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RESEARCH PAPER · Chemistry of Materials · 2024

Unified Roadmap for ZIF-8 Nucleation and Growth: Machine Learning Analysis of Synthetic Variables and Their Impact on Particle Size and Morphology

Juan A. Allegretto, Diego Onna, Sara A. Bilmes, Omar Azzaroni, Matías Rafti

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Unified Roadmap for ZIF-8 Nucleation and Growth: Machine Learning Analysis of Synthetic Variables and Their Impact on Particle Size and MorphologyOriginalBayesian Optimization Enhanced Neural Networks for Predicting Metal-Organic Framework Morphology: A Zif-8 Synthesis Case Study21Machine Learning Approaches to Analyze the Effect of Reaction Parameters on Zif-8 Synthesis6Benefits and complexity of defects in metal-organic frameworks85Recent developments on the design of advanced porous materials based on Metal Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), and their combinations into composites as sorbents in sample preparation and chromatographic applications0Unraveling MOF growth in colloids with controllable dual-doping through ultrafast sintering for wide temperature range LIBs4Machine learning based insights for metal-organic frameworks synthesis: A comparative and explainable analysis of ZIF-8 morphology11Insights into zeolite imidazole frameworks (ZIFs) for CO2 capture and separation: A short review19Optimizing ZIF-8 membrane growth on top of semiconductive Ga-doped ZnO sensitive layers3Synthesis methods, structure, and recent trends of ZIF-8-based materials in the biomedical field85Dual-Stage Stacking Machine Learning Method Considering Virtual Sample Generation for the Prediction of ZIF-8′ BET Specific Surface Area with Experimental Validation5MOF membranes for gas separations141Amorphous-to-Crystalline Transformation: How Cluster Aggregation Drives the Multistep Nucleation of ZIF-832Preparation of Si@CZIF-8 composites and their electrochemical energy storage performance1Comparison of laboratory-acquired ZIF-8 drug delivery-related parameters with literature-based data via machine learning tools1Data-driven approaches for autonomous experimentation: Insights into modeling and prediction dynamics of metal–organic frameworks synthesis0Enhanced antibacterial activity of ZIF-8 and ZIF-67 loaded Mn0.5/Ce0.5 mixed Oxide–Hydroxyapatite composites5Noninvasive and Sensitive Biosensor for the Detection of Oral Cancer Prognostic Biomarkers10Biotemplated self-assembly of ZIF-8 on Vischeria sp. WL1 for efficient uranium removal3In Situ Formation of Zeolitic Imidazolate Frameworks on Nanocellulose Revealed by Time-Resolved Synchrotron Small-Angle and Wide-Angle X-ray Scattering8Synthesis, characterization and evaluation of ZIF-8/CMC composites loaded with eugenol for sustained antimicrobial activity4Intercrystalline defect healing in polycrystalline MOF membranes by pressurized counter-diffusion secondary growth2Transfer learning-based modeling of synthesis-particle size relationships in metal-organic frameworks3Recent progress in the synthesis, scaling, processing and technoeconomic analysis of metal-organic frameworks towards industrial applications30Incremental learning with heterogeneous data for morphology prediction in metal-organic frameworks1Advances and challenges of ZIF-based nanocomposites in immunotherapy and anti-inflammatory therapy8Cellulose/zeolitic imidazolate framework (ZIF) hybrid: Recent progress in synthesis and applications4In situ growth of defect-minimized ZIF-8 membranes suitable for practical propylene/propane separation processes: Elucidation of mechanistic insights into ZIF-8 crystal growth led to an optimal synthetic route2Metal–Organic Frameworks as Synergistic Scaffolds in Biomass Fermentation: Evolution from Passive Adsorption to Active Catalysis6Biocompatible chitosan-coated polydatin@ZIF-8 MOF nanostructures: synthesis, drug delivery and enhanced antibacterial properties3Defects in MOFs0Zn metal organic framework tailored cellulose acetate/PVdF- co -HFP based proton conductive composite membranes: performance enhancement in direct methanol fuel cells2Review: advances in MOF-based composites for supercapacitor applications8Rational Design of High-Quality ZIF-8 Membranes: Machine Learning-Guided Optimization of ALD ZnO Conversion6Covalently bonded amino-functionalized ZIF-8 on Cu2O for photocatalytic reduction of low-concentration CO22Transformation of metal organic frameworks into mono and bimetallic metal oxides for photocatalysis process: a review4Metal-organic frameworks for catalytic degradation of emerging dye contaminants in wastewater: A critical review of material design, reaction mechanisms, and engineering application12Recent advances in the architecture of ZIF-8 and derived porous carbon for drug delivery applications0Direct Visualization of MOF Film CVD Growth Using a Dual-Heating Zone In Situ TEM Microreactor0In Situ Ultrasound Monitoring of Fast ZIF-8 Nanoparticle Synthesis0Learning Synthesis and Property Measurements of Nanoporous Metal–Organic Framework ZIF-80Recent advances in ZIF-67-based composites for heavy and radioactive metal ion removal: synthesis, adsorption mechanisms, performance assessment, and future directions0Biocatalytic membranes anchored with zeolitic imidazolate framework‑8 for enhanced trypsin loading and efficient proteolysis0Orientational Order of Linkers Controls ZIF-8 Crystallization0Large-scale preparation of hollow Fe3O4–ZIF8 composite templated by microalgae and efficient U(VI) adsorption0Machine Learning-Guided Design of ZIF-8 Polymer Nanocomposites for Sustainable Applications: Current Progress and Future Opportunities0Can Small Language Models Learn Materials Synthesis From Limited Experiments? A ZnO‐to‐ZIF‐8 Case Study0ZIF-8 functionalized with eucalyptol and thymol for antibacterial applications0Smart design of crocin-loaded ZIF-8 nanoparticles via design of experiments and machine learning: physicochemical characterization and a molecular dynamics simulation study0

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  1. Bayesian Optimization Enhanced Neural Networks for Predicting Metal-Organic Framework Morphology: A Zif-8 Synthesis Case Study

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  2. Machine Learning Approaches to Analyze the Effect of Reaction Parameters on Zif-8 Synthesis

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  3. Benefits and complexity of defects in metal-organic frameworks

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  4. Recent developments on the design of advanced porous materials based on Metal Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), and their combinations into composites as sorbents in sample preparation and chromatographic applications

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  5. Unraveling MOF growth in colloids with controllable dual-doping through ultrafast sintering for wide temperature range LIBs

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  6. Machine learning based insights for metal-organic frameworks synthesis: A comparative and explainable analysis of ZIF-8 morphology

    Materials Today Communications · 2024-11-30

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  7. Insights into zeolite imidazole frameworks (ZIFs) for CO2 capture and separation: A short review

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    Junmei Yu, Kai Qi, Xuelian Li, Lili Gao, Jiancheng Wang, Jian Zeng, Shixun Du

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  8. Optimizing ZIF-8 membrane growth on top of semiconductive Ga-doped ZnO sensitive layers

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  9. Synthesis methods, structure, and recent trends of ZIF-8-based materials in the biomedical field

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  10. Dual-Stage Stacking Machine Learning Method Considering Virtual Sample Generation for the Prediction of ZIF-8′ BET Specific Surface Area with Experimental Validation

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  11. MOF membranes for gas separations

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  12. Amorphous-to-Crystalline Transformation: How Cluster Aggregation Drives the Multistep Nucleation of ZIF-8

    Journal of the American Chemical Society · 2025-03-03

    Ahmet Dok, Sambhu Radhakrishnan, Flip de Jong, Estelle Becquevort, Olivier Deschaume, C. Vinod Chandran, Yovan de Coene, Carmen Bartic, Mark Van der Auweraer, Wim Thielemans, Christine E. A. Kirschhock, Monique Ann van der Veen, Thierry Verbiest, Eric Breynaert, Stijn Van Cleuvenbergen

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  13. Preparation of Si@CZIF-8 composites and their electrochemical energy storage performance

    Colloids and Surfaces A Physicochemical and Engineering Aspects · 2025-06-03

    Juan Liao, Huang Zhengqian, Lan Jiayi, Gan Linfeng, Zhang Ruibo, Qi Jiang

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  14. Comparison of laboratory-acquired ZIF-8 drug delivery-related parameters with literature-based data via machine learning tools

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  15. Data-driven approaches for autonomous experimentation: Insights into modeling and prediction dynamics of metal–organic frameworks synthesis

    MRS Communications · 2025-06-16

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  16. Enhanced antibacterial activity of ZIF-8 and ZIF-67 loaded Mn0.5/Ce0.5 mixed Oxide–Hydroxyapatite composites

    Materials Chemistry and Physics · 2025-07-24

    Piaw Phatai, Sakuntala Siri-udom, Pongtanawat Khemthong, Saran Youngjan, Teera Butburee, Wuttichai Roschat, Rattabal Khunphonoi, Cybelle M. Futalan, Sirilak Kamonwannasit, Khongvit Prasitnok, Orrasa Prasitnok, Orrasa Prasitnok

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  17. Noninvasive and Sensitive Biosensor for the Detection of Oral Cancer Prognostic Biomarkers

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  18. Biotemplated self-assembly of ZIF-8 on Vischeria sp. WL1 for efficient uranium removal

    Biochemical Engineering Journal · 2025-08-05

    Changhuang Cao, Chaoli Shao, Wei Zhang, Yuantao Chen, Shutian Liu, Ting Zhang

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  19. In Situ Formation of Zeolitic Imidazolate Frameworks on Nanocellulose Revealed by Time-Resolved Synchrotron Small-Angle and Wide-Angle X-ray Scattering

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  20. Synthesis, characterization and evaluation of ZIF-8/CMC composites loaded with eugenol for sustained antimicrobial activity

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  21. Intercrystalline defect healing in polycrystalline MOF membranes by pressurized counter-diffusion secondary growth

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  22. Transfer learning-based modeling of synthesis-particle size relationships in metal-organic frameworks

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  23. Recent progress in the synthesis, scaling, processing and technoeconomic analysis of metal-organic frameworks towards industrial applications

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  24. Incremental learning with heterogeneous data for morphology prediction in metal-organic frameworks

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  25. Advances and challenges of ZIF-based nanocomposites in immunotherapy and anti-inflammatory therapy

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  27. In situ growth of defect-minimized ZIF-8 membranes suitable for practical propylene/propane separation processes: Elucidation of mechanistic insights into ZIF-8 crystal growth led to an optimal synthetic route

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  28. Metal–Organic Frameworks as Synergistic Scaffolds in Biomass Fermentation: Evolution from Passive Adsorption to Active Catalysis

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  29. Biocompatible chitosan-coated polydatin@ZIF-8 MOF nanostructures: synthesis, drug delivery and enhanced antibacterial properties

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  30. Defects in MOFs

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  31. Zn metal organic framework tailored cellulose acetate/PVdF- co -HFP based proton conductive composite membranes: performance enhancement in direct methanol fuel cells

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  32. Review: advances in MOF-based composites for supercapacitor applications

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  33. Rational Design of High-Quality ZIF-8 Membranes: Machine Learning-Guided Optimization of ALD ZnO Conversion

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  34. Covalently bonded amino-functionalized ZIF-8 on Cu2O for photocatalytic reduction of low-concentration CO2

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  36. Metal-organic frameworks for catalytic degradation of emerging dye contaminants in wastewater: A critical review of material design, reaction mechanisms, and engineering application

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  37. Recent advances in the architecture of ZIF-8 and derived porous carbon for drug delivery applications

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  38. Direct Visualization of MOF Film CVD Growth Using a Dual-Heating Zone In Situ TEM Microreactor

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  39. In Situ Ultrasound Monitoring of Fast ZIF-8 Nanoparticle Synthesis

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  40. Learning Synthesis and Property Measurements of Nanoporous Metal–Organic Framework ZIF-8

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  41. Recent advances in ZIF-67-based composites for heavy and radioactive metal ion removal: synthesis, adsorption mechanisms, performance assessment, and future directions

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  42. Biocatalytic membranes anchored with zeolitic imidazolate framework‑8 for enhanced trypsin loading and efficient proteolysis

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  43. Orientational Order of Linkers Controls ZIF-8 Crystallization

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  44. Large-scale preparation of hollow Fe3O4–ZIF8 composite templated by microalgae and efficient U(VI) adsorption

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  45. Machine Learning-Guided Design of ZIF-8 Polymer Nanocomposites for Sustainable Applications: Current Progress and Future Opportunities

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  46. Can Small Language Models Learn Materials Synthesis From Limited Experiments? A ZnO‐to‐ZIF‐8 Case Study

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  47. ZIF-8 functionalized with eucalyptol and thymol for antibacterial applications

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  48. Smart design of crocin-loaded ZIF-8 nanoparticles via design of experiments and machine learning: physicochemical characterization and a molecular dynamics simulation study

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