interfaces · 2026-05-07

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  24. Spin‐State Modulation of Nickel Enables High‐Efficiency and Durable Nitrate Electroreduction to Ammonia

    Advanced Functional Materials · 2026-05-20

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  25. Boosting Electrochemical Ammonia Synthesis from Nitrate via Electrolyte Cation-Tuned NiFe-LDH Catalysts with Low-Spin Fe 3+ Active Sites

    ACS Applied Materials & Interfaces · 2026-05-26

    Zhenyu Yan, Wenyu Gao, Junkai Wen, Biyue Xie, Jisheng Geng, Qiangqiang Jiao, Jia Liu

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  26. Synergistic Integration of Intermediate Adsorption and Hydrogen Supply to Boost Nitrate Electroreduction to Ammonia Performance via Anchoring Nickel on Monolithic Copper Nanocone Arrays

    Small Methods · 2026-07-06

    Aijing Ma, Xuan Wu, Xin Li, Dan Liu, Alex Tawanda Kuvarega, Bhekie B. Mamba, Jianzhou Gui

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  27. From Waste to Wealth: Single‐Atom Catalysts for Green Ammonia Synthesis via Nitrate Electroreduction

    ChemSusChem · 2026-07-12

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  28. Light-induced dynamic oxygen vacancies for synchronized photocatalytic nitrate reduction and alcohol oxidation

    Applied Catalysis B: Environmental · 2026-09-05

    Peng Liu, Du Fei, Gen Chen, Xiaohe Liu, Min Liu, Ning Zhang

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  29. Spin-State Engineering for Multi-Electron Reactions: Active Sites and Reaction Mechanisms

    ACS Nano · 2026-10-02

    Zihang Liu, Weiyao Hao, Xianghong Niu, Zhaoming FU, Longlu Wang, Qiang Zhao, Shiyan Wang

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