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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Fluoride Clusterfullerenes: Tuning Metal–Metal Bonding and Magnetic Properties via Single Fluorine Atom Doping

Yi Shen, Yannick Roselló, Laura Abella, Jiawei Qiu, Xiya Du, Qingyu Meng, Lihao Zheng, Zhengkai Cao, Zhiwen He, Josep Maria Poblet, Luis A. Echegoyen, Lei Sun, Antonio Rodríguez‐Fortea, Ning Chen

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Fluoride Clusterfullerenes: Tuning Metal–Metal Bonding and Magnetic Properties via Single Fluorine Atom DopingOriginalSize matching and electrostatic potential as complementary methods for understanding the metallic cluster configurations inside fullerenes1Stable Unpaired Electron States in the Lu–Lu Bond Leading to the Absence of Odd–Even Parity in the Kondo Effect of Lu 2 @C 82 Transistors7Valence-delocalized trithorium nanocluster superatoms with open-shell exalted diamagnetism5Computational Investigations of Metal–Metal Bonding in Molecular Thorium Compounds and Ce and Group IV Analogues2DFT Calculations of Structure and IR Spectra of M@C60 and M2@C60 Endofullerenes (M=Sc and Y)2Bingel–Hirsch reaction on actinidofullerene U@C2v(9)-C82: Improved regioselectivity compared to lanthanide counterpart0Exohedral Complexes of Lanthanide Atoms with the C 60 Fullerene Cage: Hexagonal versus Pentagonal Ring Coordination2Metal–metal bonds inside fullerenes2Relaxation of magnetization in Dy 2 and Tb 2 dimers with single-electron lanthanide–lanthanide bonds: the effect of cage perturbation and its ultimate symmetry0Orientationally Resolved Electron-Spin Relaxation and Coherence in Fullerene-Encapsulated Rare-Earth Dimers with a Single-Electron Metal–Metal Bond2Photoluminescent Rare-Earth Qubits Embedded in a Metal–Organic Framework as Candidates for Optical Quantum Memories0Interaction of Lanthanide Atoms with the External Surface of C80 Fullerene Cage: η5 vs. η6 Coordination1Stabilization of High-Energy Metallic Clusters via Superatom Formation Inside Fullerenes0Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis0

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  1. Size matching and electrostatic potential as complementary methods for understanding the metallic cluster configurations inside fullerenes

    Physical Chemistry Chemical Physics · 2025-01-01

    Chenliang Pan, Shuai‐Jiang Liu, Peng Jin

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  2. Stable Unpaired Electron States in the Lu–Lu Bond Leading to the Absence of Odd–Even Parity in the Kondo Effect of Lu 2 @C 82 Transistors

    Nano Letters · 2025-03-27

    Jun Chen, Yuan Shui, Wangqiang Shen, Feng Wang, Yifu Mao, Haoran Qi, Xinrong Liu, Yu Du, Fucong Fei, Yuyuan Qin, Jianguo Wan, Lipiao Bao, Minhao Zhang, Tao Yang, Xing Qiang Lü, Fengqi Song

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  3. Valence-delocalized trithorium nanocluster superatoms with open-shell exalted diamagnetism

    Nature Chemistry · 2025-04-11

    John A. Seed, Xinglan Deng, Josef Tomeček, Adam Brookfield, David Collison, Floriana Tuna, Ashley J. Wooles, George F. S. Whitehead, Nikolas Kaltsoyannis, Stephen T. Liddle

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  4. Computational Investigations of Metal–Metal Bonding in Molecular Thorium Compounds and Ce and Group IV Analogues

    Inorganic Chemistry · 2025-07-03

    Josef Tomeček, Stephen T. Liddle, Nikolas Kaltsoyannis

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  5. DFT Calculations of Structure and IR Spectra of M@C60 and M2@C60 Endofullerenes (M=Sc and Y)

    Molecules · 2025-08-19

    Alexey V. Krisilov, I. V. Nechaev, V. E. Chernov, Gie Eli Kallu

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  6. Bingel–Hirsch reaction on actinidofullerene U@C2v(9)-C82: Improved regioselectivity compared to lanthanide counterpart

    The Journal of Chemical Physics · 2025-09-26

    Daniel Torrens, Bei Li, Qin Wang, Laura Abella, Yang‐Rong Yao, Josep Maria Poblet, Ning Chen, Antonio Rodríguez‐Fortea

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  7. Exohedral Complexes of Lanthanide Atoms with the C 60 Fullerene Cage: Hexagonal versus Pentagonal Ring Coordination

    The Journal of Physical Chemistry Letters · 2025-11-25

    Vladimir A. Basiuk, Oleg V. Prezhdo, Elena V. Basiuk

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  8. Metal–metal bonds inside fullerenes

    Chemical Communications · 2025-12-05

    Zhanxin Jiang, Ziqi Hu, Shangfeng Yang

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  9. Relaxation of magnetization in Dy 2 and Tb 2 dimers with single-electron lanthanide–lanthanide bonds: the effect of cage perturbation and its ultimate symmetry

    Chemical Science · 2026-01-01

    Matheus Barbosa, Wei Yang, Yaofeng Wang, Georgios Velkos, Stanislav M. Avdoshenko, Fupin Liu, Alexey A. Popov

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  10. Orientationally Resolved Electron-Spin Relaxation and Coherence in Fullerene-Encapsulated Rare-Earth Dimers with a Single-Electron Metal–Metal Bond

    Journal of the American Chemical Society · 2026-02-10

    Michal Zalibera, Lukas Spree, Fupin Liu, Marco Rosenkranz, Leonid Rapatskiy, Alexander Schnegg, Alexey A. Popov

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  11. Photoluminescent Rare-Earth Qubits Embedded in a Metal–Organic Framework as Candidates for Optical Quantum Memories

    ACS Materials Letters · 2026-03-23

    Xiya Du, Lei Sun

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  12. Interaction of Lanthanide Atoms with the External Surface of C80 Fullerene Cage: η5 vs. η6 Coordination

    Surfaces · 2026-04-30

    Vladimir A. Basiuk, Elena V. Basiuk

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  13. Stabilization of High-Energy Metallic Clusters via Superatom Formation Inside Fullerenes

    Inorganic Chemistry · 2026-07-29

    Haoxuan Li, Peng Jin

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  14. Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis

    Angewandte Chemie · 2026-08-23

    Jitpisut Poolwong, Adrian Jenner, Eric Juriatti, Mustafa Turan, Manfred Manßen

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