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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Rational Pathways to Ordered Multianion Chalcogenides Using Retrosynthetic Crystal Chemistry

Ayat Tassanov, Huiju Lee, Yi Xia, James M. Hodges

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Rational Pathways to Ordered Multianion Chalcogenides Using Retrosynthetic Crystal ChemistryOriginalMixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl1Structural evolution and bonding features of electron deficient copper chalcogenides3Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method14Dimensional Evolution Guides Property Control in the A n Cu 4– n TiS 4 Semiconductor Series6Compositional Design Guides Property Control in A 2 M 2+ x Ti 1–( x /4) Q 4 Semiconductors6Homogeneous Luminescence Detection Based on Lanthanide Coordination Compound2Dimensional Reduction Guides Electronic Structure Evolution in the A n Cu 4– n SnS 4 Semiconductor Series8Preferential Site Ordering Alters the Magnetic Behavior of Sm3Ru4Sn13–xGex (x = 0–2)1Mixed-anion thermoelectrics: Advanced tuning of electron and phonon transport10A stoichiometrically conserved homologous series with infinite structural diversity2Reduced multiplicity of crystallographic sites for superior thermoelectric performance of cubic Cu 6 GeTeS 4 via chemical tailoring0Structure–Optical Property Relationships in AMM′Q 3 Chalcogenides0Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies0Solution Synthesis of Actinide Chalcogenide and Oxychalcogenide Nanoparticles0Solution Synthesis of Actinide Chalcogenide and Oxychalcogenide Nanoparticles0Beyond Familiar Phases: Discovering New Crystal Chemistry at the Nanoscale0

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  1. Mixed-anion chalcogenide-halide semiconductors A 2 BaTaS 4 Cl (A = K, Rb, Cs) and K 2 BaNbS 4 Cl

    Dalton Transactions · 2025-01-01

    Thomas S. Ie, Siddhartha S. Nathan, James M. Rondinelli, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  2. Structural evolution and bonding features of electron deficient copper chalcogenides

    CrystEngComm · 2025-01-01

    Sergei A. Novikov, James Casey, Hope A. Long, Vladislav V. Klepov

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  3. Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method

    Dalton Transactions · 2025-01-01

    Gopabandhu Panigrahi, Habiba Binte Kashem, Gregory W. Morrison, Hans‐Conrad zur Loye

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  4. Dimensional Evolution Guides Property Control in the A n Cu 4– n TiS 4 Semiconductor Series

    Journal of the American Chemical Society · 2025-06-13

    Michael A. Viti, Zhi Li, Zhifu Liu, Chris M. Wolverton, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  5. Compositional Design Guides Property Control in A 2 M 2+ x Ti 1–( x /4) Q 4 Semiconductors

    Journal of the American Chemical Society · 2025-07-11

    Michael A. Viti, Zhi Li, Craig C. Laing, Chris M. Wolverton, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  6. Homogeneous Luminescence Detection Based on Lanthanide Coordination Compound

    Analytical Chemistry · 2025-07-21

    Xin Tong, Zicheng Wang, Lina Zhao, Kai Wang, Yuxin Li

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  7. Dimensional Reduction Guides Electronic Structure Evolution in the A n Cu 4– n SnS 4 Semiconductor Series

    Journal of the American Chemical Society · 2025-08-07

    Michael A. Viti, Zhi Li, Chris M. Wolverton, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  8. Preferential Site Ordering Alters the Magnetic Behavior of Sm3Ru4Sn13–xGex (x = 0–2)

    Inorganic Chemistry · 2025-09-24

    Jacob W. Fritsky, Hui‐Fei Zhai, Yi‐Feng Zhao, Aryan Rauniyar, Antía S. Botana, Jason F. Khoury

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  9. Mixed-anion thermoelectrics: Advanced tuning of electron and phonon transport

    Applied Physics Reviews · 2025-11-18

    Takayoshi Katase, Naoki Sato, Takao Mori

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  10. A stoichiometrically conserved homologous series with infinite structural diversity

    Science · 2025-12-04

    Hengdi Zhao, Xiuquan Zhou, Ziliang Wang, Patricia E. Meza, Yihao Wang, Denis T. Keane, Steven L. Weigand, Saul H. Lapidus, Duck Young Chung, Chris M. Wolverton, Vinayak P. Dravid, Stephan Rosenkranz, Mercouri G. Kanatzidis

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  11. Reduced multiplicity of crystallographic sites for superior thermoelectric performance of cubic Cu 6 GeTeS 4 via chemical tailoring

    Science Advances · 2026-03-13

    Ya Yang, Ying Zhang, Z. Chen, Pengju Han, Shuailiang Chen, Chong Hua, Yunpeng Zheng, Hongwei Ming, Naifeng Zhuang, Zhong‐Zhen Luo, Zhigang Zou

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  12. Structure–Optical Property Relationships in AMM′Q 3 Chalcogenides

    Chemistry of Materials · 2026-06-10

    Ayat Tassanov, Huiju Lee, Daniel W. Spainhour, Yi Xia, James M. Hodges

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  13. Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies

    Inorganic Chemistry · 2026-06-30

    Gopabandhu Panigrahi, Rachita Panigrahi, P. S. S. Dabare, Hope Eden Catalano, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  14. Solution Synthesis of Actinide Chalcogenide and Oxychalcogenide Nanoparticles

    Angewandte Chemie · 2026-06-30

    Cheyenne Orozco, Orlando Stewart, Nicole A. Vanagas, Gregory W. Morrison, Hans‐Conrad zur Loye, Hope E. Smith, Karah E. Knope, Sarah L. Stoll

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  15. Solution Synthesis of Actinide Chalcogenide and Oxychalcogenide Nanoparticles

    Angewandte Chemie International Edition · 2026-06-30

    Cheyenne Orozco, Orlando Stewart, Nicole A. Vanagas, Gregory W. Morrison, Hans‐Conrad zur Loye, Hope E. Smith, Karah E. Knope, Sarah L. Stoll

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  16. Beyond Familiar Phases: Discovering New Crystal Chemistry at the Nanoscale

    Chemistry of Materials · 2026-08-18

    Rahul Ramachandran Manikkoth, Julie L. Fenton

    Read original paper ↗ ·
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