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RESEARCH PAPER · Angewandte Chemie International Edition · 2024

Superionic Conduction in K3SbS4 Enabled by Cl‐Modified Anion Lattice

Yudan Chen, Pengbo Wang, Erica Truong, Bright O. Ogbolu, Yongkang Jin, Ifeoluwa Peter Oyekunle, Haoyu Liu, Md. Mahinur Islam, Tej Prasad Poudel, Chen Huang, Ivan Hung, Zhehong Gan, Yan‐Yan Hu

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Superionic Conduction in K3SbS4 Enabled by Cl‐Modified Anion LatticeOriginalStable solid-state potassium metal batteries enabled by a KB 11 H 14 ·2Me 3 NBH 3 complex electrolyte3Solid-state inorganic electrolytes for next generation potassium batteries29Inducing amorphous domains by P-doping to improve the Li-ion storage capacity of Nb2O5 anode10Cl-Doped Cubic K3SbS4 as a Solid-State Electrolyte for K-Ion Batteries with Ultrafast Ionic Conductivity5Li 1.6 AlCl 3.4 S 0.6 : a low-cost and high-performance solid electrolyte for solid-state batteries11Li 3.6 In 7 S 11.8 Cl: an air- and moisture-stable superionic conductor6Room Temperature Operation of All‐Solid‐State Potassium‐Ion Battery Enabled by Unconventional Ionic Solid Electrolyte K 6 [Rh 4 Zn 4 ( l ‐cys) 12 O]· n H 2 O1Status and Challenges of Solid‐State Electrolytes for Potassium Batteries13Fast Potassium‐Ion Conduction in K3LnSi3O9 (Ln = Y and Gd) Enabled by P‐Doping Toward Ultrastable Quasi‐Solid‐State Batteries8Mg-Ion Conduction in Antiperovskite Solid Electrolytes Revealed by 25Mg Ultrahigh Field NMR and First-Principles Calculations2Modulating Lithium‐Ion Transport in LiAlBr4 via S‐Modified Anion Sublattice1High-valent manganese promotes percolating K-vacancy networks to boost bulk K + conduction in K 2− γ Mn x Fe 4− x O 7− δ0Molecular Design of Crystalline Potassium Pyridonate Electrolytes for All-Solid-State Potassium Metal Batteries3Effect of Cl-Doping on K 3 PS 4 as a Superionic Solid Electrolyte for K-Ion Batteries0Synergistic Ionicity and Phase Regulation Enable Ultrahigh Potassium-Ion Conductivity in KxMg(1+x)/3Sb(2-x)/3O20Polymorphism in K3SbS4 and the Role of Tungsten Substitution on Structure and Potassium-Ion Conductivity1

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  1. Stable solid-state potassium metal batteries enabled by a KB 11 H 14 ·2Me 3 NBH 3 complex electrolyte

    Inorganic Chemistry Frontiers · 2024-01-01

    Guo-guo Zhang, Pengtao Qiu, Jiaxin Kang, Zhiwei Lu, An-Qi Zhu, Xiaohu Yu, Xuenian Chen

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  2. Solid-state inorganic electrolytes for next generation potassium batteries

    Communications Materials · 2024-07-20

    Jonas Grill, Simon Krarup Steensen, Diana Lucia Quintero-Castro, Ivano E. Castelli, Jelena Popović

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  3. Inducing amorphous domains by P-doping to improve the Li-ion storage capacity of Nb2O5 anode

    Journal of Energy Storage · 2024-10-22

    Huiqiao Liu, Sitian Wang, Jiahui Ma, Yulian Dong, Lisha Liang, Chao Li, Yang Fan, Yong Lei, Kangzhe Cao

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  4. Cl-Doped Cubic K3SbS4 as a Solid-State Electrolyte for K-Ion Batteries with Ultrafast Ionic Conductivity

    Chemistry of Materials · 2024-12-12

    Rongyu Zhang, Yongjun Zhou, Shifeng Xu, Liyan Wang, Dan Yang Xu, Wenbo Li, Xing Meng, Xu Yang, Yi Zeng, Fei Du

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  5. Li 1.6 AlCl 3.4 S 0.6 : a low-cost and high-performance solid electrolyte for solid-state batteries

    Chemical Science · 2025-01-01

    Tej Prasad Poudel, Ifeoluwa Peter Oyekunle, Michael J. Deck, Yudan Chen, Dewen Hou, Pawan Kumar Ojha, Bright O. Ogbolu, Chen Huang, Hui Xiong, Yan‐Yan Hu

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  6. Li 3.6 In 7 S 11.8 Cl: an air- and moisture-stable superionic conductor

    Chemical Science · 2025-01-01

    Ifeoluwa Peter Oyekunle, Erica Truong, Tej Prasad Poudel, Yudan Chen, Yongkang Jin, Islamiyat A. Ojelade, Michael J. Deck, Bright O. Ogbolu, Md. Mahinur Islam, Pawan Kumar Ojha, J. S. Raaj Vellore Winfred, Dewen Hou, Hui Xiong, Chen Huang, Yan‐Yan Hu

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  7. Room Temperature Operation of All‐Solid‐State Potassium‐Ion Battery Enabled by Unconventional Ionic Solid Electrolyte K 6 [Rh 4 Zn 4 ( l ‐cys) 12 O]· n H 2 O

    Chemistry - An Asian Journal · 2025-04-08

    Ryo Sakamoto, Kosuke Nakamoto, Atsushi Inoishi, Masato Ito, Nobuto Yoshinari, Takumi Konno, Yukihiro Hara, Takafumi Fujii, Shigeto Okada

    Read original paper ↗ ·

  8. Status and Challenges of Solid‐State Electrolytes for Potassium Batteries

    Small · 2025-05-02

    Kangzhe Cao, Jiahui Ma, Ziwei Yue, Huimin Li, Yang Fan, Huiqiao Liu

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  9. Fast Potassium‐Ion Conduction in K3LnSi3O9 (Ln = Y and Gd) Enabled by P‐Doping Toward Ultrastable Quasi‐Solid‐State Batteries

    Advanced Materials · 2025-07-24

    Shuhong Yi, Chenlong Gao, Qingfeng Fu, Shunqing Wu, Jian‐Fang Wu, Yan Qing Duan, Menghao Yang, Jilei Liu

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  10. Mg-Ion Conduction in Antiperovskite Solid Electrolytes Revealed by 25Mg Ultrahigh Field NMR and First-Principles Calculations

    Journal of the American Chemical Society · 2025-07-24

    David M. Halat, Haoyu Liu, Kwangnam Kim, Grant C. B. Alexander, Xiao-Ling Wang, Amrit Venkatesh, Adam R. Altenhof, Harris E. Mason, Saul H. Lapidus, Jeong Seop Yoon, Ivan Hung, Zhehong Gan, Jordi Cabana, Donald J. Siegel, Jeffrey A. Reimer, Baris Key

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  11. Modulating Lithium‐Ion Transport in LiAlBr4 via S‐Modified Anion Sublattice

    ChemSusChem · 2025-08-09

    Ifeoluwa Peter Oyekunle, Tej Prasad Poudel, Yudan Chen, Erica Truong, Islamiyat A. Ojelade, Pawan Kumar Ojha, Md. Mahinur Islam, Yongkang Jin, Yan‐Yan Hu

    Read original paper ↗ ·

  12. High-valent manganese promotes percolating K-vacancy networks to boost bulk K + conduction in K 2− γ Mn x Fe 4− x O 7− δ

    Chemical Communications · 2026-01-01

    Zhuangzhuang Chen, Liping Li, Taotao Huang, Junhong Zhou, Yaowen Wang, Xu Han, Yuhan Yi, Guangshe Li

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  13. Molecular Design of Crystalline Potassium Pyridonate Electrolytes for All-Solid-State Potassium Metal Batteries

    Journal of the American Chemical Society · 2026-04-06

    Khai Chen Tan, Zhaoji Huang, Yang Yu, Jiaquan Guo, Shangshang Wang, Yuting Wang, Xiaofeng Li, Anan Wu, Teng He, Ping Chen

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  14. Effect of Cl-Doping on K 3 PS 4 as a Superionic Solid Electrolyte for K-Ion Batteries

    Inorganic Chemistry · 2026-04-28

    Wei Tian, Xu Yang, Yongjun Zhou, Shifeng Xu, Liyan Wang, Di Yang, Di Jin, Rongyu Zhang

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  15. Synergistic Ionicity and Phase Regulation Enable Ultrahigh Potassium-Ion Conductivity in KxMg(1+x)/3Sb(2-x)/3O2

    Nano Letters · 2026-07-29

    Xinyi Kong, Yingying Wu, Xingyu Li, Jian Zhou, Jian‐Fang Wu, Tao Zhang, Jilei Liu

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  16. Polymorphism in K3SbS4 and the Role of Tungsten Substitution on Structure and Potassium-Ion Conductivity

    ACS Applied Energy Materials · 2026-08-06

    Matthias Hartmann, Phuong Nam Le Pham, Jacob C. Hickey, Alexandra Morscher, Marvin A. Kraft, Max Wacha, Eamonn T. Connolly, Lucy K. Saunders, Jürgen Janek, Wolfgang G. Zeier, Xabier Martínez de Irujo-Labalde

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