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RESEARCH PAPER · Energy & Environmental Science · 2024

Solar-driven photoelectrochemical conversion of biomass: recent progress, mechanistic insights and potential scalability

Caidi Jin, Mingxia Han, Yuheng Wu, Shurong Wang

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Solar-driven photoelectrochemical conversion of biomass: recent progress, mechanistic insights and potential scalabilityOriginalCarbon-based electrodes for photo-bio-electrocatalytic microbial fuel and electrolysis cells: advances and perspectives21Conductive MOF coating on TiO2 nanorod photoanodes with boosted glycerol upgrading activity via interfacial engineering0Conductive MOF coating on TiO2 nanorod photoanodes with boosted glycerol upgrading activity via interfacial engineering0Efficient photoelectrochemical oxidation of benzyl alcohol in a microchannel flow cell using compact and mesoporous TiO 2 photoanodes2Enhancing Radiotherapy for Hypoxic Tumors: Integrative Strategies Using Bacteria and Nanoparticles5Inverse opal anatase/rutile TiO 2 multi-heterojunctions enable efficient photoelectrochemical water splitting41Photoelectrochemical comproportionation of pre-treated PET plastics and CO 2 to formate41Photon-coupled-proton buffers: reshaping solar-driven hydrogen and formic acid production with biomass2Powering lignocellulose biorefineries with solar energy – a critical review with furfural as a case study9Spinel-structured photoelectrodes for photoelectrochemical energy and environmental applications: synergistic photothermal–magnetic effects7Surface engineering strategies for selectivity tuning and enhancement in photoelectrochemical biomass and CO 2 valorization15Multiphysics Modeling of Heat and Mass Transfer for Photoelectrochemical CO 2 Reduction to CO6Photoelectrocatalytic highly selective oxidation of glycerol to C3 products on Mo:BiVO4/NiOOH photoanodes5Photocatalytic and Electrochemical Synthesis of Biofuel via Efficient Valorization of Biomass132Localized Phosphorization Manipulating Internal Electric Field Orientation in Carbon Nitride Homojunction for Efficient Photocatalytic Hydrogen Evolution34Paired Chemical Upgrading in Photoelectrochemical Cells8Photoelectrocatalytic conversion for wastewater to high-value chemicals and energy21Photoelectrocatalytic Transformations of Waste into Value12Unique TiO2@Cu phthalocyanine core-shell photoanodes via molecular interface engineering for effective solar-driven upgrading of glycerol10Dual structure Brønsted sites activated carbon beads solid acid enhances the highly efficient synthesis of HMF: From batch to continuous6Improved Solar‐Powered Water‐Splitting Performance of Bi 4 Ti 3 O 12 /TiO 2 Composite with Synergistically Interacted Heterointerfaces Under Platinum Cocatalysis7NiFe-LDH/BiVO4–BOD Photocatalytic Fuel Cell for Bias-Free and Selective 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid3Photoelectrochemical Solar Fuels: What’s Next?9Effect of pyrolysis temperature and heating rate on the physicochemical properties of alkali lignin-derived biochar: A comparative study of fast and slow pyrolysis58Photoelectrochemical Charge Transfer Imaging at Nanoscale Catalysts8Structural modulation of imine bridges in Cu-N2O2 catalysts for electronic property tuning toward enhanced electrocatalytic CO2 reduction to high-value chemicals0An integrated platform for predicting straw pyrolysis by flash joule heating: Optimizing three-phase product yields and properties using HRF algorithm3Photoelectrochemical Asymmetric Epoxidation of Alkenes with Water as an Oxygen Source in a Biphasic System12LSPR-boosted Sr1/3Ca2/3TiO3–Pt heterojunctions for synergistic photocatalytic hydrogen evolution and selective biomass valorization2Hydrogen Production from Biowaste: A Systematic Review of Conversion Technologies, Environmental Impacts, and Future Perspectives35Recent Progress on Photoelectrochemical Organic Upgrading: A Review from Direct and Indirect Charge Transfer Pathway10Bio-hybrid photoelectrochemical catalysis for solar fuels and chemicals conversion32Unlocking overall electrolysis efficiency: pairing value-added reduction reactions with oxidative valorization of biomass-derived compounds3Ferroelectric Control of Photoelectrochemical Ammonia Oxidation Reaction3Dual‐Asymmetric Janus Aerogel Enabled by Ambient Drying for Synergistic Hydrovoltaic and Solar Steam Generation9Exploring nanoporous CuWO4 photoanode for sustainable conversion of 5-hydroxymethylfurfural to diformylfuran with exceptional selectivity1Recent Progress in Biomass‐Based Materials for Rechargeable Batteries †0Facet-Engineered oriented construction of 002-WO3/TiO2 heterojunctions for highly selective photoelectrocatalytic oxidation of glycerol to glyceraldehyde4Bias-free solar to ammonia production via integrated perovskite–organic tandem photovoltaics1Coordination-gated selective dehydrogenation for bias-free biomass valorization0Hybrid photoelectrocatalytic advanced oxidation systems for pharmaceutical wastewater treatment: mechanisms, reactive species, operational parameters, toxicity assessment and real wastewater treatment0Light-triggered interface reconstruction of heterojunction electrocatalysts for enhanced glycerol oxidation0Perspectives and challenges of electrochemical, photochemical, and photoelectrochemical conversion of CO 2 into valuable fuels using metal and metal oxide-based catalysts9Photocatalytic valorization of biomass derivatives for fine chemicals and fuels production over halide perovskite catalysts5Research progress on photo-driven catalytic oxidation of 5-hydroxymethylfurfural3Surface phosphate functionalization regulates electron-phonon coupling and glycerol oxidation pathway for dihydroxyacetone production over BiVO4 photoanodes0Various energy-driven high-value-added oxidation reactions in CO 2 reduction systems9Pulse-enhanced photoelectrochemical upcycling of polyethylene terephthalate to glycolic acid via dynamic interfacial adsorption tuning4Unraveling spatially decoupled redox pathways in 2D/2D g-C3N4/ZnIn2S4 enables highly selective aerobic photooxidation of biomass1Atomic-level lattice matching in hexagonal WO3/TiO2 S-scheme heterojunctions for high-efficiency selective photoelectrocatalytic glycerol-to-dihydroxyacetone conversion2Molecular‐Bridged Core–Shell TiO 2 @CuFe Conductive Metal–Organic Framework Photoanode for Hydroxyl Radical‐Mediated Selective Glycerol Oxidation to Glyceraldehyde0Polymer-controlled growth of BiSI/Bi13S18I2 thin films for photoelectrochemical applications2Efficient photoelectrochemical synthesis of azo compounds via in situ surface reconstruction of BiVO 41Unlocking photoelectrochemistry for converting abundant resources into value-added chemicals2Dynamic Hydrogen‐Bonding Nanonetworks and Asymmetric Dual‐Interface Built‐In Electric Fields Cooperatively Mediate Proton‐Coupled Electron Transfer for C─H Activation0Recent Progress on Photoelectrochemical Biomass‐Derived Platform Molecules Conversion Coupled With Hydrogen Evolution0Thermodynamic Aspects of the Electrochemical Conversion of Biomass and CO 2 to Sustainable Chemicals0Photoelectrocatalytic upgrading conversion of biomass-derived alcohols/aldehydes: Regulating the oxidation pathway by designing photoanode materials1Photoelectrochemical oxidation for biomass valorization: Upgrading biorefinery-derived feedstocks into value-added chemicals3Unlocking a High Photovoltage in BiVO 4 Photoanodes via Repairing Oxygen‐Defect‐Induced Surface Traps Boosting Photoelectrochemical Performance4Valorization of waste biomass in the circular bioeconomy: advances in pretreatment and catalytic conversion technologies in modern biorefineries4Advances in Ta 3 N 5 ‐Based Photoanodes for Photoelectrochemical Hydrogen Production and Beyond0Glycerol Valorization to High‐Value Chemicals: Chemical and Biocatalytic Routes With Emphasis on Enzyme Immobilization and Laccase/TEMPO Systems: A Review2Low-temperature liquid-phase dehydration of glycerol to acrolein based on Fe-modified ZSM-50An energy-carbon dual-control biohybrid: integrating photosynthetic microorganisms with patterned perovskite solar cells for concurrent electricity and biopolymer production1W 1 /TiO 2− x Enabled Photoelectrochemical Tandem Upgrading of Glycerol to Nucleoside Precursors0W 1 /TiO 2− x Enabled Photoelectrochemical Tandem Upgrading of Glycerol to Nucleoside Precursors0Upgrading glycerol to sorbose via a tandem photoelectrocatalysis–enzyme catalysis relay0ZnWO 4 /WO 3 Heterojunction Photoanodes for Selective Photoelectrochemical Conversion of Glycerol to Glyceraldehyde0Urea induced reduction of crystallinity of α-NiCo layered double hydroxides for high performance asymmetric supercapacitors1Fast Interfacial Hole Consumption Suppresses Space–Charge Layer Trap Filling in BiVO 4 Photoanodes2From biased cells to artificial leaves: A device-centric review of solar chemical transformations0Spacing-matching enabled spatially paired Co-SA/Ru-NC catalysts for room temperature tandem oxidation of HMF at industrial-level concentration0Surface phosphate functionalization regulates electron polaron and glycerol oxidation pathway for dihydroxyacetone production over BiVO4 photoanodes8Cr-incorporated CoFe LDHs as an efficient cocatalyst for accelerating the water oxidation kinetics of BiVO40Highly efficient nitrogen-doped biochar-supported LaCoO3 perovskite catalysts for peroxymonosulfate activation: A dual-radical system for imidacloprid degradation1Activation of lattice oxygen in single-atom Pd1-MnO2 electrocatalyst for simultaneous acidic hydrogen evolution and biomass valorization0Photocatalytic and photoelectrocatalytic conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid: A review0Molecular Segments Reorganization Strategy Coupled With Retrosynthetic Analysis for Designing Sustainable Alternatives to Alkylphenol Ethoxylates0Molecular Segments Reorganization Strategy Coupled With Retrosynthetic Analysis for Designing Sustainable Alternatives to Alkylphenol Ethoxylates0Ligand-Induced Built-In Electric Field Amplification for Selective Photoelectrochemical Glycerol Valorization0Pd Size‐Controlled C–C Bond Cleavage‐Recoupling in Photocatalytic Glycerol Selective Oxidation to Glycolaldehyde0Interface-tuned Janus-type high-entropy heterostructures for cascade electrocatalytic oxidation of 5-hydroxymethylfurfural0Conductive Materials in Microbial Chain Elongation for Medium-Chain Fatty Acids Biosynthesis: A Critical Review of Mechanisms and Metabolic Regulation0Bridging the scaling gap: From laboratory to industry in large-area photoelectrochemical water splitting0Design principles for functional carbon materials derived from biomass conversion0Chloride‐Mediated Photoelectrochemical Selective Oxidation of Polyols Coupled With Hydrogen Evolution0

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  50. Atomic-level lattice matching in hexagonal WO3/TiO2 S-scheme heterojunctions for high-efficiency selective photoelectrocatalytic glycerol-to-dihydroxyacetone conversion

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