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RESEARCH PAPER · Chemistry of Materials · 2024

Edge-Sharing Tetrahedra Realizing Superior Birefringence and High Deep-Ultraviolet Transmittance in α-Be3(H2O)2(PO4)2 Crystal Synthesized by Mild Chemistry

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Edge-Sharing Tetrahedra Realizing Superior Birefringence and High Deep-Ultraviolet Transmittance in α-Be3(H2O)2(PO4)2 Crystal Synthesized by Mild ChemistryOriginalLarge optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer16Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap2A strongly birefringent sulfate crystal with a wide second-harmonic generation phase-matching range4Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response1Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution21Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution6NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations2Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges6Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Mixed-Connectivity GeS4 Framework for Wavelength-Dependent Linear Dichroism in Layered GeS20

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  1. Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiao Xia, Xingxing Jiang, Qi Lu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Kazuyuki Tatsumi, Chi Zhang

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  2. Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap

    Dalton Transactions · 2024-01-01

    Zhao Wang, Jiazheng Zhou, Linan Wang, Wenqi Jin, Yingying Kong, Yu Chu, Junjie Li

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  3. A strongly birefringent sulfate crystal with a wide second-harmonic generation phase-matching range

    Journal of Materials Chemistry C · 2025-01-01

    Zhiyong Bai, Shanshan Chen, Xu Chen, Yong Wang, Xinwei Zhou, Yipeng Song, Yanqiang Li, Sangen Zhao, Junhua Luo

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  4. Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-01-04

    Meihui Chen, Wei Wei, Jiawei Zhao, Juanjuan Lu, Donghai An, Yanna Chen

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  5. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

    Angewandte Chemie International Edition · 2025-03-17

    Lingli Wu, Chensheng Lin, Haotian Tian, Yan Xin Tao, Bingxuan Li, Huixin Fan, Yujie Fan, Shunda Yang, Min Luo

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  6. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

    Angewandte Chemie · 2025-03-17

    Lingli Wu, Chensheng Lin, Haotian Tian, Tao Yan, Bingxuan Li, Huixin Fan, Yujie Fan, Shunda Yang, Min Luo

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  7. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  8. Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations

    Chemistry of Materials · 2025-10-23

    Luyong Zhang, Zhencheng Wu, Jingdong Yan, Shibin Wang, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  9. Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges

    Chemistry of Materials · 2025-11-17

    Yurui Wang, Xuehua Dong, Wei Zeng, Ling Huang, Zhien Lin, Hongmei Zeng, Guohong Zou

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  10. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  11. Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence

    Journal of the American Chemical Society · 2026-03-26

    Yuexin Zhang, Yipeng Song, Zhiyong Bai, Zhou Yuan, Wei Huang, Ji Qi, Xinwei Zhou, Sangen Zhao, Ling Chen, Kang Min Ok, Junhua Luo

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  12. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie International Edition · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  13. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  14. Mixed-Connectivity GeS4 Framework for Wavelength-Dependent Linear Dichroism in Layered GeS2

    Crystal Growth & Design · 2026-09-08

    Yangsen Hu, 胡全, Yuting Zhang, Wenhao Li, Na Wang, Jian Liu, Qinghua Lv, Huai Yang

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