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RESEARCH PAPER · Chemical Communications · 2024

Chiral 2D and quasi-2D hybrid organic inorganic perovskites: from fundamentals to applications

Marco Moroni, Clarissa Coccia, Lorenzo Malavasi

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Chiral 2D and quasi-2D hybrid organic inorganic perovskites: from fundamentals to applicationsOriginalWhy Mixed Halides in 2D Chiral Perovskites Weaken Chirality-Induced Spin Selectivity242D and quasi-2D halide perovskite-based artificial synapses: highlights6Chiral heterogeneous photocatalysts for enantioselective synthesis: standing on the shoulders of organocatalysis5Chirality-driven dimensionality and broadband emission in lead bromide perovskites6Photoluminescence and Chiroptical Activity of Chiral Enantiomeric Organic Compounds0Photoluminescence and Chiroptical Activity of Chiral Enantiomeric Organic Compounds0Stepwise kinetics of the early-stage nucleation in chiral perovskites via ab initio molecular dynamics and free-energy calculations4Structural Design and Applications of Chiral Perovskites14Technical Routes to Achieve High Circular Polarized Luminescence in Chiral Perovskites: A Mini‐Review8Hafnium-Based Chiral 2D Organic–Inorganic Hybrid Metal Halides: Engineering Polarity and Nonlinear Optical Properties via Para -Substituent Effects86Recent Advances in Emerging Polarization‐Sensitive Materials: From Linear/Circular Polarization Detection to Neuromorphic Device Applications60Chiroptical Signal Inversion of Peptido‐Coassemblies in Confined Parallel‐Laminar Microfluidics1Chiroptical Signal Inversion of Peptido‐Coassemblies in Confined Parallel‐Laminar Microfluidics10Chiroptical Activities of Low‐Dimensional Lead‐Free Chiral Halide Perovskites with White‐Light Emission33D Chiral Metal Halide Semiconductors16Chiral Phonons in 2D Halide Perovskites9Achiral Cation-Induced Chirality Tuning in Cycloalkyl Chiral Cation-Based Quasi-1D and 2D Perovskites6Multifunctional Chiral Halide Perovskites: Advancing Chiro‐Optics, Chiro‐Optoelectronics, and Spintronics33Engineering the Electronic Structure and Optoelectronic Properties of Chiral Metal Halides through Cation Design0Dimensional Engineering in Hybrid Transition Metal Halide Materials through the Introduction of Chiral Organic Cations5Chiral Rare Earth Nanomaterials: Synthesis, Optical Properties, and Potential Applications4Stability strategies and luminescent applications of low-dimensional metal halide perovskites7Strain-Induced Interlayer Interactions under Hydrostatic Pressure Can Boost Circularly Polarized Luminescence in Chiral Hybrid Halide Perovskites3Photoluminescence and chiroptical activity of chiral enantiomeric organic compounds1Cyclodextrin-mediated circularly polarized luminescence in achiral two-dimensional blue perovskites7Recent Advances in Spin‐LEDs Based on Chiral Nanomaterials: Bridging Fundamental Physics, Materials, and Devices Performance9Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence1Structural Distortion‐Driven Chirality Transfer and Circularly Polarized Light Emission in Quasi‐2D Perovskites Based Light‐Emitting Diodes6Emerging trends and future perspectives for hybrid metal halides under pressure0Exploring Spin-Phonon Coupling, Barocaloric, and Polar Phonon Features in the Multiferroic [(CH3)2NH2][Mn(N3)3] Hybrid Perovskite0Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23POLARIS: perovskite optimization using LLM-assisted refinement and intelligent screening2Spacer cations: molecular switches for 2D and 2D/3D perovskite photovoltaics1Synthesis, crystal structure, optical properties, thin-film deposition, and SCAPS-1D simulation of a new lead-free 2D hybrid perovskite (C 6 H 7 NBr) 2 [CuCl 4 ] for potential photovoltaic applications1Chirality Transfer in Metal Halide Semiconductors16Nonlinear optical quantum communication with a two-dimensional perovskite light source1Optimizing cross-domain transfer for universal machine learning interatomic potentials14Chirality‐Dependent Photoluminescence Redshift of 2D Perovskites Under High Pressure1Fabrication of methylammonium lead bromide perovskite nanocrystals on chitosan for enhanced structural and optical stability0Chirality Engineering and Properties in Two‐Dimensional Layered Materials2Variation in the Spin-Splitting Magnitude from Dynamic Structural Distortions in 2D Hybrid Perovskites0Exploring spin-phonon coupling, barocaloric, and polar phonon features in the multiferroic [(CH3)2NH2][Mn(N3)3] hybrid perovskite0Chirality-Dependent Modulation of Organic-Inorganic Interaction and Exciton Response in 2D Perovskites under Pressure0Rashba-Related Spin-Selective Effect in 2D Chiral Perovskites with Achiral Organic Cation Spacers0Mutual Amplification of Chirality Driven by Interfacial Interactions in In Situ Synthesized Perovskite/Polymer Composites0A Lightweight Universal Machine-Learning Interatomic Potential via Knowledge Distillation for Scalable Atomistic Simulations1Circularly Polarized Lasing and Ultrafast Optical Helicity Switching in Chiral Perovskite Microcavities0How Self Absorption Shapes the Photoluminescence Spectrum of 2D Perovskites0A step-by-step workflow to account for linear polarization artifacts in circular dichroism of thin films0Low-Dimensional Perovskites and Metal Halides across Structures and Functions: Connectivity, Dimensionality, and Emerging Principles1Coupled Molecular and Framework Descriptors for Band-Edge Spin Splitting in Chiral Hybrid Organic–Inorganic Perovskites0

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  1. Why Mixed Halides in 2D Chiral Perovskites Weaken Chirality-Induced Spin Selectivity

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  2. 2D and quasi-2D halide perovskite-based artificial synapses: highlights

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  3. Chiral heterogeneous photocatalysts for enantioselective synthesis: standing on the shoulders of organocatalysis

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  4. Chirality-driven dimensionality and broadband emission in lead bromide perovskites

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    Cássio C. S. Soares, Carlos Mera Acosta, Fábio Furlan Ferreira, Aryane Tofanello, Mayra A. Padrón Gómez, Alejandro Pedro Ayala, José Roberto de Toledo, Y. Galvão Gobato, Maykon Alves Lemes, Carlos W. A. Paschoal, Jose Antonio Souza

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  5. Photoluminescence and Chiroptical Activity of Chiral Enantiomeric Organic Compounds

    SSRN Electronic Journal · 2025-01-01

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  6. Photoluminescence and Chiroptical Activity of Chiral Enantiomeric Organic Compounds

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  7. Stepwise kinetics of the early-stage nucleation in chiral perovskites via ab initio molecular dynamics and free-energy calculations

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  8. Structural Design and Applications of Chiral Perovskites

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  9. Technical Routes to Achieve High Circular Polarized Luminescence in Chiral Perovskites: A Mini‐Review

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  10. Hafnium-Based Chiral 2D Organic–Inorganic Hybrid Metal Halides: Engineering Polarity and Nonlinear Optical Properties via Para -Substituent Effects

    Journal of the American Chemical Society · 2025-01-08

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  11. Recent Advances in Emerging Polarization‐Sensitive Materials: From Linear/Circular Polarization Detection to Neuromorphic Device Applications

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  12. Chiroptical Signal Inversion of Peptido‐Coassemblies in Confined Parallel‐Laminar Microfluidics

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  13. Chiroptical Signal Inversion of Peptido‐Coassemblies in Confined Parallel‐Laminar Microfluidics

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  14. Chiroptical Activities of Low‐Dimensional Lead‐Free Chiral Halide Perovskites with White‐Light Emission

    Small Science · 2025-05-15

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  15. 3D Chiral Metal Halide Semiconductors

    ACS Energy Letters · 2025-05-22

    Marco Moroni, Luca Gregori, Clarissa Coccia, Massimo Boiocchi, Marta Morana, Doretta Capsoni, Andrea Olivati, Antonella Treglia, Giulia Folpini, M. Patrini, Isabel Goncalves, Heyong Wang, Chiara Milanese, Annamaria Petrozza, Edoardo Mosconi, Filippo De Angelis, Lorenzo Malavasi

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  16. Chiral Phonons in 2D Halide Perovskites

    Nano Letters · 2025-06-16

    Mike Pols, Geert Brocks, Sofı́a Calero, Shuxia Tao

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  17. Achiral Cation-Induced Chirality Tuning in Cycloalkyl Chiral Cation-Based Quasi-1D and 2D Perovskites

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  18. Multifunctional Chiral Halide Perovskites: Advancing Chiro‐Optics, Chiro‐Optoelectronics, and Spintronics

    Advanced Science · 2025-07-12

    Qi Liu, Hui Jun Ren, Qi Wei, Mingjie Li

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  19. Engineering the Electronic Structure and Optoelectronic Properties of Chiral Metal Halides through Cation Design

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  20. Dimensional Engineering in Hybrid Transition Metal Halide Materials through the Introduction of Chiral Organic Cations

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  21. Chiral Rare Earth Nanomaterials: Synthesis, Optical Properties, and Potential Applications

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  22. Stability strategies and luminescent applications of low-dimensional metal halide perovskites

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  23. Strain-Induced Interlayer Interactions under Hydrostatic Pressure Can Boost Circularly Polarized Luminescence in Chiral Hybrid Halide Perovskites

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  24. Photoluminescence and chiroptical activity of chiral enantiomeric organic compounds

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  25. Cyclodextrin-mediated circularly polarized luminescence in achiral two-dimensional blue perovskites

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  26. Recent Advances in Spin‐LEDs Based on Chiral Nanomaterials: Bridging Fundamental Physics, Materials, and Devices Performance

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  27. Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence

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  28. Structural Distortion‐Driven Chirality Transfer and Circularly Polarized Light Emission in Quasi‐2D Perovskites Based Light‐Emitting Diodes

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  29. Emerging trends and future perspectives for hybrid metal halides under pressure

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  30. Exploring Spin-Phonon Coupling, Barocaloric, and Polar Phonon Features in the Multiferroic [(CH3)2NH2][Mn(N3)3] Hybrid Perovskite

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  31. Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications

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  32. POLARIS: perovskite optimization using LLM-assisted refinement and intelligent screening

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  33. Spacer cations: molecular switches for 2D and 2D/3D perovskite photovoltaics

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  34. Synthesis, crystal structure, optical properties, thin-film deposition, and SCAPS-1D simulation of a new lead-free 2D hybrid perovskite (C 6 H 7 NBr) 2 [CuCl 4 ] for potential photovoltaic applications

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  35. Chirality Transfer in Metal Halide Semiconductors

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  38. Chirality‐Dependent Photoluminescence Redshift of 2D Perovskites Under High Pressure

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  41. Variation in the Spin-Splitting Magnitude from Dynamic Structural Distortions in 2D Hybrid Perovskites

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  42. Exploring spin-phonon coupling, barocaloric, and polar phonon features in the multiferroic [(CH3)2NH2][Mn(N3)3] hybrid perovskite

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  43. Chirality-Dependent Modulation of Organic-Inorganic Interaction and Exciton Response in 2D Perovskites under Pressure

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