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RESEARCH PAPER · Advanced Materials · 2024

Rare‐Metal‐Free Ultrabroadband Near‐Infrared Phosphors

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Rare‐Metal‐Free Ultrabroadband Near‐Infrared PhosphorsOriginalAchieving high performance ultra-broadband near-infrared emission through a multi-site occupancy and energy transfer strategy for NIR LED applications16Achieving tunable ultra-broadband NIR emission originating from the two-site occupation of Cr 3+ ions in Mg 3 Ga 2 SnO 8 :Cr 3+17Efficiency optimization of BaY 2 Al 2− y Sc y Ga 2 SiO 12 : x Cr 3+ garnet phosphors with sustained anti-thermal quenching behavior7Energy-transfer enhanced Cr 3+ /Ni 2+ co-doped tantalate phosphors for broadband NIR pc-LED applications9Investigation of the Structure, Energy Transfer, and Tunable Emission of Bi3+/Tb3+/Sm3+: Calaga3o7 Phosphors0Near-infrared luminescence from Li 2 ZnGeO 4 :Ln 3+ (Ln = Er, Tm, Ho)11Strategies for broadening the emission spectra of Cr 3+ -doped near-infrared emitting phosphors59Time-Dependent Chemiluminescence Fingerprint for Ultrasensitive Trap State Identification in Zinc Gallates6Remarkable role of B site regulation on a highly heat-resistant double-perovskite phosphor with versatile NIR utilizations41Ultra-transparent β-Ga 2O 3:Cr 3+ glass-ceramics enabling high-efficiency true-transmission near-infrared light-emitting diodes42Ultrabroadband (Vis‐NIR) Emission in Single‐Component Perovskite LEDs via Tailored Multi‐Exciton Energy Transfer Pathways26Cr3 + -activated SrAl2B2O7 phosphors for near-infrared light-emitting diodes5Energy Transfer Engineering Enabled Efficient and Broad-Band Near-Infrared Emission14Small Stokes Shift Induced Highly Efficient and Thermally Stable Broadband Near‐Infrared Antimonite Double Perovskite Emitters for Spectroscopy Applications8High-efficiency Cr3+-activated broadband near-infrared phosphor GdGa0.5Sb1.5O6: Cr3+ with superior thermal stability for pc-LED8Glass-crystallized far-red-emitting ceramics for high-power, spectrally matched plant-growth light sources20Site‐Selective Occupation of Mn 2+ Activators for Tunable Luminescence in Well‐Designed CaZnGe 2 O 6 Phosphors7Density functional theory facilitates heterovalent substitution: The multi-functional application of near-infrared emitting phosphors with excellent thermal stability0Broadband near-infrared emission enabled by Cr3+→Yb3+ energy transfer in Sr2ScNbO6 double-perovskites for thermally robust NIR pc-LEDs0Structural evolution-facilitated broadband near-infrared emission of multifunctional Sc-based phosphor with long wavelength5Neutron‐Resolved Double Spinel Host Engineering for Ultra‐Broadband NIR Luminescence and Cr 3+ , Ni 2+ Energy Transfer13Traps-engineering in LiGa5O8:xTb3+by Li/Ga ratios for X-ray multimode imaging0Highly Efficient Near‐Infrared Emission (IQE 85%/EQE 75%) From [(Mo 6 I 8 )I 6 ] 2− Cluster‐Doped (ETP) 2 SbCl 5 0D Metal Halide Glass for Multifunctional Optoelectronic Applications2Luminescent Materials for Emerging Sensing Technologies7A blue-light-excitable ultra-broadband near-infrared phosphor across the entire NIR-I and NIR-II windows5High-performance Cr3+-doped Ca2GdGa3Ge2O12 near-infrared phosphors toward multifunctional applications5Ultrawideband Emission of Bi 3+ Ions Spanning Visible to Near‐Infrared Spectral Regions (400 nm–1700 nm)0Ultrawideband Emission of Bi 3+ Ions Spanning Visible to Near‐Infrared Spectral Regions (400 nm–1700 nm)12Efficient Near‐Infrared Emission from W 4+ in Cs 4 MnBi 2 Cl 12 Quadruple Perovskite via “Mn 2+ Energy Bridge”2Fabrication of injection‐molded phosphor‐in‐silica glass for high‐power far‐red LEDs0Advanced Fabrication of Phosphor-in-Silica Glass for Stable and High-Power LEDs4Visible‐Light‐Driven Nd 3+ Emission Enabled by a Garnet‐Based Cr 3+ ‐Doped Phosphor–Glass Composite for Broadband‐to‐NIR Spectral Conversion0Boosting broadband NIR luminescence in Mo4+-doped Cs2TeCl6 perovskite for toluene detection via cerium doping3Enhancing efficiency and tuning the emission band via energy transfer of Cr 3+ , Ce 3+ co-doped CaLu 2 Mg 2 Si 3 O 12 phosphors0Recent advances in Cr 3+ -doped near-infrared phosphors: preparation, luminescence, and LED applications5Simultaneous broadening and enhancement of Cr 3+ photoluminescence in Ba 3 ZrTa 4 O 15 by chemical unit co-substitution1Ultra-efficient energy transfer and near-infrared luminescence in hexagonal aluminate phosphors enabled by heterogeneous ion pair co-doping1Unlocking high absorption efficiency of Cr 3+ ions in magnesium titanates with intrinsically high octahedron distortion0Vacancy-mediated stabilization of Cr 3+ and near-infrared luminescence enhancement in Mg 2 GeO 4 via Zn 2+ incorporation0Sb 3+ ‐Doping Induced Quasi‐2D Single Crystal Growth from 0D Cs 3 BiCl 6 : Modulation of Site‐Specific Cr 3+ Near‐Infrared Emission1Crystal‐Field‐Driven Broadband‐to‐Narrowband Transition in Cr 3+ ‐Activated La 3 (Sc 1‐ x Al x ) 2 Ga 3 O 12 Garnet‐Perovskite Solid Solutions3Polyhedral Symmetry Breaking Strategy Enabled High‐Performance Broadband Near‐Infrared Emission in Cr 3+ ‐Doped Garnet Phosphors1High-precision and efficient nondestructive infrared thermal imaging detection and recognition of defect size and depth in GFRP composites based on BP neural network1Cr 3+ -Activated Mg 4 GaSbO 8 Orthorhombic Spinel-Derived Phosphors with Multisite Occupation for Tunable Broadband Near-Infrared Emission2Entropy‐Enabled Site Inversion and Defect Activation in Medium‐Entropy Spinels for Near‐Black Infrared Emission12Efficient Cr3+→Yb3+ energy transfer in Na3.25Mg5.375Si8O22F2:Cr3+,Yb3+ via a cation-substitution strategy for enhanced photoluminescence thermal stability0High-Output-Power Broadband Near-Infrared Phosphor Suitable for Various LED Applications5Origin of the Unusual Narrowband Near-Infrared Emission from Cr 3+ -Doped Oxides6Bridging the Gap Between NIR‐I and NIR‐II Bands via Efficient Cr 3+ →Ni 2+ Energy Transfer in Superstoichiometric MgO· n Ga 2 O 3 ( n > 1) Spinels2Structural Insights and Multi-center Luminescence in Cr 3+ -Doped Gallogermanate for High-Efficiency Near-Infrared pc-LEDs7Next‐Generation Short‐Wave Infrared LED Phosphors Based on Chromium Doped Rare Earth Sulfides5Cr 3+ -Activated Spinel Phosphors with Inhibited Cr(VI) Formation for Multiapplication via a Lattice Occupation Strategy0Anisotropic implantation damage build-up and crystal recovery in β-Ga2O30Temperature-dependent burst ultra-broadband continuous white light emission in lanthanide-based phosphors0Broadband‐Emitting NaGdSiO 4 :Eu 2+/3+ Phosphor for White Light‐Emitting Diodes0Vibronically Coupled Visible and Near‐Infrared Dual‐Band Emission From Te 4+ /Mo 4+ Emitters in Cs 2 HfCl 60Comparative study of broadband and narrowband near-infrared LEDs for optical wireless power transmission to implantable electronic devices across biological tissue0Mg2+ substitution triggering modulated emission for high-precision anti-counterfeiting applications0A Unified Photophysical Framework for Anomalous Cr‐Activated Near‐Infrared Emission in Oxide Hosts0Crystal‐Field‐Weakening Engineering Unlocks Ultra‐Efficient Eu 2+ Near‐Infrared Emission for Emerging Spectroscopic Applications1Crystal‐Field‐Weakening Engineering Unlocks Ultra‐Efficient Eu 2+ Near‐Infrared Emission for Emerging Spectroscopic Applications0Efficient and thermally stable Cr3+-doped pyrochlore NIR phosphors through chemical pressure engineering-induced crystal field strengthening0Boosting NIR Emissions and Thermal Resistance in Cr3+-Doped MgGa2O4 Semiconductor Microcrystals by Energy Transfer for Smart Detection0Disorder Engineering of Spinel Structure Synergistically Enhances Luminescence and Afterglow Emission of Mn 2+ for Multifunctional Optoelectronic Applications0Achieving High Quantum Efficiency in Fe 3+ ‐Doped Garnet for Multifunctional NIR Applications0Multiple Crystal‐Fields Engineering in Spinel Unlocks Efficient Broadband NIR Emission of Cr 3+0Concentration‐Driven Energy‐Bridge Synergistic Sensitized High‐Efficiency Rare‐Earth NIR Emitters Enable Colorful High‐Fidelity Hyperspectral Imaging0Ultra‐Broadband and Anti‐Thermal Quenching NIR Emission in ZnMgAl 10 O 17 :Cr 3+ via Cr 3+ Concentration Engineering0Upconversion Charging‐Induced Near‐Infrared Persistent Luminescence for Simultaneous Imaging and Temperature Sensing0Data-Driven Discovery of Broadband Cr3+ Phosphors Emitting in the Second Near-Infrared Window0Unraveling the Mystery of Near-Infrared Emission in an Antimony Halide Dimer Driven by the Jahn–Teller Effect0A low-threshold mechanoluminescence platform for broadband NIR emission and obstruction-penetrating optical communication0

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