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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Tadpole-Like Polar Molecule Encapsulated in a Two-in-One Supramolecular Cage: Molecular Motion, Phase Transition and Ferroelectricity

Lin-Yong Sheng, Ding‐Chong Han, Rui‐Kang Huang, Liming Cao, Chun‐Ting He, Zi‐Yi Du, Takayoshi Nakamura

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Tadpole-Like Polar Molecule Encapsulated in a Two-in-One Supramolecular Cage: Molecular Motion, Phase Transition and FerroelectricityOriginalHydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials9A Ferroelastic Salt Cocrystal with Ultraviolet Emission3Guest molecule dynamics and ferroelectric transition in a clathrate compound1Indications of ferroelectric behaviour near room temperature in the organic–inorganic hybrid Q 2 CuBr 45Thermal responsive cation flipping and dielectric constant in an organic–inorganic hybrid crystal2Spiro‐Driven Ferroelectric Coordination Polymer Exhibiting Distinct Phase Transitions Under Thermal and Pressure Stimuli0Spiro‐Driven Ferroelectric Coordination Polymer Exhibiting Distinct Phase Transitions Under Thermal and Pressure Stimuli5Efficient Synthesis of Arylhydrazone Capsule with Single Precursor for Encapsulation of C60 and C701Structural Phase Transition‐Associated Ferroelectricity and Piezoelectric Energy Harvesting in 0D Halogenozincate Hybrid via Cation's Terminal Group Lengthening4Mathematical Double‐Matrix Switchable Homochiral Ferroelectric18Mathematical Double‐Matrix Switchable Homochiral Ferroelectric6Metal‐Free Molecular Debye‐Type Relaxor Ferroelectric Crystals Enable Broadband Photo‐Pyroelectric Detection3Achieving Combined Photoluminescence and SHG in a New Polar Hybrid Glass‐Ceramic with Square‐Pyramidal [SbBr 5 ] Units1Achieving Combined Photoluminescence and SHG in a New Polar Hybrid Glass‐Ceramic with Square‐Pyramidal [SbBr 5 ] Units10Molecular Symmetry and Geometry Engineering for High‐Temperature Ferroelectricity and Low Coercive Field in Hybrid Metal Halides1Molecular Symmetry and Geometry Engineering for High‐Temperature Ferroelectricity and Low Coercive Field in Hybrid Metal Halides4Thermochromic Hybrid Ferroelastic Semiconductor with Thermal/Electrical/Optical Switching Responses2Cation ordering and metal anisotropy enable ferroelectricity and single molecule magnets behavior in a Co-based molecular crystal0Recent advances in supramolecular ferroelectrics based on macrocycles and cages0Guest conformational rigidification and solid solution in a supramolecular cage Compound: Molecular Dynamics, phase Transition, ferroelectricity and fluorescence0From challenges to solutions: insights into AIEgen-based diagnostic and therapeutic strategies for breast cancer0

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  1. Hydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials

    Chemical Communications · 2024-01-01

    Xin Deng, Lin Zhou, Xin Yan, Yanjuan Wang, Wen-Li Yang, Hui‐Peng Lv, Yuan‐Yuan Tang

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  2. A Ferroelastic Salt Cocrystal with Ultraviolet Emission

    Inorganic Chemistry · 2024-11-27

    Xin Yan, Lin Zhou, Wen-Li Yang, Yanjuan Wang, Xin Deng, Yan Fang Qin, Yuan‐Yuan Tang

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  3. Guest molecule dynamics and ferroelectric transition in a clathrate compound

    Physical Chemistry Chemical Physics · 2025-01-01

    Aitor Erkoreka, Zi‐Yi Du, Alberto Oleaga, Rui‐Kang Huang, Josu Martínez-Perdiguero

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  4. Indications of ferroelectric behaviour near room temperature in the organic–inorganic hybrid Q 2 CuBr 4

    Dalton Transactions · 2025-01-01

    Agnieszka Ciżman, Dorota A. Kowalska, Paweł Szarek, W. Medycki, Natalia Anna Wójcik, Marek Adam Gusowski, Monika Trzebiatowska, Adam Bartosiewicz, L. M. Filevska, Piotr Staniorowski, Ewelina Jach

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  5. Thermal responsive cation flipping and dielectric constant in an organic–inorganic hybrid crystal

    CrystEngComm · 2025-01-01

    Lei Wang, Wei-Yu Hu, Hua-Qing Zhou, Li Wang, Shi‐Yong Zhang, Zhong-Xia Wang

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  6. Spiro‐Driven Ferroelectric Coordination Polymer Exhibiting Distinct Phase Transitions Under Thermal and Pressure Stimuli

    Angewandte Chemie · 2025-03-12

    Zi‐Yi Du, Miao Xie, Wenbo Qiu, Ding‐Chong Han, Shi‐Yong Zhang, Ying Zeng, Weizhao Cai, Takayoshi Nakamura, Rui‐Kang Huang, Chun‐Ting He

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  7. Spiro‐Driven Ferroelectric Coordination Polymer Exhibiting Distinct Phase Transitions Under Thermal and Pressure Stimuli

    Angewandte Chemie International Edition · 2025-03-12

    Zi‐Yi Du, Miao Xie, Wenbo Qiu, Ding‐Chong Han, Shi‐Yong Zhang, Ying Zeng, Weizhao Cai, Takayoshi Nakamura, Rui‐Kang Huang, Chun‐Ting He

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  8. Efficient Synthesis of Arylhydrazone Capsule with Single Precursor for Encapsulation of C60 and C70

    Chemistry - An Asian Journal · 2025-04-08

    Qian Li, He Deng, Wei Zeng, Qi Zhao, Tian‐Guang Zhan, Shigui Chen, Lu Wang

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  9. Structural Phase Transition‐Associated Ferroelectricity and Piezoelectric Energy Harvesting in 0D Halogenozincate Hybrid via Cation's Terminal Group Lengthening

    Small Methods · 2025-05-24

    Caihong Shi, Caihong Shi, Si‐Yu Deng, Jun‐Yi Li, Hao‐Ran Chen, Qing‐Ling Cao, Wen‐He Zhong, Jieyu Zhu, Shuai Shao, Wei Bao, Hao Du, Li-Zhuang Chen, Chao Yi Shi, Chao Yi Shi, Jiajia Zhao

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  10. Mathematical Double‐Matrix Switchable Homochiral Ferroelectric

    Angewandte Chemie International Edition · 2025-07-02

    Xian‐Jiang Song, Yan Fang Qin, Yong Ai, Xiao‐Gang Chen, Yan‐Ran Weng, Hang Peng, Hui‐Peng Lv, Ren‐Gen Xiong, Wei‐Qiang Liao

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  11. Mathematical Double‐Matrix Switchable Homochiral Ferroelectric

    Angewandte Chemie · 2025-07-02

    Xian‐Jiang Song, Yan Fang Qin, Yong Ai, Xiao-Gang Chen, Yan‐Ran Weng, Hang Peng, Hui‐Peng Lv, Ren‐Gen Xiong, Wei‐Qiang Liao

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  12. Metal‐Free Molecular Debye‐Type Relaxor Ferroelectric Crystals Enable Broadband Photo‐Pyroelectric Detection

    Advanced Materials · 2025-09-30

    Qingshun Fan, Pengfei Zhu, Yi Liu, Yu Ma, Liwei Tang, Wenjing Li, Jingtian Zhang, Linjie Wei, Junhua Luo, Zhihua Sun

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  13. Achieving Combined Photoluminescence and SHG in a New Polar Hybrid Glass‐Ceramic with Square‐Pyramidal [SbBr 5 ] Units

    Angewandte Chemie · 2025-11-02

    Ding‐Chong Han, Yanan Fan, Shuai Chen, Yu Wang, Zuoling Fu, Zijun Fang, Wei‐Xiong Zhang

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  14. Achieving Combined Photoluminescence and SHG in a New Polar Hybrid Glass‐Ceramic with Square‐Pyramidal [SbBr 5 ] Units

    Angewandte Chemie International Edition · 2025-11-02

    Ding‐Chong Han, Yanan Fan, Shuai Chen, Yu Wang, Zhou‐Yu Fu, Zijun Fang, Wei‐Xiong Zhang

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  15. Molecular Symmetry and Geometry Engineering for High‐Temperature Ferroelectricity and Low Coercive Field in Hybrid Metal Halides

    Angewandte Chemie · 2025-11-23

    Shu‐Yin Jia, Chao‐Yang Chai, Qiang‐Qiang Bi, Xiaobin Fu, Chengdong Liu, Ming‐Liang Jin, Jing‐Meng Zhang, Wei Qiang Wang, Jili Wu, Rui Zuo, Feiyang Li, Wen Zhang

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  16. Molecular Symmetry and Geometry Engineering for High‐Temperature Ferroelectricity and Low Coercive Field in Hybrid Metal Halides

    Angewandte Chemie International Edition · 2025-11-23

    Shu‐Yin Jia, Chao‐Yang Chai, Qiang‐Qiang Bi, Xiaobin Fu, Chengdong Liu, Ming‐Liang Jin, Jing‐Meng Zhang, Wei Qiang Wang, Jili Wu, Rui Zuo, Feiyang Li, Wen Zhang

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  17. Thermochromic Hybrid Ferroelastic Semiconductor with Thermal/Electrical/Optical Switching Responses

    Inorganic Chemistry · 2026-03-02

    Yan-Juan Wang, Ye Du, Xiao-Yu Zhang, Yan‐Ran Weng, Yan Qin, Lin Zhou, Yuan‐Yuan Tang

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  18. Cation ordering and metal anisotropy enable ferroelectricity and single molecule magnets behavior in a Co-based molecular crystal

    Chinese Chemical Letters · 2026-06-01

    Kai‐Ping Xie, Zi-Luo Fang, Kai-Ye Lin, Xiao-Yin Weng, Peng-Peng Gong, Rong Lin, Bo Huang, Yun-Xia Qu, Zi-Cheng Xiao, Yuan Chen, Yi-Fei Deng, Wei‐Jian Xu, Jiang Liu

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  19. Recent advances in supramolecular ferroelectrics based on macrocycles and cages

    Materials Today Chemistry · 2026-08-01

    Shuai Cao, Fei Chen, Mingyue Zou, Huacheng Zhang, Quan Diao, Zhixin Wang, Zhongzhu Liu, Mingli Jiao

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  20. Guest conformational rigidification and solid solution in a supramolecular cage Compound: Molecular Dynamics, phase Transition, ferroelectricity and fluorescence

    Materials & Design · 2026-10-01

    Rongfu Zhou, Xiao-Geng Yang, Lin-Yong Sheng, Wenbing Yuan, Si‐Guo Wu, He Chun-Ting, Takayoshi Nakamura, Ruikang Huang, Zi‐Yi Du

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  21. From challenges to solutions: insights into AIEgen-based diagnostic and therapeutic strategies for breast cancer

    Coordination Chemistry Reviews · 2026-10-09

    Yunwei Yu, Jiawei Zhao, Jie Li, Jun Li, Xiaoyu Xu, Huazhen Liang, Chao Yuan, Siwei Dong, Meijia Gu, Zhiqiang Li

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