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RESEARCH PAPER · Chemistry of Materials · 2024

[B3O3F4(OH)]2–: A Versatile Hydroxyfluorooxoborate Heteroanion Producing Compounds with Highly Tunable Optical Anisotropy

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[B3O3F4(OH)]2–: A Versatile Hydroxyfluorooxoborate Heteroanion Producing Compounds with Highly Tunable Optical AnisotropyOriginalSulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy4[C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence13BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect9(CN 4 H 7 ) 2 SO 4 ·H 2 O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration5Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions1Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals10[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15Boron Oxides, Boric Acid, and Borates0(CN4H7)H2C3N3S3: Trithiocyanurate Exhibiting Giant Optical Anisotropy via Weak Interaction-Mediated Functional Module Alignment3Triple Integration of π‐Conjugated Building Blocks: Unprecedented Assembly for Large Optical Anisotropy11Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach8A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1[C 3 N 2 H 5 ]B 7 O 10 F 2 : Demonstrating a New Hydrogen‐Bond‐Induced Intralayer Charge‐Balanced Structure Model with Large Birefringence3Hydrogen‐Bond‐Directed Assembly of Urea Derivatives: Exceptional Birefringence Achieved by π ‐Conjugated Unit Alignment3Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites0Steric hindrance and hydrogen-bond networks synergistically directing molecular alignment for high-performance ultraviolet birefringent1

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  1. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  2. SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap

    Small · 2024-10-27

    Mengya Ji, Yilin Li, Chun‐Li Hu, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·
  3. From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

    Inorganic Chemistry · 2024-11-06

    Ruyi Niu, Qing‐Yu Liu, Minqiang Gai, Zhihua Yang, Shujuan Han, Shilie Pan

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  4. [C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence

    Inorganic Chemistry · 2024-11-18

    Ya-Lan Deng, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·
  5. BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect

    Inorganic Chemistry · 2024-12-02

    Yuan Hua Lin, Rongfang Zhang, Yucheng Hao, Ming-Yang Cao, Xuanlin Pan, Jiang‐Gao Mao

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  6. (CN 4 H 7 ) 2 SO 4 ·H 2 O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration

    Inorganic Chemistry Frontiers · 2025-01-01

    Xia Hao, Sijing Xie, Ruijie Wang, Chensheng Lin, Lingli Wu, Guang Peng, Tao Yan, Ning Ye, Min Luo

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  7. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  8. K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions

    New Journal of Chemistry · 2025-01-01

    Min-Quan Lin, M. Duan, Jiang-Gao Mao, Bing‐Ping Yang

    Read original paper ↗ ·
  9. Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals

    Advanced Optical Materials · 2025-04-29

    Ziqi Chen, Changyou Liu, Chenxu Li, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  10. [CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy

    Small · 2025-05-23

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  11. Boron Oxides, Boric Acid, and Borates

    Kirk-Othmer Encyclopedia of Chemical Technology · 2025-06-23

    David M. Schubert

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  12. (CN4H7)H2C3N3S3: Trithiocyanurate Exhibiting Giant Optical Anisotropy via Weak Interaction-Mediated Functional Module Alignment

    Inorganic Chemistry · 2025-08-19

    Xia Hao, Y.K. Su, Chensheng Lin, Min Luo, Lingli Wu, Ruijie Wang, Xin Wen, Ning Ye

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  13. Triple Integration of π‐Conjugated Building Blocks: Unprecedented Assembly for Large Optical Anisotropy

    Small · 2025-10-07

    Ruyi Niu, Xiaona Li, Zhihua Yang, Juanjuan Lu, Xueling Hou, Shujuan Han, Shilie Pan, Miriding Mutailipu

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  14. Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach

    The Journal of Physical Chemistry Letters · 2025-10-24

    Xinyue Shi, Xueqing Liu, Ying Su, Yangkai Zhang, Yong Wu, Run Li, Degao Zhong, Bing Teng, Yisheng Huang, Zhoubin Lin, Shijia Sun

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  15. A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations

    Materials Chemistry Frontiers · 2026-01-01

    Zhi Fang, G Xu, Wenhu Wang, Huanhuan Wang, Jian Wei Han

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  16. [C 3 N 2 H 5 ]B 7 O 10 F 2 : Demonstrating a New Hydrogen‐Bond‐Induced Intralayer Charge‐Balanced Structure Model with Large Birefringence

    Small · 2026-02-20

    Chunjie Shen, Huan Zhou, Zhihua Yang, Xueling Hou, Feng Zhang, Shilie Pan

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  17. Hydrogen‐Bond‐Directed Assembly of Urea Derivatives: Exceptional Birefringence Achieved by π ‐Conjugated Unit Alignment

    Small · 2026-04-14

    Peng Jiang, Yuqi Qin, Junwei Feng, Minqiang Gai, Shilie Pan

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  18. Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites

    Small · 2026-05-07

    Chanhee Ko, Congcong Jin, Taek Rim Kim, Seung Han Shin, Yunseung Kuk, Jiachen Lu, Chong‐An Chen, Wei Zeng, Joon Ik Jang, Kang Min Ok

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  19. Steric hindrance and hydrogen-bond networks synergistically directing molecular alignment for high-performance ultraviolet birefringent

    Journal of Molecular Structure · 2026-05-07

    Yuqi Qin, Paipai Zhang, Peng Jiang, Xueling Hou, Hu Jiang, Minqiang Gai

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