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RESEARCH PAPER · ACS Energy Letters · 2024

The Detail Matters: Unveiling Overlooked Parameters in the Mechanochemical Synthesis of Solid Electrolytes

Abdulkadir Kızılaslan, Mustafa Bahattin Çelik, Yuta Fujii, Zheng Huang, Chikako Moriyoshi, Shogo Kawaguchi, Satoshi Hiroi, Koji Ohara, Mariko Ando, Kiyoharu Tadanaga, Saneyuki Ohno, AKIRA B. MIURA

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The Detail Matters: Unveiling Overlooked Parameters in the Mechanochemical Synthesis of Solid ElectrolytesOriginalDual-site synergistic passivation for CsPbBr 3 perovskite solar cells with record 1.707 V V oc and 11.23% efficiency19Storage Batteries as a Key Device for Solving the Global Warming Issue—Team-based Research for Development of Rechargeable Batteries in the Green Technologies for Excellence (GteX) Program—0Kinetic effects of ball-milling precursors on the synthesis pathway of KSbF40Exploring the Effect of Anion Substitution on the Solid Ionic Conductor NaTaCl60Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes1Oxygen-Mediated Structural Modulation and Ion Transport in x Na 2 O-TaCl 5 Glass Electrolytes11A Sub‐1 Nm Cluster Chains‐enhanced Poly(ethylene oxide) Electrolyte for an All‐solid‐State Lithium Metal Battery with a Long Cycling Lifespan2Advances in solid-state lithium–sulfur batteries for next-generation energy storage12Structural Aspects, Ionic Conductivity, and Electrochemical Properties of New Bromine-Substituted Alkali-Based Crystalline Phases MTa(Nb)X 6– y Br y (M = Li, Na, K; X = Cl, F)3Crystal structure and Li + conductivities of lithium oxy-thiophosphate solid electrolytes Li 9 P 3 S (12− x ) O x prepared via mechanochemical synthesis0HCl-free mechanochemical synthesis of oxyhalide solid electrolyte LiNbO x Cl (6−2 x ) using LiCl, NbCl 5 , and Nb 2 O 50Preparation and Electrochemical Analysis of Si@PVP/Sugar Structured Self-Supporting Silicon Anodes0Research trend of solid electrolytes by mechanochemical synthesis: a review0Structural stabilization of high-voltage P2-type layered oxide cathodes through Li/Ti co-doping for sodium-ion batteries0Tailoring crystallization protocols to boost ionic conductivity in Li7P3S11 solid electrolytes via controlled two-step thermal processing2Air Stability of Sulfide Solid Electrolytes: From Theoretical Insights to Practical Solutions0One-step Ta2O5-induced amorphization enables improved humid-air tolerance in NaTaCl6-based solid electrolytes for all-solid-state sodium batteries0Glass formation and ionic transport in the mechanosynthesized Na₂S-SnS₂ system0

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  1. Dual-site synergistic passivation for CsPbBr 3 perovskite solar cells with record 1.707 V V oc and 11.23% efficiency

    Journal of Materials Chemistry A · 2025-01-01

    Yinping Teng, Yuanyuan Zhao, Zhe Xin, Liqiang Bian, Qiyao Guo, Jialong Duan, Jie Dou, Yan Zhang, Qiang Zhang, Qunwei Tang

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  2. Storage Batteries as a Key Device for Solving the Global Warming Issue—Team-based Research for Development of Rechargeable Batteries in the Green Technologies for Excellence (GteX) Program—

    Electrochemistry · 2025-05-01

    Susumu Kuwabata

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  3. Kinetic effects of ball-milling precursors on the synthesis pathway of KSbF4

    Ceramics International · 2025-05-09

    Ryuku Hisasue, Tack Saquai, Tom Ichibha, Yuta Fujii, Aichi Yamashita, Kenta Hongo, Ryo Maezono, Kiyoharu Tadanaga, Akira Miura

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  4. Exploring the Effect of Anion Substitution on the Solid Ionic Conductor NaTaCl6

    Inorganic Chemistry · 2025-09-10

    Vasiliki Faka, Bibek Samanta, Iven Koers, Martin Lange, Marvin A. Kraft, Michael Ryan Hansen, Xabier Martínez de Irujo-Labalde

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  5. Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

    Advanced Materials Interfaces · 2025-10-27

    Keita Kurigami, Akihiro Ishii, Itaru Oikawa, Hitoshi Takamura

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  6. Oxygen-Mediated Structural Modulation and Ion Transport in x Na 2 O-TaCl 5 Glass Electrolytes

    Journal of the American Chemical Society · 2025-11-11

    Zheng Huang, Neha Yadav, Shun Itakura, Peng Song, Hirofumi Akamatsu, Katsuro Hayashi, Prashun Gorai, Saneyuki Ohno

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  7. A Sub‐1 Nm Cluster Chains‐enhanced Poly(ethylene oxide) Electrolyte for an All‐solid‐State Lithium Metal Battery with a Long Cycling Lifespan

    Advanced Science · 2025-11-28

    Shanshan Song, Fei He, Yijun Gao, Yumeng Zhang, Junming Zhang, Tongjiao Yin, Qiqi Sun, Zhiliang Liu, Piaoping Yang

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  8. Advances in solid-state lithium–sulfur batteries for next-generation energy storage

    Progress in Solid State Chemistry · 2025-11-29

    Vennila Selvaraj, Baeksang Yoon, Suresh Sagadevan, Byoenghun Oh, Sangwon Noh, Dong Ick Son, Hyung‐Kee Seo, Inseok Seo, Inseok Seo

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  9. Structural Aspects, Ionic Conductivity, and Electrochemical Properties of New Bromine-Substituted Alkali-Based Crystalline Phases MTa(Nb)X 6– y Br y (M = Li, Na, K; X = Cl, F)

    ACS Energy Letters · 2025-12-12

    Anshuman Chaupatnaik, Gwenaëlle Rousse, Maxim Avdeev, Jean‐Marie Tarascon

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  10. Crystal structure and Li + conductivities of lithium oxy-thiophosphate solid electrolytes Li 9 P 3 S (12− x ) O x prepared via mechanochemical synthesis

    Materials Advances · 2026-01-01

    Yuta Fujii, Harunari Ohta, Akira Miura, Kiyoharu Tadanaga, Kota Terai, Futoshi Utsuno

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  11. HCl-free mechanochemical synthesis of oxyhalide solid electrolyte LiNbO x Cl (6−2 x ) using LiCl, NbCl 5 , and Nb 2 O 5

    RSC Mechanochemistry · 2026-01-01

    Yuta Fujii, Masako Kakesu, Koji Ohara, AKIRA B. MIURA, Kiyoharu Tadanaga

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  12. Preparation and Electrochemical Analysis of Si@PVP/Sugar Structured Self-Supporting Silicon Anodes

    SSRN Electronic Journal · 2026-01-01

    Dengming Xu, Chen Feng, Yuxin Meng, Xiaoxia Ma, Dianping Zhang

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  13. Research trend of solid electrolytes by mechanochemical synthesis: a review

    RSC Mechanochemistry · 2026-01-01

    Biying Lin, Jiaming Zhang, Bowei Gan, Yulin Cheng, Chengan Liao, Chuwen Liang, Sunyao Zhang, Qingqing Zhang, Ming Li, Zhipeng Sun

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  14. Structural stabilization of high-voltage P2-type layered oxide cathodes through Li/Ti co-doping for sodium-ion batteries

    Dalton Transactions · 2026-01-01

    Yang Liu, Guo Yong, Xinxin Yin, Xuntao Zhang, Wenjin Qin, Jing Xie, Jindou Hu, Zhenjiang Lu, Yali Cao

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  15. Tailoring crystallization protocols to boost ionic conductivity in Li7P3S11 solid electrolytes via controlled two-step thermal processing

    Journal of Energy Storage · 2026-02-11

    Mustafa Bahattin Çelik, Abdulkadir Kızılaslan, Akira Miura, Kiyoharu Tadanaga, Hatem Akbulut, Tugrul Cetinkaya

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  16. Air Stability of Sulfide Solid Electrolytes: From Theoretical Insights to Practical Solutions

    Energy & environment materials · 2026-05-01

    Hongbing Ding, Yue Hu, Xin Li, Yang Su, X J Wang, Xinlu Wang, Hongbo Zhang, Guixia Liu, Wensheng Yu, Xiangting Dong, X J Wang, Xin Wang, Xin Wang

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  17. One-step Ta2O5-induced amorphization enables improved humid-air tolerance in NaTaCl6-based solid electrolytes for all-solid-state sodium batteries

    Journal of Energy Chemistry · 2026-09-01

    Mingwei Liu, Yanbo Li, Tianyu Guan, Shuting Kong, Xingqun Liao, Yun Yan, Yulin Cao, Xuhui Li, Xinye Mai, Qichong Yuan, Kuan Jing, Yingzhi Li, Huanzhu Lv, Guangfu Luo, Zhouguang Lu

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  18. Glass formation and ionic transport in the mechanosynthesized Na₂S-SnS₂ system

    Solid State Ionics · 2026-09-22

    L. Walczak, R. Escalier, Romain Berthelot, L.H.B. Nguyen, Virginie Viallet, PIARRISTEGUY Andrea Alejandra

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