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RESEARCH PAPER · Green Chemistry · 2024

Characterization of polymer properties and identification of additives in commercially available research plastics

Amy A. Cuthbertson, Clarissa L. Lincoln, Joel Miscall, Lisa M. Stanley, Anjani K. Maurya, Arun S. Asundi, Christopher J. Tassone, Nicholas A. Rorrer, Gregg T. Beckham

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Characterization of polymer properties and identification of additives in commercially available research plasticsOriginalAtomic spectrometry update: review of advances in the analysis of metals, chemicals and materials22Liquid-assisted grinding enables a direct mechanochemical functionalization of polystyrene waste27Structural Elucidation of a Metagenomic Urethanase and Its Engineering Towards Enhanced Hydrolysis Profiles61Thermal degradation of nanoporous Si-containing hybrid terpolymer3Characteristics of organic matter driven by Eichhornia crassipes during co-contamination with per(poly)fluoroalkyl substances (PFASs) and microplastics (MPs)13A High-Throughput Screening Platform for Engineering Poly(ethylene Terephthalate) Hydrolases29Revisiting the activity of two poly(vinyl chloride)- and polyethylene-degrading enzymes68Assessment of Different Application Grades of Post-Consumer Recycled (PCR) Polyolefins from Material Recovery Facilities (MRFs) in the United States13A comparative biomonitoring study of trace metals and organic compounds bioaccumulation in marine biofilms and caged mussels along the French Mediterranean coast4Additives in bioplastics: Chemical characterization, migration in water and effects on photosynthetic organisms16Mechanism of Quiescent Nanoplastic Formation from Semicrystalline Polymers0Disentangling mechanisms by which microplastic films affect plant-soil systems: physical effects of particles can override toxic effects of additives16Direct Additive Detection in Polymer Films via Platinum-Assisted SALDI Mass Spectrometry Imaging1Wavelength Sensitive Plastic Photodissolution: Elucidating Quantum Yield Trends for Solar Activation Spectra11Influence of ball milling parameters on the mechano-chemical conversion of polyolefins35Applying the principles of green chemistry to achieve a more sustainable polymer life cycle15An Exhaustive Characterization of Polyvinyl Chloride to Support Recycling Processes by Two-Dimensional Sec-Rplc-Esi-Hrms/Ms0Beyond size and shape: physicochemical properties of microplastic test materials generated by cryomilling0Biocatalytic recycling of plastics: facts and fiction25Homolytic fracture of inorganic crystalline materials enhances the mechano-chemical degradation of polypropylene7Influence of functional additives, fillers, and pigments on thermal and catalytic pyrolysis of polyethylene for waste plastic upcycling61Microbial degradation of a widely used model polyethylene is restricted to medium- and long-chain alkanes and their oxidized derivatives9Microplastics Quantification in Organic-Rich Samples: The Relevance of Testing Substrate-Specific Calibration Curves0Multiscale characterization of commercial and landfill-recovered plastics in Songkhla province, Thailand2Plastic-derived carbons for high-performance battery electrodes: upcycling, design strategies, and perspectives9Production, labeling, and applications of micro- and nanoplastic reference and test materials31A screening method for polyester films-degrading microorganisms and enzymes11Asphaltene-Recycled Polyethylene Terephthalate (rPET) Blends as Sustainable Carbonaceous Fiber Precursors3Plastic Waste to Carbon Adsorbent: Activation with Sodium Carbonate and Functionalization with Citric Acid13Characterization of Inorganic Additives in and Photochemically Liberated from Consumer Plastics: Implications for Global and Local Biogeochemical Cycles12Processing behavior evolution of recycled polypropylene: An integrated experimental and Computer-Aided engineering simulation study6Mechanism of quiescent nanoplastic formation from semicrystalline polymers34Development of moisture-adsorbent cellulose aerogels with application in the packaging and preservation of fresh products16A screening of metal(loid) content in conventional and compostable plastic polymers: understanding the sources and the connected environmental implications14Single-Fiber Visualization of Poly(ethylene terephthalate) during Alkaline Hydrolysis: Testing of Surface Reaction Model and Mechanism3An efficient and precise (micro)plastic identification method: feature infrared spectra extraction based on EIS-VIP-CARS and ANN modeling1Standardization guidelines and future trends for PET hydrolase research70Engineering PHL7 for improved poly(ethylene terephthalate) depolymerization via rational design and directed evolution9Exhaustive characterization of polyvinyl chloride to support recycling processes by off-line two-dimensional size-exclusion chromatography coupled with reversed-phase liquid chromatography-high-resolution tandem mass spectrometry1Protocol for engineering poly(ethylene terephthalate) hydrolases via directed evolution using a high-throughput screening assay1Catalytic pyrolysis of refuse-derived fuel (RDF) to aromatic-rich oils: Insights into Fe-modified zeolites regeneration characteristics and iron species evolution1Effect of mechanical recycling and virgin PBR addition on the properties of ABS recovered from WEEE: A multi-technique characterization3Recent advances in enzyme engineering for improved deconstruction of poly(ethylene terephthalate) (PET) plastics42Machine Learning-Guided Identification of PET Hydrolases from Natural Diversity27Closed-loop recycling of mixed polyesters via catalytic methanolysis and monomer separations22Challenges of polyethylene (PE) biodegradation – A perspective17Mixed polyamide and polyester upcycling via chemical autoxidation and engineered Pseudomonas putida4Recycling of Single-Use Multilayer Plastics for Biomanufacturing with Solvent-Targeted Recovery and Precipitation10Management of bioplastic waste: a critical analysis of biodegradation and recycling approaches4Materials in Water Supply Systems: Migration of Organic Compounds from Rubber Materials1Advancing chemical recycling for waste plastic conversion1Upcycling waste polystyrene to adipic acid through a hybrid chemical and biological process16Biorecycling of polyethylene (PE): an integrated effort in pretreatment, degradation, and upcycling8Assessing the anaerobic biodegradability of PHB filament and its 3D printed sheets through biochemical methane potential (BMP) test3Comment on “Expanded polystyrene is not chemically degraded by mealworms” by Z. M. Tahroudi, G. Flematti, J. Joshi, G. Fritz and R. Atkin, RSC Sustainability , 2025, 3 , 3834Process optimization for enhanced enzymatic nylon deconstruction2Impact and Interaction of Additives on the Formation of Nonintentionally Added Substances and Polystyrene Rheology0From additive analysis to process monitoring: characterization of polypropylene solvent-based recycling from plastic feedstocks representative of sorting centres2Intrinsically Bifunctional and Tunable Tungsten Carbide Catalysts Enable Efficient PVC-Compatible Polyolefin Hydrocracking8Advances in polyethylene biodegradation and bioconversion: Microbial, enzymatic, and biotechnological insights2Investigation of zinc borate-reinforced epoxy composites produced via additive manufacturing: thermal and mechanical analysis0Microbial production of polyhydroxyalkanoates and lactate-based biopolymers from C1 resources: current advances and trends1A Brief Overview of Microplastics and Nanoplastics0Carbon–carbon bond cleavage for lignin and plastics deconstruction0Chromatographic Techniques for Polymer Analysis0Detection, identification, and quantification of polymer additives: a review of techniques, approaches, challenges, and a possible roadmap in analysis15Introduction to Conducting Polymers0Marine Microplastic Enters Food Chains and Challenges Human Nutritional Security0Polymer backbone modification to introduce degradability0Pre-Ignition Source Localization using a 3D Network of Semiconducting Metal Oxide Gas Sensors0Solvent-mediated contaminant removal from plastic waste using thermodynamic modeling4The migration of non-toxic plasticisers from melt-processed PHBV blends in water0Advancement in Analytical Characterization of NBR: Py-GC-MS as an Alternative to NMR for Acrylonitrile Quantification0Microplastics quantification in organic-rich samples: The relevance of testing substrate-specific calibration curves2Pyrolysis of Cellulose with Gallium/HZSM-5 Catalysts via Py/GC-MS1Beyond size and shape: Physicochemical properties of microplastic test materials generated by cryomilling0Rapid and Efficient GC-MS Method for the Multiresidue Analysis of Contaminants from Recycled Polyethylene and Polypropylene0High-performance functionalized waterborne polyurethane coatings9Energy-Efficient Upcycling of Waste Poly(ethylene terephthalate) via Pre-Annealing-Induced Formation of Reactive Telechelic Oligomers4Construction of inorganic confining structures in layered double hydroxide interlayers for enhancing anti-migration performance0Polymer Deconstruction and Redesign Strategies for Plastics Recycling0Alcoholysis of nylon 6 waste to ε-caprolactam promoted by phosphoric acid4Release of volatile organic compounds from raw and torrefied polymer components of the refuse-derived fuel: Characterization and implications0Masterbatch Systems Based on Thermomechanical Pulp Fibers and Clay Fillers for Applications in Virgin and Recycled Polyolefins0Catalytic Autoxidation for Depolymerization of Multilayer Plastic Films0Effects of Polymer Morphology on Solvent and Catalyst Accessibility during Polyethylene and Polystyrene Autoxidation0Hidden hazards of eco-friendly plastics: Thermally induced release of micro/nanoplastics and dissolved organic matter from polylactic acid0The presence of additives dominates the metal adsorption process on plastic over polymer type and UV aging0Vat Photopolymerization-Fabricated Theranostic Hydrogels for Smart Wound Management0Alkylidene functionalization produces highly recyclable and scalable polyhydroxyalkanoates3From Renewable Aromatic Compounds to High-Performance Thermosets: Synthesis, Performance, and Toxicity Screening of Novel Biobased Diamines for Epoxy Curing2A Tiered Multi-Technique Decision-Support Framework for Contaminant Screening and Recycling-Route Assignment of Mixed Plastic Waste4Challenges and opportunities in the enzymatic recycling of nylons1Tailoring polyhydroxybutyrate by molecular weight regulation: Green synthesis, food-grade performance and innovative ketogenic applications0From dust to durability: Upcycling waste marble into resilient PLA composites0Exploring pre-ignition source localization using a 3D network of semiconducting metal oxide gas sensors1Reaction Optimization for Enzymatic Deconstruction of Industrially Relevant Nylon Composites0Upcycling of low-density polyethylene and multilayer plastic waste into sand-plastic paving blocks: Material characterization and mechanical properties1Schizophrenic polymer: Synthetic strategy, nanostructural inversion and versatile applications0Assessment of Mechanical Recycling Potential of Plastic Waste from End-of-Life LFP Battery Cases0Explainable Deep Learning and Targeted Spectral Augmentation for Mid-Infrared Classification of Additive-Containing Polymers0Rapid identification of ABS copolymers and SAN copolymers based on proton nuclear magnetic resonance spectroscopy0Closed-loop recycling of post-consumer PET oligomers via solid-state repolymerization0Elemental Blend Solver: An open-source browser tool for polymer blend identification by non-negative least squares0Strategies for Recycled Plastics Content Verification0Upcycling post-consumer household textiles into a biodegradable thermoplastic0Assessing biological degradation of non-hydrolysable synthetic polymers1Profiling autofluorescence signatures of microplastics from commercial plastic products by flow cytometry and multivariate analysis0Prior-Attention-Mechanism-Based Spectral Identifier for Revealing Hazardous Chemical Additives in Commercial PVC0Upcycling of polymer waste into high value energy products0Challenges in polyolefin re/upcycling catalysis specific to polymer feedstock0Recent Advances in Plastic Waste Biodegradation: Microorganisms, Enzymes, Invertebrates, and Evidence Standards0

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