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RESEARCH PAPER · Organic Letters · 2024

Difluorocarbene Enables Access to 2,2-Difluorohydrobenzofurans and 2-Fluorobenzofurans from ortho -Vinylphenols

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Difluorocarbene Enables Access to 2,2-Difluorohydrobenzofurans and 2-Fluorobenzofurans from ortho -VinylphenolsOriginalFive-membered ring systems: furans and benzofurans0Difluorocarbene-Enabled Dehydration of Primary Amides To Access Nitriles6Synthesis of 2‐Fluoropyrroles via [4 + 1] Cycloaddition of α,β‐Unsaturated Imines with In Situ‐Generated Difluorocarbene3Silver-Catalyzed Difluorocarbene Activation Enables Multicomponent Synthesis of δ,γ-Unsaturated β-Hydroxynitriles1Difluorocarbene-enabled selective Csp 3 –N bond cleavage in aliphatic tertiary amines to access sulfilimines and sulfoximines1Diastereoselective Synthesis of Difluoromethylene—Bridged Cyclopropane‐Cyclobutanes from 2‐(Difluoromethylene)‐cyclobutyl Sulfonium Salt and Cyclopropenes2Difluorocarbene (: CF 2 ) as a Minimal Perfluorocarbon linker for the Synthesis of gem ‐Difluoromethylenated Compounds ( G 1 ‐ CF 2 ‐ G 2 , G 1 , G 2 ≠ H, F): From 2019 to 20254Photoredox-Catalyzed Radical Cascade Cyclization with Carboxylic Anhydrides to Access CF2H/CF2Cl-Substituted Indolo- and Benzimidazo[2,1- a ]isoquinolin-6(5 H )-Ones0Synthesis of 1,4-Benzoxazepines via [4 + 3] Annulation of ortho -Vinylphenols and Azaoxyallyl Cations0

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  1. Five-membered ring systems: furans and benzofurans

    Progress in heterocyclic chemistry · 2025-01-01

    Halina U. Kwiecień

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  2. Difluorocarbene-Enabled Dehydration of Primary Amides To Access Nitriles

    Organic Letters · 2025-03-17

    Bofan Feng, Huosheng Guo, Xiaosha Wang, Xinyuan Hu, Chengbo Li, Yu C. Guo, Jianke Su, Qingqing Xuan, Qiuling Song

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  3. Synthesis of 2‐Fluoropyrroles via [4 + 1] Cycloaddition of α,β‐Unsaturated Imines with In Situ‐Generated Difluorocarbene

    European Journal of Organic Chemistry · 2025-07-27

    Kohei Fuchibe, Takaya Miura, Junji Ichikawa

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  4. Silver-Catalyzed Difluorocarbene Activation Enables Multicomponent Synthesis of δ,γ-Unsaturated β-Hydroxynitriles

    The Journal of Organic Chemistry · 2025-09-03

    Tong Zhou, Yu Chen, Yuan Xu, Qiaoqiao Wang, Mingquan Yuan, Jia Tian, Yi Jin

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  5. Difluorocarbene-enabled selective Csp 3 –N bond cleavage in aliphatic tertiary amines to access sulfilimines and sulfoximines

    Organic Chemistry Frontiers · 2026-01-01

    Liang Wang Chen, Yong-Liang Pan, Sheng Fang, Huan Yuan, Pengju Feng, Bing Shu

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  6. Diastereoselective Synthesis of Difluoromethylene—Bridged Cyclopropane‐Cyclobutanes from 2‐(Difluoromethylene)‐cyclobutyl Sulfonium Salt and Cyclopropenes

    Chinese Journal of Chemistry · 2026-05-02

    Shi‐Chang Gao, Xiao‐Tian Feng, Hai‐Yang Zhao, Xi Zhang

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  7. Difluorocarbene (: CF 2 ) as a Minimal Perfluorocarbon linker for the Synthesis of gem ‐Difluoromethylenated Compounds ( G 1 ‐ CF 2 ‐ G 2 , G 1 , G 2 ≠ H, F): From 2019 to 2025

    Chinese Journal of Chemistry · 2026-05-21

    Haoyu Yan, Yining Pan, Wei Wu, Shouxiong Chen, Zhiqiang Weng

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  8. Photoredox-Catalyzed Radical Cascade Cyclization with Carboxylic Anhydrides to Access CF2H/CF2Cl-Substituted Indolo- and Benzimidazo[2,1- a ]isoquinolin-6(5 H )-Ones

    The Journal of Organic Chemistry · 2026-08-08

    Pingping Liang, Tianming Liu, Yuxuan Liu, Sirou Jia, Min Zhang, Weiping Su

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  9. Synthesis of 1,4-Benzoxazepines via [4 + 3] Annulation of ortho -Vinylphenols and Azaoxyallyl Cations

    The Journal of Organic Chemistry · 2026-09-21

    Zhan‐Yong Wang, Can Zhang, Xiao-Tian Wang, Xiao-Jin Sun, Yi-Lin Wang, LI Xue-kai, Rong-Hao Zhang, Ran Xia, Hongxin Liu

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