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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

New advances in solid-state electrolytes: from halides to oxyhalides

Qingtao Wang, Zhenyang Shen, Pengfei Du, Yongmei Zhou, Peng Zhang, Ying Liu

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New advances in solid-state electrolytes: from halides to oxyhalidesOriginalHeterovalent doping of amorphous oxyhalide solid electrolytes for high-performance all-solid-state lithium batteries3The chemistry of halide-based solid electrolytes: unlocking advances in solid-state Li-ion batteries20Inorganic Solid‐State Electrolytes in Potassium Batteries: Advances, Challenges, and Future Prospects9A Pre‐Oxidation Strategy to Establish Stable Oxide Cathode/Halide Solid‐State Electrolyte Interfaces for High Energy all Solid‐State Batteries11From Li7La3Zr2O12 to Li4La4Zr2Cl24: Rapid three-dimensional transport of ions in halide solid electrolytes5A lithium-poor tantalum oxychloride solid electrolyte for all-solid-state lithium batteries8Recovering the Ionic Conductivity of Oxygen‐Doped Li3.25InCl5.75O0.25 Electrolyte through Heat Treatment: Reconstructing the Structure Damaged by Moisture11Status and Challenges of Solid‐State Electrolytes for Potassium Batteries13Crystalline Li-Ta-Oxychlorides with Lithium Superionic Conduction1Unraveling Ultrafast Li-Ion Dynamics in the Solid Electrolyte LiTi2(PS4)3 by NMR down to Cryogenic Temperatures9Enhancing Na ion conductivity of Na chloride cathode material NaFeCl 4 through polyatomic anion substitution1Beyond designer's knowledge: Generating materials design hypotheses via a large language model22Critical issues in lithium halide solid-state electrolytes: From intrinsic properties, existing challenges to multidimensional regulation strategies3Interface Engineering in Solid‐State Sodium Batteries: Advances in Materials Design, Interfacial Strategies, and Multiscale Characterization15Halide solid-state electrolytes: structures, properties, anodic interfacial challenges and modification strategies0Lithium superionic behavior and defect robustness in LiNbOCl 4 : a first-principles molecular dynamics study2Vibrational dynamics and the interplay of Li-ion mobility and thermal transport in LiAlSiO 46A mechanistic study of cation-anion co-doped sulfide solid-state electrolytes for sodium-ion batteries1Halide Li-ion solid electrolytes with soft feature for all-solid-state batteries1Research progress, challenges and prospects of solid-state electrolyte3Halide and oxyhalide solid-state electrolytes: From structural chemistry to electrochemical applications in all-solid-state Na-ion batteries3Revisiting the Modification Strategies of Alloy-Base Anode for Solid-State Lithium-Ion Batteries Through Deconstructing Anode-Interface-Solid Electrolyte12Design Principles for Aqueous Stability of Lithium Halide and Oxyhalide Solid Electrolytes from First-Principles Pourbaix Analysis0Halide-Based Solid Electrolytes for Advanced All-Solid-State Batteries: Design, Interfaces, and Electrochemical Performance1Cation valence and size as synergistic descriptors: Toward rational doping of chloride solid-state electrolytes0Multi‐Ion Doped Zr‐Based Halide Solid Electrolytes for High‐Performance All‐Solid‐State Batteries0Mechanistic study of mixed lithium halides solid-state electrolytes1Dual-functional iron-doped lithium zirconium chloride electrolytes for high-capacity all-solid-state lithium batteries0

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  1. Heterovalent doping of amorphous oxyhalide solid electrolytes for high-performance all-solid-state lithium batteries

    Journal of Materials Chemistry A · 2025-01-01

    Hongda Li, Lingzhi Yang, Wentao Zhou, Jiale Wang, Wanting Zhang, Fangzhi Wang, Pengyan Li, Haixin Chang

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  2. The chemistry of halide-based solid electrolytes: unlocking advances in solid-state Li-ion batteries

    Chemical Communications · 2025-01-01

    Palanivel Molaiyan, Tingwu Jin, Shuo Wang, Glaydson S. dos Reis, Shaikshavali Petnikota, Ulla M. Lassi, Andrea Paolella

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  3. Inorganic Solid‐State Electrolytes in Potassium Batteries: Advances, Challenges, and Future Prospects

    ChemElectroChem · 2025-02-14

    Titus N. Masese, Godwill Mbiti Kanyolo

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  4. A Pre‐Oxidation Strategy to Establish Stable Oxide Cathode/Halide Solid‐State Electrolyte Interfaces for High Energy all Solid‐State Batteries

    Small · 2025-02-28

    Hanzhou Liu, Yang Lu, Yanchen Liu, Shenghao Jing, Zongliang Zhang, Siliang Liu, Yang Liu, Yongle Chen, Kun Zhang, Shuo Yin, Fanqun Li, Fangyang Liu

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  5. From Li7La3Zr2O12 to Li4La4Zr2Cl24: Rapid three-dimensional transport of ions in halide solid electrolytes

    Energy storage materials · 2025-03-01

    Qingtao Wang, Zhenyang Shen, Pengfei Du, Yongmei Zhou, Peng Zhang, Ying Liu, Dongfei Sun, Ziqiang Lei

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  6. A lithium-poor tantalum oxychloride solid electrolyte for all-solid-state lithium batteries

    Chemical Engineering Journal · 2025-03-31

    Hao Cheng, Kangzhe Yu, Deli Xu, Guoxian Wu, Minghua Li, Sheng Wang, Baolong Shen, Jinyong Zhang, Xiao Huang, Bingbing Tian

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  7. Recovering the Ionic Conductivity of Oxygen‐Doped Li3.25InCl5.75O0.25 Electrolyte through Heat Treatment: Reconstructing the Structure Damaged by Moisture

    ChemSusChem · 2025-05-02

    Miao Deng, Shiyu Liu, Siwu Li, Wenwen Hu, Ziyu Lu, Ziling Jiang, Lin Li, Kunpeng Tang, Lei Shi, Qiyue Luo, Haitao Li, Jie Yang, Chen Liu, Chuang Yu

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  8. Status and Challenges of Solid‐State Electrolytes for Potassium Batteries

    Small · 2025-05-02

    Kangzhe Cao, Jiahui Ma, Ziwei Yue, Huimin Li, Yang Fan, Huiqiao Liu

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  9. Crystalline Li-Ta-Oxychlorides with Lithium Superionic Conduction

    Crystals · 2025-05-17

    Hao-Tian Bao, Bo-Qun Cao, Gang-Qin Shao

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  10. Unraveling Ultrafast Li-Ion Dynamics in the Solid Electrolyte LiTi2(PS4)3 by NMR down to Cryogenic Temperatures

    Journal of the American Chemical Society · 2025-06-02

    Denise Tapler, Bernhard Gadermaier, Jonas Spychala, Florian Stainer, Annika Marko, Jana Königsreiter, Katharina Hogrefe, Paul Heitjans, Martin Wilkening

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  11. Enhancing Na ion conductivity of Na chloride cathode material NaFeCl 4 through polyatomic anion substitution

    Journal of Asian Ceramic Societies · 2025-07-03

    Keisuke Makino, Naoto Tanibata, Hayami Takeda, Masanobu Nakayama

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  12. Beyond designer's knowledge: Generating materials design hypotheses via a large language model

    Acta Materialia · 2025-07-04

    Quanliang Liu, Maciej P. Polak, So Yeon Kim, MD Al Amin Shuvo, Hrishikesh Shridhar Deodhar, Jeongsoo Han, Dane D. Morgan, Hyunseok Oh

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  13. Critical issues in lithium halide solid-state electrolytes: From intrinsic properties, existing challenges to multidimensional regulation strategies

    Journal of Material Science and Technology · 2025-09-27

    Dongfan Li, Jian-Cang Wang, Shudong Xu, Manni Li, Jiayin Shang, Zemin He, Zongcheng Miao

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  14. Interface Engineering in Solid‐State Sodium Batteries: Advances in Materials Design, Interfacial Strategies, and Multiscale Characterization

    Interdisciplinary materials · 2025-12-31

    Yonghuan Fu, Guosheng Shao, Yong Lei

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  15. Halide solid-state electrolytes: structures, properties, anodic interfacial challenges and modification strategies

    Chemical Science · 2026-01-01

    Tianxi He, Yingying Zhang, Kecheng Pan, Bin Tang, Yongzheng Fang, Kai Zhu, Zhen Zhou, Dianxue Cao

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  16. Lithium superionic behavior and defect robustness in LiNbOCl 4 : a first-principles molecular dynamics study

    Journal of Materials Chemistry A · 2026-01-01

    Halimah Harfah, Yoshitaka Tateyama, Kazunori Takada, Randy Jalem

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  17. Vibrational dynamics and the interplay of Li-ion mobility and thermal transport in LiAlSiO 4

    Journal of Materials Chemistry A · 2026-01-01

    Mayanak K. Gupta, Sajan Kumar, Chanchal Chanchal, Samiran Malgope, R. Mittal, Shovit Bhattacharya, Ajay Kumar Singh, P Saha, Srungarpu Nagabhusan Achary, Avesh Kumar Tyagi, Samrath Lal Chaplot

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  18. A mechanistic study of cation-anion co-doped sulfide solid-state electrolytes for sodium-ion batteries

    Electrochimica Acta · 2026-01-12

    Yihang Song, Hanyu Zhou, Weijia Wang, Lijun Yang, Xiaoze Du

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  19. Halide Li-ion solid electrolytes with soft feature for all-solid-state batteries

    Materials Today Energy · 2026-01-19

    Yu Yang, Xinlin Yan, Yi Wang, Long Zhang

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  20. Research progress, challenges and prospects of solid-state electrolyte

    Journal of Energy Storage · 2026-01-29

    Pengfei Wu, Bin Guan, Lei Zhu, Tiankui Zhu, Zhongqi Zhuang, Junyan Chen, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Junjie Gao, Luyang Zhang, Yuan Li, L.X. Xu, Yunlong Bai, Shuo Wei, Yuyang Mao, Wenbo Zeng, Shuai Chen, Linhui Wang, Zhen Huang

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  21. Halide and oxyhalide solid-state electrolytes: From structural chemistry to electrochemical applications in all-solid-state Na-ion batteries

    Materials Today Chemistry · 2026-04-18

    Chaeeun Boo, Jihyun Jang

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  22. Revisiting the Modification Strategies of Alloy-Base Anode for Solid-State Lithium-Ion Batteries Through Deconstructing Anode-Interface-Solid Electrolyte

    Nano-Micro Letters · 2026-04-21

    Yueying Chen, Hanyi Yu, Yuerui Lin, Cong Liu, Akif Zeb, Zijian Cai, Hongzhe Chu, Yuhuo Luo, Xiaoming Lin, Jiaye Ye

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  23. Design Principles for Aqueous Stability of Lithium Halide and Oxyhalide Solid Electrolytes from First-Principles Pourbaix Analysis

    ACS Energy Letters · 2026-06-22

    Yan Li, Zeyu Deng

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  24. Halide-Based Solid Electrolytes for Advanced All-Solid-State Batteries: Design, Interfaces, and Electrochemical Performance

    Nano-Micro Letters · 2026-06-22

    Shivaraju Guddehalli Chandrappa, Gerardo Morell, Ram S. Katiyar

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  25. Cation valence and size as synergistic descriptors: Toward rational doping of chloride solid-state electrolytes

    Chemical Engineering Journal · 2026-06-26

    Yingxiang He, Zhiyuan Wang, Pengzu Kou, Yao Dai, Sun H, Runguo Zheng, Yanguo Liu

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  26. Multi‐Ion Doped Zr‐Based Halide Solid Electrolytes for High‐Performance All‐Solid‐State Batteries

    Small · 2026-07-25

    Shuwang Xu, Lei Xi, Hulei Yu, Pingbo Xie, Jun Liu

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  27. Mechanistic study of mixed lithium halides solid-state electrolytes

    Physical Review Materials · 2026-08-26

    Davide Tisi, Sergey Pozdnyakov, Michele Ceriotti

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  28. Dual-functional iron-doped lithium zirconium chloride electrolytes for high-capacity all-solid-state lithium batteries

    Materials Today Energy · 2026-10-04

    Haipeng Chen, D. Chen, Hongfei Bao, Bin Wang, Shuai Li, Mengyu Tian, Kaili Li, Yang Sun

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