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RESEARCH PAPER · Chemical Society Reviews · 2024

Anion⋯anion self-assembly under the control of σ- and π-hole bonds

Andrea Pizzi, Arun Dhaka, Roberta Beccaria, Giuseppe Resnati

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Anion⋯anion self-assembly under the control of σ- and π-hole bondsOriginalIntermolecular non-covalent interactions in the organic perrhenates crystal structures: from theory to practice4Tetrel Bond Affects the Self‐Assembly of Acetylcholine and its Analogues and is an Ancillary Interaction in Protein Binding5IUPAC Recommendations: (Un)equivocal Understanding of Hydrogen and Halogen Bonds and Their (Un)equivocal Naming!5A Computational DFT Study of the Stereoinversion of Succinimide Residues Formed in Proteins and Peptides Catalyzed by a Hydrogen Phosphate Ion: An Unsymmetrical SE1 Mechanism1The Lattice Mismatch-Driven Photochemical Self-Assembly of Supported Heterostructures for Stable and Enhanced Electrocatalytic Carbon Dioxide Reduction Reaction0Accessible and Effective Nanomedicines: Self‐Assembly Products From Chinese Herbal Medicines (CHMs)50Ammonium 18-crown-6 complexes with tetrahedral monoanions: X-ray, thermal and comparative analysis of non-covalent interactions2Exploring coinage bonding interactions in [Au(CN) 4 ] − assemblies with silver and zinc complexes: a structural and theoretical study6Halonium and chalconium salt-catalyzed Schiff condensation: kinetics and DFT insights into organocatalyst activity parameters15Noble gas bonds facilitate anion⋯anion supramolecular assemblies: insights from CSD and DFT analysis4Phenolized lignin binders inducing ultrathin SEI of hard carbon for advanced sodium storage0Pillar[5]arene-based ionic single crystals formed by dual self-assemblies through host–guest and ionic interactions for iodine capture5Proton delocalization in short hydrogen bonds assembling HSeO 4 − anions into supramolecular adducts6Tuning probe permeability via chalcogen and halogen atom substitution for monitoring alkaline phosphatase activity in mammalian cells9Unusually short Au( iii )⋯Au( iii ) aurophilic contacts between anions. Necessity of counterions2Upgrade of Weak σ‐Hole Bond Donors via Cr(CO) 3 Complexation8127 I Solid‐State NMR Spectroscopy of Organic Periodates Featuring Halogen Bonded IO 4 − ⋅ ⋅ ⋅ IO 4 − Adducts7The Role of Chalcogen Bonding in Organic Dichalcogenides of Biological Interest3Chalcogen-Bonded [Se–N]2 Cyclic Supramolecular Synthons Enhanced by Halogen Bonds: Studies in the Gas Phase and Crystalline Phase4Perfluoroaromatic Bisselanes: From Molecular Design to Supramolecular Architecture Through Tandem σ/π‐hole Interactions8Regulating Extra‐Layer Ion Channels in the Conductive V 2 O 5 Hydrogel Cathode5In silico, in vitro, and in vivo assessment of anti-Trypanosoma cruzi activity of the 1H-indazole-containing ruthenium complex FOR0E24Taxonomy of Chemical Bondings: Opportunities and Challenges5Taxonomy of Chemical Bondings: Opportunities and Challenges37When CuCl 4 2– and CuBr 4 2– Form Anion···Anion Networks Assembled via Cu···Cl/Br Regium Bonds9Comparative Studies on the Structural, Optical, and Electrical Properties of Two [Co(II) and Ni(II)] Complexes: Insights through Theoretical Analysis8Anion-Induced Self-Assembly of Bis(cyclopeptides) with Rigid Linkers2Cooperativity of chalcogen and halogen bonding in cocrystals of PdII and PtII acetylacetonates with perfluoroarene selanes: Impact of the arene iodination on supramolecular architecture13Revisiting the Methyl Group as a Nonconventional Electron Donor in Triel, Tetrel, Pnictogen, Chalcogen, and Halogen Bonding8Speciation and Complex Formation of Zirconium(IV) with Tc(VII) and Re(VII) in Liquid–Liquid Extraction Systems1Anion-Controlled Regioselectivity in Halonium-Mediated Arylations: A Kinetic and Mechanistic Study2Positional Control of σ- and π-Hole Directionality in Iodoselane Cocrystals: Structural Impact of the Iodine Position on the Supramolecular Assembly with 1,4-Diazabicyclo[2.2.2]octane (DABCO)7Structural Evidence of Interanionic Hydrogen Bonding in Phosphoric Acid Solutions9Multidentate halogen bond acceptors: from fluorides to iodides. Anticooperativity in halogen-bonded clusters0From fluorine chemistry to noncovalent interactions: celebrating Prof. Giuseppe Resnati1Group 9 elements as donors of hole bonds0Phenolized lignin binders inducing ultrathin SEI of hard carbon for advanced sodium storage0Stabilizing Anion–Anion Aggregates via Dihydrogen Bonds in Non‐Classical Inorganic Molecules0Supramolecular anion⋯anion motifs in dichromate hybrid salts and their detection through 53 Cr SSNMR0Ruthenium Complexes Containing Thiobenzamide Act as Potent and Selective Anti- Trypanosoma cruzi Agents through Apoptotic Cell Death1Cooperative, anti-cooperative, and synergistic supramolecular interactions mediate self-organization of self-assembling dendrons, dendrimers, and dendronized macromolecules5Fundamentals and solid-state applications of π-hole-driven molecular recognition6Anion-directed structural hierarchies in a new o-chloroanilinium salt: Comparative crystallographic insights across the o-chloroanilinium family1Chiral Cyclic Hypervalent Iodine(III) for Halogen Bonding–Mediated Dimerization and Modulable Chirality Induction in Solution0Anion···π interactions and hydrogen bonds in cyanidometallate-based co-crystal systems: novel synthons, functional properties, and stories behind them2Experimental and theoretical studies of technetium complexes with N-heterocycles: Tc N vs Tc=O1Hydrogen Bond Triggers the Self-Assembly of Dihydrogen Arsenates into Supramolecular Anion⋯Anion Adducts1Conformationally Adaptive SERS Receptors: Reconfiguring Binding Environments via Dynamic Gauche – Trans Transitions for Broad-Spectrum Ion Sensing0Terminal Substituent Control of Trifunctional σ/π-Hole Donor Behavior in Iodoselane Cocrystals: From Discrete Heterotrimers to Extended Polymeric Networks0Anti-Electrostatic Anion-Anion Noncovalent Interactions Are Not Halogen Bonds: Evidence from X···O Contacts in XO4− Dimers and Oligomers in Crystals Structures1Decoction-derived nano-granules from traditional Chinese medicine for drug delivery0Deriving General Energy Predictors for Pnictogen Bonding0Ion Enrichment‐Mediated Charge Transfer in CNTs‐Based Films for Infrared Electrochromism0Phenolized lignin binders inducing ultrathin SEI of hard carbon for advanced sodium storage0Halide-Dependent Structure and Pressure-Induced Electronic Evolution in DABCO-Stabilized Polyiodide Frameworks0Charge-dipole bound anion-anion complexes0Molecular Recognition by Halogen Bonding With Atomic Precision in a Covalent Organic Cage0Molecular Recognition by Halogen Bonding With Atomic Precision in a Covalent Organic Cage0

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  2. Tetrel Bond Affects the Self‐Assembly of Acetylcholine and its Analogues and is an Ancillary Interaction in Protein Binding

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  3. IUPAC Recommendations: (Un)equivocal Understanding of Hydrogen and Halogen Bonds and Their (Un)equivocal Naming!

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    E. Arunan, Pierangelo Metrangolo, Giuseppe Resnati, Steve Scheiner

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  4. A Computational DFT Study of the Stereoinversion of Succinimide Residues Formed in Proteins and Peptides Catalyzed by a Hydrogen Phosphate Ion: An Unsymmetrical SE1 Mechanism

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  5. The Lattice Mismatch-Driven Photochemical Self-Assembly of Supported Heterostructures for Stable and Enhanced Electrocatalytic Carbon Dioxide Reduction Reaction

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  6. Accessible and Effective Nanomedicines: Self‐Assembly Products From Chinese Herbal Medicines (CHMs)

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  7. Ammonium 18-crown-6 complexes with tetrahedral monoanions: X-ray, thermal and comparative analysis of non-covalent interactions

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  8. Exploring coinage bonding interactions in [Au(CN) 4 ] − assemblies with silver and zinc complexes: a structural and theoretical study

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  9. Halonium and chalconium salt-catalyzed Schiff condensation: kinetics and DFT insights into organocatalyst activity parameters

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  10. Noble gas bonds facilitate anion⋯anion supramolecular assemblies: insights from CSD and DFT analysis

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  11. Phenolized lignin binders inducing ultrathin SEI of hard carbon for advanced sodium storage

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  12. Pillar[5]arene-based ionic single crystals formed by dual self-assemblies through host–guest and ionic interactions for iodine capture

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  13. Proton delocalization in short hydrogen bonds assembling HSeO 4 − anions into supramolecular adducts

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  14. Tuning probe permeability via chalcogen and halogen atom substitution for monitoring alkaline phosphatase activity in mammalian cells

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  15. Unusually short Au( iii )⋯Au( iii ) aurophilic contacts between anions. Necessity of counterions

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  16. Upgrade of Weak σ‐Hole Bond Donors via Cr(CO) 3 Complexation

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  17. 127 I Solid‐State NMR Spectroscopy of Organic Periodates Featuring Halogen Bonded IO 4 − ⋅ ⋅ ⋅ IO 4 − Adducts

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  18. The Role of Chalcogen Bonding in Organic Dichalcogenides of Biological Interest

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  19. Chalcogen-Bonded [Se–N]2 Cyclic Supramolecular Synthons Enhanced by Halogen Bonds: Studies in the Gas Phase and Crystalline Phase

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  20. Perfluoroaromatic Bisselanes: From Molecular Design to Supramolecular Architecture Through Tandem σ/π‐hole Interactions

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  21. Regulating Extra‐Layer Ion Channels in the Conductive V 2 O 5 Hydrogel Cathode

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  23. Taxonomy of Chemical Bondings: Opportunities and Challenges

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  25. When CuCl 4 2– and CuBr 4 2– Form Anion···Anion Networks Assembled via Cu···Cl/Br Regium Bonds

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  27. Anion-Induced Self-Assembly of Bis(cyclopeptides) with Rigid Linkers

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  31. Anion-Controlled Regioselectivity in Halonium-Mediated Arylations: A Kinetic and Mechanistic Study

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  32. Positional Control of σ- and π-Hole Directionality in Iodoselane Cocrystals: Structural Impact of the Iodine Position on the Supramolecular Assembly with 1,4-Diazabicyclo[2.2.2]octane (DABCO)

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  33. Structural Evidence of Interanionic Hydrogen Bonding in Phosphoric Acid Solutions

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  34. Multidentate halogen bond acceptors: from fluorides to iodides. Anticooperativity in halogen-bonded clusters

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  38. Stabilizing Anion–Anion Aggregates via Dihydrogen Bonds in Non‐Classical Inorganic Molecules

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  39. Supramolecular anion⋯anion motifs in dichromate hybrid salts and their detection through 53 Cr SSNMR

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  40. Ruthenium Complexes Containing Thiobenzamide Act as Potent and Selective Anti- Trypanosoma cruzi Agents through Apoptotic Cell Death

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  45. Anion···π interactions and hydrogen bonds in cyanidometallate-based co-crystal systems: novel synthons, functional properties, and stories behind them

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  46. Experimental and theoretical studies of technetium complexes with N-heterocycles: Tc N vs Tc=O

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  47. Hydrogen Bond Triggers the Self-Assembly of Dihydrogen Arsenates into Supramolecular Anion⋯Anion Adducts

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  50. Anti-Electrostatic Anion-Anion Noncovalent Interactions Are Not Halogen Bonds: Evidence from X···O Contacts in XO4− Dimers and Oligomers in Crystals Structures

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