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RESEARCH PAPER · Inorganic Chemistry · 2024

Structural Phase Transition in 0D (3,5-DMP) 2 Bi 1– x Sb x Cl 5 Metal Halides: Expression of the Lone Pair Effect and Polyhedral Distortion

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Structural Phase Transition in 0D (3,5-DMP) 2 Bi 1– x Sb x Cl 5 Metal Halides: Expression of the Lone Pair Effect and Polyhedral DistortionOriginalPhase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal2Crystal structure and optical properties of a new 0D Sb-based hybrid metal halide: (3,5-DMP)3Sb2Br911Photoluminescent chain-of-dimer anion in a novel hybrid halometallate (C 5 H 14 N 2 ) 3 {Sb 2 Br 9 } 2 : atypical behavior in one-dimensional anionic systems5Large-scale preparation of Sb 3+ -activated hybrid metal halides with efficient tunable emission from visible to near-infrared regions for advanced photonic applications20Understanding the effect of hydrogen bonding on the structural transition and emission properties in zero-dimensional hybrid metal halides: (3,5-DMP)3BiX6 (X = Cl, Br, I)3Synthesis and Luminescence Properties of (TMS) 4 Bi 1– x Sb x Br 7 : A Series of 0D Hybrid Metal Halides Containing S-Based Organic Cations6Understanding the Relation between the Structure and Emission Properties in 0D (2-ABI) 3 Bi 1– x Sb x Cl 6 ·H 2 O: Impact of Structural Distortion and Stereoactivity of ns 2 Lone Pairs8A Halobismuthate Hybrid Characteristic of a T-Shaped Cation: Structure, Band Gap, Photocurrent Response, and Theoretical Study8Multi‐Color Switchable Luminescence in Organic‐Inorganic Metal Halides via Local Polyhedron Regulation Under Light and Temperature Stimuli16Multi‐Color Switchable Luminescence in Organic‐Inorganic Metal Halides via Local Polyhedron Regulation Under Light and Temperature Stimuli1Bright yellow emission from self-trapped exciton in a new antimony chloride-based hybrid material [C8H10N3]2SbCl53Effect of Solvent Coordination on the Structural Transformation and Photoluminescence Properties of Hybrid Metal Halide: (TMS) 2 SbBr 54Iodine incorporated direct band gap materials for enhanced electrochemical hydrogen evolution: role of structural distortion and weak metal halide bonds0Local lattice distortion-driven highly efficient luminescence and thermal quenching resistance in Sb 3+ -doped hybrid indium chlorides1Unravelling thermally induced and Sb 3+ -activated self-trapped exciton emission in 0D Bi-based hybrid halides for reversible luminescence switching and solid-state lighting applications0White-light emitting hybrid Bi 3+ /Sb 3+ bimetallic halides for resin-free LED packaging0Indium-to-Tin Metal Modulation as a Strategy for Tuning Emission from Yellow to Orange in Zero-Dimensional Metal Halides0Mn2 +-activated red luminescence in zero-dimensional hybrid zinc halides with enhanced photoluminescence for solid-state lighting0

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  1. Phase Transition of a Chiral Lead‐Free Hybrid Antimony(III) Halide Crystal

    European Journal of Inorganic Chemistry · 2024-07-26

    Jun‐Chao Qi, Zhang‐Tian Xia, Xin Shen, Hang Peng, Huiping Chen, Yong‐Ju Bai, Wei‐Qiang Liao

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  2. Crystal structure and optical properties of a new 0D Sb-based hybrid metal halide: (3,5-DMP)3Sb2Br9

    Journal of Solid State Chemistry · 2024-10-01

    Subhasish Sahoo, Rajanikanta Rana, Saroj L. Samal

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  3. Photoluminescent chain-of-dimer anion in a novel hybrid halometallate (C 5 H 14 N 2 ) 3 {Sb 2 Br 9 } 2 : atypical behavior in one-dimensional anionic systems

    Dalton Transactions · 2024-11-27

    Andrey V. Bykov, Tatiana A. Shestimerova, M. A. Bykov, Victoria E. Gontcharenko, Konstantin Alexandrovich Lyssenko, Mikhail T. Metlin, Il'ya Viktorovich Taydakov, Anastasia V. Grigorieva, Аndrei V. Shevelkov

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  4. Large-scale preparation of Sb 3+ -activated hybrid metal halides with efficient tunable emission from visible to near-infrared regions for advanced photonic applications

    Materials Horizons · 2024-12-02

    Ou Xu, Hui Hua Peng, Qilin Wei, Linghang Kong, Xiao Wang, Heng Zhang, Jialong Zhao, Bingsuo Zou

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  5. Understanding the effect of hydrogen bonding on the structural transition and emission properties in zero-dimensional hybrid metal halides: (3,5-DMP)3BiX6 (X = Cl, Br, I)

    Dalton Transactions · 2025-01-01

    Subhasish Sahoo, Rajanikanta Rana, Chakali Srinivas, Parameswar Krishnan Iyer, Laxmipriya Dash, Himansu S. Biswal, Saroj L. Samal

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  6. Synthesis and Luminescence Properties of (TMS) 4 Bi 1– x Sb x Br 7 : A Series of 0D Hybrid Metal Halides Containing S-Based Organic Cations

    Crystal Growth & Design · 2025-02-06

    Suman S. Das, Rajanikanta Rana, Chakali Srinivas, Aman Mishra, Parameswar Krishnan Iyer, Saroj L. Samal

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  7. Understanding the Relation between the Structure and Emission Properties in 0D (2-ABI) 3 Bi 1– x Sb x Cl 6 ·H 2 O: Impact of Structural Distortion and Stereoactivity of ns 2 Lone Pairs

    Inorganic Chemistry · 2025-03-10

    Subhasish Sahoo, Rajanikanta Rana, Chakali Srinivas, Parameswar Krishnan Iyer, Laxmipriya Dash, Himansu S. Biswal, Saroj L. Samal

    Read original paper ↗ ·
  8. A Halobismuthate Hybrid Characteristic of a T-Shaped Cation: Structure, Band Gap, Photocurrent Response, and Theoretical Study

    Inorganic Chemistry · 2025-05-05

    Jun Li, Shuyue Xie, Jiu-Jiang Dong, Hanhua Zhao, Yan Yang, Yue Wu, Bo Zhang

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  9. Multi‐Color Switchable Luminescence in Organic‐Inorganic Metal Halides via Local Polyhedron Regulation Under Light and Temperature Stimuli

    Angewandte Chemie International Edition · 2025-08-04

    Wei Yang, Peipei Dang, Dongjie Liu, Yingsheng Wang, Long Tian, Yi Min Wei, Hongzhou Lian, Guogang Li, Jun Lin

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  10. Multi‐Color Switchable Luminescence in Organic‐Inorganic Metal Halides via Local Polyhedron Regulation Under Light and Temperature Stimuli

    Angewandte Chemie · 2025-08-04

    Wei Yang, Peipei Dang, Dongjie Liu, Yingsheng Wang, Long Tian, Yi Min Wei, Hongzhou Lian, Guogang Li, Jun Lin

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  11. Bright yellow emission from self-trapped exciton in a new antimony chloride-based hybrid material [C8H10N3]2SbCl5

    Journal of Luminescence · 2025-09-25

    A. Kessentini, T. Dammak, Kawthar Abid

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  12. Effect of Solvent Coordination on the Structural Transformation and Photoluminescence Properties of Hybrid Metal Halide: (TMS) 2 SbBr 5

    Inorganic Chemistry · 2025-10-29

    Suman S. Das, Rajanikanta Rana, Chakali Srinivas, Parameswar Krishnan Iyer, Saroj L. Samal

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  13. Iodine incorporated direct band gap materials for enhanced electrochemical hydrogen evolution: role of structural distortion and weak metal halide bonds

    Dalton Transactions · 2026-01-01

    Abinash Pradhan, Thillai Natarajan M, Rajanikanta Rana, Tanmay K. Pradhan, Sumanta Kumar Padhi, Saroj L. Samal

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  14. Local lattice distortion-driven highly efficient luminescence and thermal quenching resistance in Sb 3+ -doped hybrid indium chlorides

    Journal of Materials Chemistry C · 2026-01-01

    Qingyi Liu, Jie Li, Qi Zhang, Dongfeng Xue, Lizhen Zhang, Yan Yu, Lingyun Li

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  15. Unravelling thermally induced and Sb 3+ -activated self-trapped exciton emission in 0D Bi-based hybrid halides for reversible luminescence switching and solid-state lighting applications

    Journal of Materials Chemistry C · 2026-01-01

    Subhasish Sahoo, Chakali Srinivas, Rajanikanta Rana, Laxmipriya Dash, Parameswar Krishnan Iyer, Himansu S. Biswal, Saroj L. Samal

    Read original paper ↗ ·
  16. White-light emitting hybrid Bi 3+ /Sb 3+ bimetallic halides for resin-free LED packaging

    Journal of Materials Chemistry C · 2026-01-01

    Xiao Lin, Lihan Chen, Maxim S. Molokeev, Kai Han, Zhiguo Xia

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  17. Indium-to-Tin Metal Modulation as a Strategy for Tuning Emission from Yellow to Orange in Zero-Dimensional Metal Halides

    ACS Applied Optical Materials · 2026-08-06

    Suman S. Das, Chakali Srinivas, Rajanikanta Rana, Parameswar Krishnan Iyer, Saroj L. Samal

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  18. Mn2 +-activated red luminescence in zero-dimensional hybrid zinc halides with enhanced photoluminescence for solid-state lighting

    Journal of Alloys and Compounds Communications · 2026-10-09

    Subhasish Sahoo, Suman S. Das, Biswajit Mohapatra, Rajanikanta Rana, Chakali Srinivas, Laxmipriya Dash, Parameswar Krishnan Iyer, Himansu S. Biswal, Saroj L. Samal

    Read original paper ↗ ·