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RESEARCH PAPER · Journal of Materials Chemistry A · 2024

Boosting the efficiency of electrocatalytic water splitting via in situ grown transition metal sulfides: a review

Haowei Jia, Linghui Meng, Yile Lu, Tianyue Liang, Yu Ying Yuan, Yifan Hu, Zekun Dong, Yingze Zhou, Peiyuan Guan, Lu Zhou, Chao Liu, Mengyao Li, Tao Wan, Bing‐Jie Ni, Zhaojun Han, Dewei Chu

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Boosting the efficiency of electrocatalytic water splitting via in situ grown transition metal sulfides: a reviewOriginalOne-dimensional multilevel stalactite-like Ni3S2-Fe(Mo2S4) bifunctional electrocatalyst with excellent oxygen evolution reaction and overall water splitting performance32A biomass derived jute carbon integrated FeCoNi alloy as a robust catalyst for alkaline water splitting11A crystalline–amorphous Co 9 S 8 /CoOOH heterostructure enables efficient and stable SOR-coupled hydrogen evolution5Highly efficient hydrogen evolution with silicon nanowire photocathodes: hierarchical triple-junction and a-MoS x catalysts achieving ABPE > 4.6%6Strategically improving the oxygen evolution reaction performance of ZnCo 2 S 4 nanoflakes: role-specific redox-additive electrolytes0Temperature-driven phase engineering: synergistic effect between NiS 2 and MoS 2 coupled with N-doped graphene self-supported on carbon cloth for efficient electrocatalytic seawater splitting7Three birds with one stone: Ni–MoN nano-heterostructures encapsulated in NCNTs for efficient hydrogen production via overall water splitting and urea electrolysis3Structural, Morphological and Charge Transport Properties of FeS2 Nanostructures4Orientation-Dependent Oxygen Evolution Catalytic Performance and Mechanistic Insights of Epitaxial Co9S8 Thin Films4Catalyst design for efficient water splitting: A comprehensive review of challenges and opportunities39Earth-Abundant W 18 O 49 Coupled with Minimal Pt for Enhanced Hydrogen Evolution under Dark and Visible Light Conditions7Sustainable Carbon‐Based Catalyst Materials Derived From Lignocellulosic Biomass for Energy Storage and Conversion: Atomic Modulation and Properties Improvement108(NiFe)2P nanoflowers decorated on 3D Ni5P4-Ni2P skeleton as self-supported electrocatalyst for efficient overall water splitting3Dual-functional hierarchical NiFe hydroxylphosphate electrocatalyst on copper dendrites for hydrogen and oxygen evolution66Recent Progress in the Synthesis and Engineering of High-Performance MoS2 Electrocatalysts for the Hydrogen Evolution Reaction10Custom exposed crystal facets: Synergistic effect of optimum crystal facet anisotropy and Ohmic heterojunction boosting photocatalytic hydrogen evolution123Dual-phased nickel sulfide heterojunction of Ni9S8/Ni3S2 doped with Co assembled on Ni foam as a highly efficient electrocatalyst for alkaline oxygen evolution reaction24Synthesis of 1T/2H-MoS2 nanosheets on dome-shaped CoS2 particles embedded in carbon nanofibers as free-standing electrodes for alkaline water splitting6Construction of Co9S8/CoO/NC/CP with heterogeneous interfaces to boost oxygen evolution for overall water splitting1Bi-metallic phosphate: Active and stable bifunctional electrocatalysts for alkaline overall water splitting7In situ synthesis of NiP-MoP heterogeneous micro-nanorods on nickel foam as bifunctional electrodes for overall water splitting5Construction of CoS2/NiS@NCNTs heterojunction for enhanced oxygen evolution reaction2Can Ferrocene‐Bridged Metal–Organic Frameworks Serve as Water‐Splitting Catalysts? A Comment on Ni/Co Ferrocene Polymers and Their Structural Stability3Sulfur Vacancy and V-Doped CoP-Modulated 3D Zr-MOF (UiO-66-NH2)/2D MoS2 Interface Restructuring for Efficient and Durable Hydrogen Evolution Reaction6Exploration of multiscale design strategies of electrocatalysts for efficient electrochemical hydrogen and oxygen evolution reactions10The Material Growth and Characteristics of Transition Metal Oxide Thin Films Based on Hot Wire Oxidation Sublimation Deposition Technology1Tuning the composition and morphology of nickel-iron sulfide for efficient methanol oxidation: Role of iron incorporation in catalytic enhancement3Ru-activated and stabilized high-entropy sulfides for improving electrocatalytic oxygen evolution reaction performance6Engineering 3D Heterostructured NiCo2S4/Co9S8-CNFs via Electrospinning and Hydrothermal Strategies for Efficient Bifunctional Energy Conversion5Inserting fluorine-salicylic acid into nonstoichiometric Ni0.96S for methanol oxidation reaction0Modulation strategy of 1T-MoS2 catalyst and its application in electrocatalytic hydrogen evolution reaction: A literature review5Smartphone‐Assisted Wireless Ultrasensitive Nitrite Detection in Food Samples via Hierarchical MXene/NiCoMn‐LDH/Sulfide Heterostructure on Flexible Laser‐Induced Graphene Electrode5Strategies for improving oxygen evolution performance of MOF nanoarrays1Simulation and Optimization of Hydrogen‐Enriched Shaft Furnace18In situ grown Co3O4@MnO2 on sulfurized Ni foam as a bifunctional catalyst for overall water splitting4Transparent Electrodes Composed of Organized Titania Nanotubes and Transition Metal Sulfides for the Oxygen Evolution Reaction6Green synthesis of MnVS and Co@MnVS nanoparticles: Applications in photocatalysis and hydrogen production via methanolysis2Emerging SrFe-MOF/Fe-BTC hybrids via post-synthetic induced Fe3+ metal node exchange and nucleation for durable bifunctional electrocatalysis9Recent Advances in Biomimetic Electrocatalysts for Water Splitting: Emerging Trends and Outlook5A hierarchical Ru nanoparticle-decorated MoS 2 @Ni-MOF for highly efficient overall water splitting1Activation-induced surface reconstruction enables enhanced pseudocapacitive charge storage and industrial-current hydrogen evolution in tetra-metallic sulfide nanoflowers0Electronic structure modulation of a CoN/TiC–C nanoarray by vanadium doping for enhanced alkaline oxygen evolution1Interfacial reconstruction in MoS 2 -CuNi@MoS 2 core–shell electrocatalysts for chloride-resistant alkaline seawater electrolysis0Nanohybrids of Ti 3 C 2 T x MXene with Ni-based structures: enabling high-performance electrocatalysts for water splitting1Nanostructured transition metal electrocatalysts on nickel foam: design and performance for the alkaline OER2Polyaniline-supported Ag 2 O/Mn 2 O 3 nanostructures on nickel foam for efficient bifunctional water splitting electrocatalysis5Regulation of the interfacial water structure and electronic structure of nickel-cobalt sulfide nanotubes via phosphorus incorporation for efficient hydrogen production coupled with sulfion upgradation0Self-supporting Fe,Co co-doped Ni 3 S 2 nanosheet arrays as advanced bifunctional electrocatalysts for alkaline seawater splitting2Controlled synthesis of sulfurization-assisted MnSeO3/S electrocatalyst for OER and HER in an alkaline medium3Recent advances in Ce-containing Ni, Fe, and Co catalysts for water/seawater electrolysis10Binder-free stabilization of transient Co(OH)2 active phases on conductive nanoparticles for durable and kinetically accelerated electrocatalytic oxygen evolution2Synthesis of 3D Co9S8/GNRs/Ti3C2T –MXene ternary composite toward enhanced oxygen evolution reaction2Interfacial synergy between Ru³ ⁺-doped NiOOH lattice and surface Ru nanoparticles: Unveiling hydrogen spillover pathways for high current density alkaline hydrogen evolution reaction3Heterostructured cobalt sulfides in N, S dual-doped hollow carbon spheres for high-performance rechargeable liquid and flexible Zn-air batteries2Influence of Thiourea Concentration on the Hydrothermal Synthesis of Nickel Sulfide Electrocatalyst0Advances in transition metal sulfides: Synthesis, properties, and modification strategies for electrocatalysis and energy conversion applications21Hierarchical assembly of NiMo3S13/MoS2/Ni3S2 in situ grown on nickel foam: Building a highly active and durable hydrogen-evolution electrocatalyst with Mo–S–Ni bridging sites4Preparation and Electrocatalytic Hydrogen Evolution Performance of CoS2:Mo Microrods1Transition metal sulfides/selenides as cathode electrocatalysts for enhanced hydrogen evolution: Nanostructure engineering strategies and recent progress4Oxidation treatment enhanced synergistic effect in NiCoFeP as a dual-functional electrocatalyst for efficient overall water splitting0Lattice distortion and built-in electric field induced by Fe&Mn doping in NiSe2(Fe)/NiFeMn heterostructure for high-performance overall water splitting5Self-supported MoS2/Fe-Ni3S2 heterostructures on Ni foam derived from Mo-doped NiFe-LDH for bifunctional HER/OER electrocatalysis6Polyoxometalate-Derived NiS-MoS2 and FeS-MoS2 Heterostructures Decorated on Reduced Graphene Oxide for Efficient Overall Water Splitting2Scalable electrodeposition of NiMoP for alkaline hydrogen production: From catalyst design to full-cell performance7Hierarchical porous carbon confined Cr2ZnS4 nanosheets as an efficient electrocatalyst for electrocatalytic nitrogen reduction0Controlled Urothermal Synthesis of NH 4 Fe 2 S 3 : An Electrocatalyst for the Oxygen Evolution Reaction0Multi-step interface assembly strategy for constructing NCF@MXene@1T/2H MoS 2 composite nanofibers0Iron and nitrogen co-doped CuO nanotubes for accelerated and stable alkaline seawater splitting via electronic structure engineering0Insights into surface reconstruction of FeMoS and FeS precatalysts and their active site in the overall water splitting reaction3Synergistic Active Sites in a Defect-Engineered FeMoO4/CeS2 Diphase for Highly Efficient Ambient Electrocatalytic Ammonia Synthesis1Fluoride-programmed surface reconstruction of monoclinic SrIrO3 nanosheets for efficient acidic oxygen evolution0Kinetics of oxygen evolution: An intrinsic limitation of metal-air batteries or a surmountable technical barrier?0MnCo2S4 nanozymes with dual enzyme-mimicking activities for catalytic degradation and optical monitoring of organic pollutants0Rice-grain like CoS nanostructures decorated on carbon cloth via in-situ solvothermal method for electrocatalytic hydrogen evolution reaction0Transition metal sulfides for seawater electrolysis: Challenges, advances, and engineering strategies for enhanced hydrogen production1Microenvironment mediated laser synthesis of transition-metal-compound nanoparticles in air0Interface-engineered CoMo-MOF@gCN heterostructure for enhanced bifunctional electrocatalyst in alkaline medium0Superwetting interface engineering for electrocatalytic water splitting: Construction strategies and mass-transfer mechanisms of nickel foam-based self-supported electrodes0Recent Progress of Biomass‐Derived Nitrogen‐Doped Carbon Materials as Electrocatalysts: Carbonization, Functionalization, and Applications0Superwetting sulfide-based self-supported electrodes for water electrolysis and coupled hydrogen production: Cross-scale wettability engineering and bubble-mediated mass transfer0

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  1. One-dimensional multilevel stalactite-like Ni3S2-Fe(Mo2S4) bifunctional electrocatalyst with excellent oxygen evolution reaction and overall water splitting performance

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  2. A biomass derived jute carbon integrated FeCoNi alloy as a robust catalyst for alkaline water splitting

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  3. A crystalline–amorphous Co 9 S 8 /CoOOH heterostructure enables efficient and stable SOR-coupled hydrogen evolution

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  4. Highly efficient hydrogen evolution with silicon nanowire photocathodes: hierarchical triple-junction and a-MoS x catalysts achieving ABPE > 4.6%

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  5. Strategically improving the oxygen evolution reaction performance of ZnCo 2 S 4 nanoflakes: role-specific redox-additive electrolytes

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  6. Temperature-driven phase engineering: synergistic effect between NiS 2 and MoS 2 coupled with N-doped graphene self-supported on carbon cloth for efficient electrocatalytic seawater splitting

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  16. Custom exposed crystal facets: Synergistic effect of optimum crystal facet anisotropy and Ohmic heterojunction boosting photocatalytic hydrogen evolution

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  17. Dual-phased nickel sulfide heterojunction of Ni9S8/Ni3S2 doped with Co assembled on Ni foam as a highly efficient electrocatalyst for alkaline oxygen evolution reaction

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  18. Synthesis of 1T/2H-MoS2 nanosheets on dome-shaped CoS2 particles embedded in carbon nanofibers as free-standing electrodes for alkaline water splitting

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  47. Regulation of the interfacial water structure and electronic structure of nickel-cobalt sulfide nanotubes via phosphorus incorporation for efficient hydrogen production coupled with sulfion upgradation

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  48. Self-supporting Fe,Co co-doped Ni 3 S 2 nanosheet arrays as advanced bifunctional electrocatalysts for alkaline seawater splitting

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  49. Controlled synthesis of sulfurization-assisted MnSeO3/S electrocatalyst for OER and HER in an alkaline medium

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    Hamna Arooj, Tauseef Munawar, Ambreen Bashir, Mostafa A. Ismail, Abdul Waheed Rabbani, Muhammad Rafaqat, Faisal Mukhtar, Muhammad Sufyan Naeem, Faisal Iqbal, Suleyman I. Allakhverdiev

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  50. Recent advances in Ce-containing Ni, Fe, and Co catalysts for water/seawater electrolysis

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