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RESEARCH PAPER · Chemistry of Materials · 2024

Tuning the Optical Absorption Edge of Vacancy-Ordered Double Perovskites through Metal Precursor and Solvent Selection

Alexandra Brumberg, Owen Kuklinski, Greggory T. Kent, Emily E. Morgan, Alexander A. Mikhailovsky, T. Amanda Strom, Michael L. Chabinyc, Ram Seshadri

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Tuning the Optical Absorption Edge of Vacancy-Ordered Double Perovskites through Metal Precursor and Solvent SelectionOriginalTwo-step spin-coating of vacancy-ordered double perovskites enables growth of thin films for electronic devices1Structural transition and emission enhancement in vacancy-ordered halide double perovskite Cs2TeCl6 under pressure5Visible Light Active Natural Rutile Photocatalyst Obtained via Nano Milling0Design Principles for Narrow-Gap Hybrid Semiconductors: Insights from Viologen-Tin and Viologen-Lead Iodides6Pressure-induced electronic transition in vacancy-ordered halide double perovskite Cs2TeBr63Mapping the structure-property relationships in Cs2SnI6 to decipher its true air-stability via precursor engineering2Phase Separation and Optical Absorption Signature in Mixed-Cation Halide Perovskite Films Processed under Ambient-Air Condition0Re 4+ -mediated multi-exciton energy transfer enables super-broadband multiphoton excited luminescence for diversified photonic applications0A high theoretical solar cell efficiency prediction of 33.25% in Na2SnI6: A promising material for photovoltaic and optoelectronic applications0A hybrid film material based on 5,10,15,20-tetrakis(4-hydroxyphenyl)palladium porphyrinate and phenol: Electrochemical formation and characterization0Unveiling the tuning effects of atomic components on geometric and electronic structures of non-magnetic supramolecular perovskites (18C6@a)2MX60Strain-enhanced thermoelectric performance in vacancy-ordered Rb2SeCl6 enabled by lattice softening and suppressed phonon transport0Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles1

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  1. Two-step spin-coating of vacancy-ordered double perovskites enables growth of thin films for electronic devices

    Journal of Materials Chemistry C · 2025-01-01

    Owen Kuklinski, Alexandra Brumberg, Linjing Tang, Anya S. Mulligan, Tim Kodalle, Carolin M. Sutter‐Fella, Ram Seshadri, Michael L. Chabinyc

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  2. Structural transition and emission enhancement in vacancy-ordered halide double perovskite Cs2TeCl6 under pressure

    Applied Physics Letters · 2025-04-01

    Suvashree Mukherjee, Debabrata Samanta, Bidisha Mukherjee, Konstantin V. Glazyrin, Goutam Dev Mukherjee

    Read original paper ↗ ·

  3. Visible Light Active Natural Rutile Photocatalyst Obtained via Nano Milling

    Molecules · 2025-04-03

    Kata Saszet, Enikő Eszter Almási, Ádám Rácz, Katalin Bohács, Milica Todea, Klára Hernádi, Zsolt Pap, Lucian Baia

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  4. Design Principles for Narrow-Gap Hybrid Semiconductors: Insights from Viologen-Tin and Viologen-Lead Iodides

    Journal of the American Chemical Society · 2025-07-07

    Robert P. Reynolds, Jessica H. Persaud, George Volonakis, Andrew J. Torma, Patricia E. Meza, Zek E. Kelly, Constantinos C. Stoumpos, Vinayak P. Dravid, Claudine Katan, Aditya D. Mohite, Mercouri G. Kanatzidis

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  5. Pressure-induced electronic transition in vacancy-ordered halide double perovskite Cs2TeBr6

    Journal of Applied Physics · 2025-07-16

    Debabrata Samanta, Suvashree Mukherjee, Asish Kumar Mishra, Bhagyashri Giri, Sonu Pratap Chaudhary, Konstantin V. Glazyrin, Sayan Bhattacharyya, Goutam Dev Mukherjee

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  6. Mapping the structure-property relationships in Cs2SnI6 to decipher its true air-stability via precursor engineering

    Surfaces and Interfaces · 2025-08-06

    Abhirami Eattath Anil Kumar, Shantikumar Vasudevan Nair, Laxman Raju Thoutam

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  7. Phase Separation and Optical Absorption Signature in Mixed-Cation Halide Perovskite Films Processed under Ambient-Air Condition

    SSRN Electronic Journal · 2026-01-01

    Malik Anjelh Baqiya, Farras Athala Fauzan, Wahyu Satria Nusantara, Rika Jaya Kusuma Wardani, Dewi Sugiarti, Adhelia Benny Nugraha, Yoyok Cahyono, Rindang Fajarin, Edi Suharyadi, Sunaryono Sunaryono, Darminto Darminto

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  8. Re 4+ -mediated multi-exciton energy transfer enables super-broadband multiphoton excited luminescence for diversified photonic applications

    Inorganic Chemistry Frontiers · 2026-01-01

    Yu Zha, Fangxue Chen, Sailian Yan, Fanju Meng, Qianjin Zhang, Jin Han, Yugeng Wen, Jianbei Qiu

    Read original paper ↗ ·

  9. A high theoretical solar cell efficiency prediction of 33.25% in Na2SnI6: A promising material for photovoltaic and optoelectronic applications

    Surfaces and Interfaces · 2026-05-06

    Muhammad Bin Javed, Hafiz Tauqeer Ali, Safdar Nazir

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  10. A hybrid film material based on 5,10,15,20-tetrakis(4-hydroxyphenyl)palladium porphyrinate and phenol: Electrochemical formation and characterization

    Electrochimica Acta · 2026-05-20

    Sergey Mikhailovich Kuzmin, Svetlana Albertovna Chulovskaya, Vladimir Ivanovich Parfenyuk

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  11. Unveiling the tuning effects of atomic components on geometric and electronic structures of non-magnetic supramolecular perovskites (18C6@a)2MX6

    Computational and Theoretical Chemistry · 2026-06-11

    Zhuolei Zhang, Yiman Guo, Ni Luan, Yaxing Wang, Xing Dai

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  12. Strain-enhanced thermoelectric performance in vacancy-ordered Rb2SeCl6 enabled by lattice softening and suppressed phonon transport

    Computational Materials Science · 2026-08-16

    Yutong Chen, Wenjun Sun, Jianhui Han, Anmin Chen

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  13. Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles

    Chemical Reviews · 2026-08-25

    Taylor E. Wiggins, Robert P. Reynolds, Jared D. Fletcher, Adam Balvanz, Isaiah W. Gilley, Edward Hartley Sargent, Mercouri G. Kanatzidis

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