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RESEARCH PAPER · Advanced Materials · 2024

Air and Thermally Stable Fluoride Bridged Rare‐Earth Clusters Showing Intense Photoluminescence and Potential LED Application

Jianyue He, Yu Wang, Xi Chen, Wei‐Peng Chen, Guijiang Zhou, Yan‐Zhen Zheng

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Air and Thermally Stable Fluoride Bridged Rare‐Earth Clusters Showing Intense Photoluminescence and Potential LED ApplicationOriginalPentacosaple-CO 3 2− bridged hexacontaoctanuclear lanthanide-alkali barrels derived from octacosanuclear discs1Suppression of Photoexcited Small Polarons-Mediated Energy Transfer to Boost Photoluminescence of Lanthanide–Titanium Nanoclusters12Phosphonate Lanthanide Carbonate Cages: Remarkably Aggregated Lanthanide-Oxo Cores with Removable Cation Templates1Iminodiacetic acid stabilized 3d-4f clusters: Synthesis, structure, and magnetism14Electrically Modulated Fluorescence in Single Rare-Earth Particles2Multicolor Rare‐Earth Film with Ultra‐Long Afterglow for Diverse Energy‐Saving Applications38Organic–Inorganic Hybrid Rare Earth Halide Glasses for Tunable Multicolor X‐ray Scintillation10Organic–Inorganic Hybrid Rare Earth Halide Glasses for Tunable Multicolor X‐ray Scintillation66On-Crystal Optical Modulator from Polarized Propagation of Lanthanide-Titanium Nanoclusters0Multifunctional lanthanide(III) single-molecule magnets displaying luminescence thermometry: Progress, challenges, and future directions16Electrospray Ionization Mass Spectrometry Insights into the Assembly of Lanthanide-Containing Clusters9Coordination clusters as emerging magnetic resonance imaging contrast agents7Ligand rigidity-mediated coordination symmetry engineering in lanthanide-titanium nanoclusters achieves >90% photoluminescence quantum yield15Ligand Engineering Enhances Fluorescence Properties of Eu‐Based Complexes for Efficiency Enhancement and UV Stability in Silicon Heterojunction Solar Cells3Ligand Engineering in Lanthanide‐Titanium‐Oxo Clusters: Preventing Charge Transfer to Ti IV for High‐Efficiency Emission1Temperature‐Inert Terbium Cluster Scintillator19Machine Learning Guided Assembly of a Nested Gd 20 @Gd 32 @Ni 36 Cluster via Urea Controlled Carbonate Release7Machine Learning Guided Assembly of a Nested Gd 20 @Gd 32 @Ni 36 Cluster via Urea Controlled Carbonate Release0Dynamic chiral Eu(III) complex emitters with molecular rotor‐regulated aggregation‐enhanced antenna effects for high‐resolution bioimaging7Applications of Inorganic Hybrid Rare‐Earth Materials in Biological Diagnostics, X‐Ray Imaging, and Lighting Display3Over 99% Photoluminescence Quantum Yield by Kernel Regulation in 8-Hydroxyquinoline-Based Icosahedral Sn12-Oxo Cluster7Stiboviologens-Decorated Sb 4 O 6 Clusters for Electrocatalytic Proton Reduction via Coupled Electron Sponge and Proton Engine4Europium-mediated fluorescence engineering for organic dyes to improve efficiency and ultraviolet stability of silicon heterojunction solar cells0On-Crystal Spectral Modulator from Polarized Propagation of Lanthanide-Titanium Nanoclusters1Multinuclear Ce III –P III –W VI Cluster-Incorporated Phospho(III)tungstate Utilized in a Chip-Based Sensor for the Selective Detection of MicroRNA-212Dual‐mode reversible photoluminescence tuning in rare‐earth doped scheelite thin films via mechanical strain1Preparation and photoluminescence of high-monochromaticity green-emitting Ca9Tb(PO4)5(SiO4)F2:Ce3+ phosphor with high quantum efficiency and excellent thermal stability for WLEDs application1Multi‐Ion Doping in Low‐Phonon‐Energy Nd 3+ Based Double Perovskite Unlocks Multimodal Anti‐Counterfeiting and High‐Performance Optical Thermometry15Divalent europium formamidinates: synthesis, structures, EPR and luminescence properties0Harnessing rare earth coordination chemistry for advanced photofunctional materials: from fundamental principles to emerging technologies20Reversible symmetry breaking and restoration in metal nanoclusters0Woven lanthanide metal–organic frameworks constructed from aggregation-induced emission luminogens and their photoresponsive VOCs0Emerging trends in rare-earth doped luminescent nanophosphors: Synthesis, advances and applications3An Antipolarity Luminescence Enhancement in Dy/Eu@Gd-MOFs Induced by Isomeric Solvents1Pyrazole‐Protected Heteronuclear Rare‐Earth Boron‐Oxo Cluster Cage With Tunable Luminescence0Suppressing concentration quenching in Eu3+/Tb3+-doped phosphates via site-self-limiting crystal structures2Highly luminescent rare-earth supramolecular glasses via a fluorine-synergized antenna effect0Advances and perspectives in the assembly and performance regulation of luminescent rare earth complexes10Prefabricated Cluster Strategy for the Facile Synthesis of Fluoro-Bridged UiO-66 Analogues1Visual, On-Site, and Accurate Detection of Aspirin Based on a 1-D Cd 6 Tb 4 -Containing Coordination Polymer0Tm 3+ ‐Sensitized Thermal Enhancement of Visible and NIR‐II Luminescence via Phonon‐Tuning in Cs 2 NaTmCl 6 Double Perovskite Nanocrystals for Advanced Ratiometric Thermometry and High‐Security Optical Encryption0Chiral Ln4 clusters featuring circularly polarized luminescence and ferromagnetic single-molecule magnetism0Cations Functionalized Lanthanide Metal–Organic Frameworks: Tunable Luminescence, Upconversion Luminescence, and Efficient Reactive Oxygen Species Storm Generation for Photodynamic Antibacterial Applications0Regulating the Arrangement of Planar Ligands in Lanthanide Metal–Organic Framework Photosensitizers to Induce a Photocatalytic Reactive Oxygen Species Storm for Sewage Purification and Photodynamic Sterilization1

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  1. Pentacosaple-CO 3 2− bridged hexacontaoctanuclear lanthanide-alkali barrels derived from octacosanuclear discs

    Inorganic Chemistry Frontiers · 2025-01-01

    Chaolun Wei, Yi Liu, Xiaojuan Li, Haoyu Liu, Hai‐Ye Li, Hou‐Ting Liu, Haiquan Tian

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  2. Suppression of Photoexcited Small Polarons-Mediated Energy Transfer to Boost Photoluminescence of Lanthanide–Titanium Nanoclusters

    Nano Letters · 2025-01-08

    Feng Jiang, Shengrong He, Yuan Ji, Jun Li Yin, Cong Yan, Weinan Dong, Xin Li, Yù Zhang, Zhennan Wu, Xue Bai

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  3. Phosphonate Lanthanide Carbonate Cages: Remarkably Aggregated Lanthanide-Oxo Cores with Removable Cation Templates

    Crystal Growth & Design · 2025-02-24

    Chaolun Wei, Xiaojuan Li, Yi Liu, Hai‐Ye Li, Hou‐Ting Liu, Haiquan Tian

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  4. Iminodiacetic acid stabilized 3d-4f clusters: Synthesis, structure, and magnetism

    Coordination Chemistry Reviews · 2025-03-05

    Ming‐Qiang Qi, Hongtai Zhang, Xin-Ya Diao, Xiang‐Jian Kong, La‐Sheng Long, Lan‐Sun Zheng

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  5. Electrically Modulated Fluorescence in Single Rare-Earth Particles

    The Journal of Physical Chemistry Letters · 2025-03-20

    Wenjing Duan, Yibo Yang, Jianyue He, Shiyang Lyu, Yuang Chen, Wenxin Zhu, Shaokun Ling, Chen Zhang, Yan‐Zhen Zheng, Jiandong Feng

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  6. Multicolor Rare‐Earth Film with Ultra‐Long Afterglow for Diverse Energy‐Saving Applications

    Advanced Materials · 2025-03-20

    Xinyi Lin, Huixuan Han, Meifang Yang, Zongxuan Yuan, Zihao Chen, Wenguang Li, Hui Dong Kang, Songtao Zhang, Yizhou Zhang, Yuxin Chen, Tian Tian, Huan Pang

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  7. Organic–Inorganic Hybrid Rare Earth Halide Glasses for Tunable Multicolor X‐ray Scintillation

    Angewandte Chemie · 2025-04-07

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  8. Organic–Inorganic Hybrid Rare Earth Halide Glasses for Tunable Multicolor X‐ray Scintillation

    Angewandte Chemie International Edition · 2025-04-07

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  9. On-Crystal Optical Modulator from Polarized Propagation of Lanthanide-Titanium Nanoclusters

    Research Square · 2025-04-11

    Zhennan Wu, Feng Jiang, Lei Qin, Qi Sun, Shengrong He, Weinan Dong, Haifeng Zhu, Lingchen Meng, Peng Xu, Wenming Tian, Yuan Ji, Yù Zhang, Xue Bai

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  10. Multifunctional lanthanide(III) single-molecule magnets displaying luminescence thermometry: Progress, challenges, and future directions

    Coordination Chemistry Reviews · 2025-04-15

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  11. Electrospray Ionization Mass Spectrometry Insights into the Assembly of Lanthanide-Containing Clusters

    Accounts of Chemical Research · 2025-04-29

    Ming‐Qiang Qi, Ming‐Hao Du, Xiang‐Jian Kong, La‐Sheng Long, Lan‐Sun Zheng

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  12. Coordination clusters as emerging magnetic resonance imaging contrast agents

    Magnetic Medicine · 2025-05-22

    Yu Wang, Zheng Yan-Zhen

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  13. Ligand rigidity-mediated coordination symmetry engineering in lanthanide-titanium nanoclusters achieves >90% photoluminescence quantum yield

    Journal of Rare Earths · 2025-06-10

    Xinran Yan, Ming Zhao, Feng Jiang, Haifeng Zhu, Weinan Dong, Shengrong He, Jingjing Xia, Meixin Hong, Zhennan Wu, Xue Bai

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  14. Ligand Engineering Enhances Fluorescence Properties of Eu‐Based Complexes for Efficiency Enhancement and UV Stability in Silicon Heterojunction Solar Cells

    Advanced Optical Materials · 2025-06-30

    S.L. Zhang, Shuai Zou, Zheng Lu, Hao Huang, Yueqian Zhen, Yu Xiao, Xiaodong Su

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  15. Ligand Engineering in Lanthanide‐Titanium‐Oxo Clusters: Preventing Charge Transfer to Ti IV for High‐Efficiency Emission

    Small · 2025-07-14

    Weidong Liu, Si‐Wei Ying, Zi‐Jing She, Han Xu, Mingxuan Zhang, La‐Sheng Long, Lan‐Sun Zheng, Xiang‐Jian Kong

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  16. Temperature‐Inert Terbium Cluster Scintillator

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  17. Machine Learning Guided Assembly of a Nested Gd 20 @Gd 32 @Ni 36 Cluster via Urea Controlled Carbonate Release

    Angewandte Chemie International Edition · 2025-09-02

    Ming‐Qiang Qi, Rui‐Le Yang, Jianyu Wu, Jianan Chen, Yue‐Bo Qi, Xin‐Ya Diao, Ming‐Hao Du, Yibin Jiang, Cheng Wang, La‐Sheng Long, Lan‐Sun Zheng, Xiang‐Jian Kong

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  18. Machine Learning Guided Assembly of a Nested Gd 20 @Gd 32 @Ni 36 Cluster via Urea Controlled Carbonate Release

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  19. Dynamic chiral Eu(III) complex emitters with molecular rotor‐regulated aggregation‐enhanced antenna effects for high‐resolution bioimaging

    Rare Metals · 2025-09-12

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  20. Applications of Inorganic Hybrid Rare‐Earth Materials in Biological Diagnostics, X‐Ray Imaging, and Lighting Display

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  21. Over 99% Photoluminescence Quantum Yield by Kernel Regulation in 8-Hydroxyquinoline-Based Icosahedral Sn12-Oxo Cluster

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  22. Stiboviologens-Decorated Sb 4 O 6 Clusters for Electrocatalytic Proton Reduction via Coupled Electron Sponge and Proton Engine

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  23. Europium-mediated fluorescence engineering for organic dyes to improve efficiency and ultraviolet stability of silicon heterojunction solar cells

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  24. On-Crystal Spectral Modulator from Polarized Propagation of Lanthanide-Titanium Nanoclusters

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  25. Multinuclear Ce III –P III –W VI Cluster-Incorporated Phospho(III)tungstate Utilized in a Chip-Based Sensor for the Selective Detection of MicroRNA-21

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  26. Dual‐mode reversible photoluminescence tuning in rare‐earth doped scheelite thin films via mechanical strain

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  27. Preparation and photoluminescence of high-monochromaticity green-emitting Ca9Tb(PO4)5(SiO4)F2:Ce3+ phosphor with high quantum efficiency and excellent thermal stability for WLEDs application

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  28. Multi‐Ion Doping in Low‐Phonon‐Energy Nd 3+ Based Double Perovskite Unlocks Multimodal Anti‐Counterfeiting and High‐Performance Optical Thermometry

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  29. Divalent europium formamidinates: synthesis, structures, EPR and luminescence properties

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  30. Harnessing rare earth coordination chemistry for advanced photofunctional materials: from fundamental principles to emerging technologies

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  31. Reversible symmetry breaking and restoration in metal nanoclusters

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  32. Woven lanthanide metal–organic frameworks constructed from aggregation-induced emission luminogens and their photoresponsive VOCs

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  33. Emerging trends in rare-earth doped luminescent nanophosphors: Synthesis, advances and applications

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  34. An Antipolarity Luminescence Enhancement in Dy/Eu@Gd-MOFs Induced by Isomeric Solvents

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  35. Pyrazole‐Protected Heteronuclear Rare‐Earth Boron‐Oxo Cluster Cage With Tunable Luminescence

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  36. Suppressing concentration quenching in Eu3+/Tb3+-doped phosphates via site-self-limiting crystal structures

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  37. Highly luminescent rare-earth supramolecular glasses via a fluorine-synergized antenna effect

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  39. Prefabricated Cluster Strategy for the Facile Synthesis of Fluoro-Bridged UiO-66 Analogues

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  40. Visual, On-Site, and Accurate Detection of Aspirin Based on a 1-D Cd 6 Tb 4 -Containing Coordination Polymer

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  41. Tm 3+ ‐Sensitized Thermal Enhancement of Visible and NIR‐II Luminescence via Phonon‐Tuning in Cs 2 NaTmCl 6 Double Perovskite Nanocrystals for Advanced Ratiometric Thermometry and High‐Security Optical Encryption

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  42. Chiral Ln4 clusters featuring circularly polarized luminescence and ferromagnetic single-molecule magnetism

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  44. Regulating the Arrangement of Planar Ligands in Lanthanide Metal–Organic Framework Photosensitizers to Induce a Photocatalytic Reactive Oxygen Species Storm for Sewage Purification and Photodynamic Sterilization

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