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RESEARCH PAPER · Laser & Photonics Review · 2024

Achieving the Anomalous Far‐Red Emission of Eu3+ by Tailoring Distorted Square Antiprism Symmetry in Potassium‐Bismuth‐Phosphates

Hongzhi Zhang, Zhiqin Yang, Hong Li, Junpeng Li, Conglin Liu, Hongming Jiang, Yuxin Liu, Rui Wang, Zhi Xie, Jing Zhu

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Achieving the Anomalous Far‐Red Emission of Eu3+ by Tailoring Distorted Square Antiprism Symmetry in Potassium‐Bismuth‐PhosphatesOriginalStructural evolution-facilitated luminescence of Sm 3+ in whitlockite-type phosphors with anti-thermal quenching behavior6Warm white light phosphors Sc2W3O12: Dy3+, Eu3+ with ultrahigh thermal stability and tunable luminescence16An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7:Eu3+ (Ln = Y and Gd)11Enhanced white light generation via Eu 3+ co-doping and Dy 3+ →Eu 3+ energy transfer in Ca 3 WO 6 phosphors for WLEDs0Investigation of 5d0 → 7f4 Strong Emission in Caeuga3o7 and Application of Led in Plant Growth0Self-supplying coreactant radical and structural distortion induced by carbonate ligand in metal–organic framework for anomalous deep-red Self-electrochemiluminescence6Synergetic Contributions of High Quenching Concentration and Tuned Square Antiprism Geometry Boosting Far‐Red Emission of Eu3+ with Near‐Unit Efficiency33Red Color Tuning and Emission Enhancement in Thermally Stable Co‐Doped Ba 3 MoTiO 8 : Bi 3+ /Eu 3+ Phosphors for Photo‐Electronic Applications3A versatile heat-resistant barium phosphate phosphor: Dy3+–Eu3+ energy transfer and tunable emission15Tunable luminescence and structural modifications in Eu³⁺/Li⁺ Co-doped YBa₃(BO₃)₃ phosphors for LEDs24Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application11A heat-resistant red-emitting K6Bi13(PO4)15:Sm3+,Eu3+ phosphor toward high color rendering LED lights8Regulation of the Crystal Structure and Luminescence Properties of a BaLa1.6ZnO5:0.4Eu3+ Phosphor by Gd3+-Mg2+ Codoping for Solar Energy Utilization3Investigation of 5D0 → 7F4 strong emission in CaEuGa3O7 and application of LED in plant growth3Novel near-UV-excitable Eu3+ doped K3Ca2(SO4)3× (X = F, Cl, Br) halosulphate phosphors for white LEDs5Facilitated self-reduction of manganese through alkali metal ions co-doping and photoluminescence properties in CaSb2O6 host lattice3Lanthanide Coordination Polymers Obtained from Ln(OH)3 and 2‐Furoic Acid for Ln3+‐Based Luminescence in the Visible and Near‐Infrared Range3Local Structure–Luminescence Correlation in Eu 3+ ‐Doped Phosphors: A Comprehensive Review33Single-phase white-emitting phosphors based on Eu2+-activated apatite-type Ba5(PO4)3Cl induced by (BO3)3− diadochic substitution3Structural evolution-facilitated broadband near-infrared emission of multifunctional Sc-based phosphor with long wavelength5Highly stable Ca3Bi(PO4)3: Eu3+ red phosphors dual-functional applications from plant growth lighting to High-Ra white LEDs7Lattice sites of Eu3+/Sm3+ in Ca3(Ga, Al)2Ge3O12 photoluminescence spectra and applications in plant fill light, W-LEDs, and fingerprint detection1Thermally boosted luminescent from a novel red phosphor with two-dimensional negative thermal expansion for high-quality WLEDs3Dual engineering of oxygen vacancies and Bi metal on BiOCl nanosheets for synergistically enhancing far-red emission of Eu3+1Activating Deep‐Red Emission in Borate Phosphors via Low‐Coordination Engineering for Efficient Plant Lighting7On the photoluminescence differences of Eu3+-activated layered perovskite La2Ti2O7 and A2La2Ti3O10 (A = Li, Na, K) phosphors for potential applications in white LEDs and plant growth lighting5Site-selective luminescence in Ca-doped Sr2YNbO6:Eu3+ phosphors for high-color-purity red emission13Control of photoluminescence properties of Sr2ZnGe2O7:Eu3+ yellow feldspar red fluorescent powder based on local symmetry breaking0Far-red-emitting Eu 3+ -doped Ca 2 SrWO 6 double perovskite: Judd–Ofelt analysis and application in plant cultivation lighting1Highly stable Mn⁴⁺-doped KNaSiF₆ red phosphor via in situ NaH₂PO₂•H₂O reduction: Superior weather resistance and WLED performance0Structural engineering of α-BaEuBO 3 F 2 borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor0Engineering Eu3+-activated molybdenum tellurates via alkali metal co-doping for enhanced luminescence in advanced lighting and security ink applications6Breaking Spin-Forbidden Transition by an Antisite Defect Strategy for Enhancing Far-Red Emission of Cr 3+ -Activated Phosphors2Exploiting structural benefit of cyclotetraphosphate for delayed quenching concentration of Eu3+ luminescence and efficiency enhancement via co-doping alkali metal1Synergistic enhancement of Eu3+ red emission in Y2O3 by Bi3+ sensitization and cation co-doping1Completely substituting anionic group to develop two Eu3+-doped tellurite oxides for precise optical thermometry and high-color-rendering white lighting applications0Ca2GeB2O7:Eu3+: an efficient deep-red phosphor with intense 5D0→7F4 emission0Monocapped square antiprism geometry enhanced far-red emission in CaLuAlO4:Eu3+ with high thermal stability for versatile applications0Anomalous 5D0→7F4 transition, near 100% emission quantum efficiency and multi-emission of Eu3+-doped Y/La3Sc2Ga3O12 for multifunctional optical devices0Surface functionalization promoted luminescence enhancement in the Bi2WO6:Eu3+ (1–11 mol%) nanophosphors for next-generation solid-state lighting and flexible electronic devices0A novel multi-center activated single-component white light emission in Ca2AlNbO6:Dy3+,Eu3+ phosphor for WLED applications0On the luminescence enhancement of SrSb2O6:Mn4+ phosphor via Ln3+ (Ln = La, Ce, Gd, Y, Lu) addition for plant growth lighting0Tunable red-to-white emission via Cu2+-induced luminescence modulation in Eu3+/Dy3+-doped borate glasses0Control of photoluminescence properties of Sr2ZnGe2O7:Eu3+ melilite-type red fluorescent powder based on progressive local distortion enhancement0Lattice Distortion‐Induced Performance Enhancement of Red Phosphors for White LEDs0Eu3+-Doped NaBa3Y3Si6O20 Phosphor for Multifunctional Optical Devices: Superior Room-Temperature Storage and Chemical Stability0

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  1. Structural evolution-facilitated luminescence of Sm 3+ in whitlockite-type phosphors with anti-thermal quenching behavior

    Journal of Advanced Ceramics · 2024-02-01

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  2. Warm white light phosphors Sc2W3O12: Dy3+, Eu3+ with ultrahigh thermal stability and tunable luminescence

    Displays · 2024-12-03

    Xiaoqing Pei, Miao Yan, Yifan Liu, Lin Fan, Tao Jiang, Zetian Mi, Lina Liu, Chun Li, Hai Yan Lin, Shasha Li, Weiling Yang, Fanming Zeng, Zhong‐Min Su

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  3. An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7:Eu3+ (Ln = Y and Gd)

    Chinese Journal of Structural Chemistry · 2024-12-19

    Hongzhi Zhang, Hong Li, Asif Ali Haider, Junpeng Li, Zhi Xie, Hongming Jiang, Conglin Liu, Rui Wang, Jing Zhu

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  4. Enhanced white light generation via Eu 3+ co-doping and Dy 3+ →Eu 3+ energy transfer in Ca 3 WO 6 phosphors for WLEDs

    New Journal of Chemistry · 2025-01-01

    Naresh Degda

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  5. Investigation of 5d0 → 7f4 Strong Emission in Caeuga3o7 and Application of Led in Plant Growth

    SSRN Electronic Journal · 2025-01-01

    Chunmiao Cui, Jiahui Yang, Bingyang Zeng, Chenglong Xia, Haoyuan Weng, Yue Guo, Xiaoguang Liu, Ling Li

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  6. Self-supplying coreactant radical and structural distortion induced by carbonate ligand in metal–organic framework for anomalous deep-red Self-electrochemiluminescence

    Chemical Science · 2025-01-01

    Lu Zhao, Zian Xu, Xianzhen Song, Caifeng Ding, Huangxian Ju

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  7. Synergetic Contributions of High Quenching Concentration and Tuned Square Antiprism Geometry Boosting Far‐Red Emission of Eu3+ with Near‐Unit Efficiency

    Advanced Science · 2025-01-10

    Hong Li, Asif Ali Haider, Zhi Xie, Conglin Liu, Hongzhi Zhang, Hongming Jiang, Junpeng Li, Jing Zhu

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  8. Red Color Tuning and Emission Enhancement in Thermally Stable Co‐Doped Ba 3 MoTiO 8 : Bi 3+ /Eu 3+ Phosphors for Photo‐Electronic Applications

    ChemistrySelect · 2025-02-01

    Pooja Rohilla, Shristy Malik, Sheetal Kumari, Aman Prasad, Allam Srinivasa Rao

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  9. A versatile heat-resistant barium phosphate phosphor: Dy3+–Eu3+ energy transfer and tunable emission

    Journal of Rare Earths · 2025-02-14

    Asif Ali Haider, Xiaoyang Zhao, Lixin Liu, Zibo Huang, Jingkai Quan, Youwen Tang, Yue Qin, Xiaoting Huang, Yanqiong Shen, Jing Zhu

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  10. Tunable luminescence and structural modifications in Eu³⁺/Li⁺ Co-doped YBa₃(BO₃)₃ phosphors for LEDs

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    Dhowah A.E. Somaily, Abeer S. Altowyan, Umit Hüseyin Kaynar, H. Aydın, Jabir Wali Hakami, Mustafa Burak Çoban, Taharh Zelai, N. Can

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  11. Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application

    Journal of Alloys and Compounds · 2025-04-01

    Jun Kyu Lee, Weiwei Xiang, Jae Su Yu

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  12. A heat-resistant red-emitting K6Bi13(PO4)15:Sm3+,Eu3+ phosphor toward high color rendering LED lights

    Ceramics International · 2025-04-03

    Haonan Cui, Yuting Li, Ran Li, Hongzhi Zhang, Asif Ali Haider, Jintao Xie, Guanhao Zhou, Zibo Huang, Yujia Xu, Dandan Gao, Wei Ping Qian, Jing Zhu

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  13. Regulation of the Crystal Structure and Luminescence Properties of a BaLa1.6ZnO5:0.4Eu3+ Phosphor by Gd3+-Mg2+ Codoping for Solar Energy Utilization

    Inorganic Chemistry · 2025-05-23

    Rumeng Xiong, Jiaen Xu, Hai Li, Yulin Fan, Songqiao Li, Wenli Zhou, Zhongxian Qiu, Shixun Lian

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  14. Investigation of 5D0 → 7F4 strong emission in CaEuGa3O7 and application of LED in plant growth

    Journal of Solid State Chemistry · 2025-06-13

    Chunmiao Cui, Jiahui Yang, Bingyang Zeng, Chenglong Xia, Haoyuan Weng, Yue Guo, Xiaoguang Liu, Ling Li

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  15. Novel near-UV-excitable Eu3+ doped K3Ca2(SO4)3× (X = F, Cl, Br) halosulphate phosphors for white LEDs

    Inorganic Chemistry Communications · 2025-06-26

    Jianwei Dao, Liang Yang, Zhihao Jiang, Zihao Han, Tiqin Wei

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  16. Facilitated self-reduction of manganese through alkali metal ions co-doping and photoluminescence properties in CaSb2O6 host lattice

    Ceramics International · 2025-07-01

    Fenzhong Long, Jiawei Fu, Lu Xie, Xinmin Zhang, Jin Han

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  17. Lanthanide Coordination Polymers Obtained from Ln(OH)3 and 2‐Furoic Acid for Ln3+‐Based Luminescence in the Visible and Near‐Infrared Range

    Zeitschrift für anorganische und allgemeine Chemie · 2025-07-09

    Maksim A. Zhernakov, Moritz Maxeiner, Jakob Möbs, Julian Burkhart, Klaus Müller‐Buschbaum

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  18. Local Structure–Luminescence Correlation in Eu 3+ ‐Doped Phosphors: A Comprehensive Review

    Advanced Photonics Research · 2025-07-24

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  19. Single-phase white-emitting phosphors based on Eu2+-activated apatite-type Ba5(PO4)3Cl induced by (BO3)3− diadochic substitution

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    Tao Zhao, Lu Xie, Fenzhong Long, Fangui Meng, Jin Han, Xinmin Zhang

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  20. Structural evolution-facilitated broadband near-infrared emission of multifunctional Sc-based phosphor with long wavelength

    Journal of Rare Earths · 2025-09-17

    Yiting Huang, Yiting Huang, Haonan Cui, Zhepei Yan, Shuping Huang, Shuping Huang, Rui Wang, Hong Yuan, Yuxin Liu, Decai Huang, Jun Zhang, Wei Ping Qian, Hong Li, Jing Zhu

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  21. Highly stable Ca3Bi(PO4)3: Eu3+ red phosphors dual-functional applications from plant growth lighting to High-Ra white LEDs

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  22. Lattice sites of Eu3+/Sm3+ in Ca3(Ga, Al)2Ge3O12 photoluminescence spectra and applications in plant fill light, W-LEDs, and fingerprint detection

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  23. Thermally boosted luminescent from a novel red phosphor with two-dimensional negative thermal expansion for high-quality WLEDs

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  24. Dual engineering of oxygen vacancies and Bi metal on BiOCl nanosheets for synergistically enhancing far-red emission of Eu3+

    Ceramics International · 2025-11-14

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  25. Activating Deep‐Red Emission in Borate Phosphors via Low‐Coordination Engineering for Efficient Plant Lighting

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  26. On the photoluminescence differences of Eu3+-activated layered perovskite La2Ti2O7 and A2La2Ti3O10 (A = Li, Na, K) phosphors for potential applications in white LEDs and plant growth lighting

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  27. Site-selective luminescence in Ca-doped Sr2YNbO6:Eu3+ phosphors for high-color-purity red emission

    Journal of Colloid and Interface Science · 2025-12-03

    Chengxiang Yang, Tingting Gou, Haoyu Wang, Qi You, Wenwei Lai, Yue Wang, Zhihao Du, Zhaobin Tang, Wei Liu, Xuchuan Jiang

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  28. Control of photoluminescence properties of Sr2ZnGe2O7:Eu3+ yellow feldspar red fluorescent powder based on local symmetry breaking

    SSRN Electronic Journal · 2026-01-01

    Pengcheng Li, Yusong Chen, Zhao Li, Weigang Wang, Jun Zhou

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  29. Far-red-emitting Eu 3+ -doped Ca 2 SrWO 6 double perovskite: Judd–Ofelt analysis and application in plant cultivation lighting

    Physical Chemistry Chemical Physics · 2026-01-01

    Naresh Degda, Nimesh Patel, M. Srinivas

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  30. Highly stable Mn⁴⁺-doped KNaSiF₆ red phosphor via in situ NaH₂PO₂•H₂O reduction: Superior weather resistance and WLED performance

    Journal of Alloys and Compounds · 2026-01-01

    Tianman Wang, Yong Fang, Siyuan Ma, Jiaoli Huang, Sen Liao

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  31. Structural engineering of α-BaEuBO 3 F 2 borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor

    Inorganic Chemistry Frontiers · 2026-01-01

    Huiyi Zhang, Li Li, Bo Zhao, Yaozu Li, Bingbing Zhang, Cuimiao Zhang, Guang Jia, Ying Wang

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  32. Engineering Eu3+-activated molybdenum tellurates via alkali metal co-doping for enhanced luminescence in advanced lighting and security ink applications

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  33. Breaking Spin-Forbidden Transition by an Antisite Defect Strategy for Enhancing Far-Red Emission of Cr 3+ -Activated Phosphors

    Inorganic Chemistry · 2026-02-02

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  34. Exploiting structural benefit of cyclotetraphosphate for delayed quenching concentration of Eu3+ luminescence and efficiency enhancement via co-doping alkali metal

    Applied Materials Today · 2026-03-19

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  35. Synergistic enhancement of Eu3+ red emission in Y2O3 by Bi3+ sensitization and cation co-doping

    Physica B Condensed Matter · 2026-05-05

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  36. Completely substituting anionic group to develop two Eu3+-doped tellurite oxides for precise optical thermometry and high-color-rendering white lighting applications

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  37. Ca2GeB2O7:Eu3+: an efficient deep-red phosphor with intense 5D0→7F4 emission

    Scientia Sinica Chimica · 2026-06-01

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  38. Monocapped square antiprism geometry enhanced far-red emission in CaLuAlO4:Eu3+ with high thermal stability for versatile applications

    Journal of Alloys and Compounds · 2026-06-01

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  39. Anomalous 5D0→7F4 transition, near 100% emission quantum efficiency and multi-emission of Eu3+-doped Y/La3Sc2Ga3O12 for multifunctional optical devices

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  40. Surface functionalization promoted luminescence enhancement in the Bi2WO6:Eu3+ (1–11 mol%) nanophosphors for next-generation solid-state lighting and flexible electronic devices

    Journal of Alloys and Compounds · 2026-07-02

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  41. A novel multi-center activated single-component white light emission in Ca2AlNbO6:Dy3+,Eu3+ phosphor for WLED applications

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  42. On the luminescence enhancement of SrSb2O6:Mn4+ phosphor via Ln3+ (Ln = La, Ce, Gd, Y, Lu) addition for plant growth lighting

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  43. Tunable red-to-white emission via Cu2+-induced luminescence modulation in Eu3+/Dy3+-doped borate glasses

    Journal of Alloys and Compounds · 2026-09-01

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  44. Control of photoluminescence properties of Sr2ZnGe2O7:Eu3+ melilite-type red fluorescent powder based on progressive local distortion enhancement

    Journal of Luminescence · 2026-09-17

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  45. Lattice Distortion‐Induced Performance Enhancement of Red Phosphors for White LEDs

    Laser & Photonics Review · 2026-09-21

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  46. Eu3+-Doped NaBa3Y3Si6O20 Phosphor for Multifunctional Optical Devices: Superior Room-Temperature Storage and Chemical Stability

    Journal of Alloys and Compounds · 2026-10-01

    Yuanjian Huang, Heng Yu, Can Yuan, Xiaojin Kuang, Mingpei Wu, Xiang Guo, Ruirui Cui

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