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RESEARCH PAPER · Nature Communications · 2024

Quantifying the interfacial triboelectricity in inorganic-organic composite mechanoluminescent materials

Xin Pan, Yixi Zhuang, Wei He, Cunjian Lin, Lefu Mei, Changjian Chen, Hao Xue, Zhigang Sun, Chunfeng Wang, Dengfeng Peng, Yanqing Zheng, Caofeng Pan, Lixin Wang, Rong‐Jun Xie

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Quantifying the interfacial triboelectricity in inorganic-organic composite mechanoluminescent materialsOriginalSmart films based on semiconductor heterojunctions of mechanoluminescent sulfide and sulfur oxide for stress sensing and anti-counterfeiting applications31Enabling Multimodal Luminescence in a Single Nanoparticle for X-ray Imaging Encryption and Anticounterfeiting49Achieving Tunable Mechanoluminescence in CaZnOS:Tb3+, Sm3+ for Multicolor Stress Sensing10Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Trap‐Controlled, Recoverable, and Persistent Mechanoluminescence for Collision Early‐Warning and Mechanics Displaying Applications7A perspective on mechanoluminescence and multipiezo in ferroelectric materials21High‐Brightness and High‐Resolution Triboelectrification‐Induced Electroluminescence Skin for Photonic Imaging and Information Interaction4Simultaneous Triboelectric and Mechanoluminescence Sensing Toward Self‐Powered Applications14Synergistic Mechanoluminescence and Mechanochromism Via Triboelectrification‐Induced Eu3+/Eu2+ Redox Shuttle23Triboelectrification-induced mechanoluminescence of isomorphic Sr3MO4F:Ln (M = Al, Ga): Performance and difference15Exploring Mechanoluminescence of Zinc Alkaline Earth Metal Oxysulfides from Fundamentals to Advanced Applications26Designing High‐Sensitivity Mechanochromic Luminescent Materials Through Friction‐Induced Crystallization Strategy10Force‐Induced Ultraviolet C Luminescence of Pr 3+ ‐Doped Sr 2 P 2 O 7 for X‐Ray Dosimetry54Interfacial dipole moment engineering in self-recoverable mechanoluminescent platform15Self-powered visualized tactile-acoustic sensor for accurate artificial perception with high brightness and record-low detection limit61Self‐Recoverable and NIR‐I to NIR‐II Tunable Broadband Mechanoluminescence of Cr 3+ ‐Doped Antimonate Double Perovskites52An Artificial Intelligence-Assisted Flexible and Wearable Mechanoluminescent Strain Sensor System64Trap Assisted Dynamic Mechanoluminescence Toward Self‐Referencing and Visualized Strain Sensing48Triboelectric nanogenerator based on changing the nanomorphology of polyoxometalates for gait monitoring of teenagers4The self-activated LiGa 5 O 8 storage phosphor: insights into its photo/thermo/mechano-stimulated NIR luminescence16Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal82Flexible mechano-optical sensors from mechanoluminescence to mechanoplasmonics: designs, applications, and prospects15High-Performance Self-Powered Visualized Acoustic Sensor with Multifunctional Nanocellulose-Based Composite and Spiral Electrodes for Sound Recognition and Interaction0Organic mechanoluminescent nanoparticles for biomedical applications7Self-Recoverable Broadband Near-Infrared Mechanoluminescence in Cr3+-Doped Scbo3 Endowing Biological Application1Innovations in phosphate phosphors: Bridging structure-property gaps for enhanced luminescence27Consistency of simulated stress distribution with experimental mechanoluminescent intensity distribution facilitating stress visualization device design4Advances in Triboelectric Energy Harvesting at Liquid–Liquid Interfaces15Flexible triboelectric nanogenerators fabricated by PAN-supported self-aggregation crosslinked PVA composite films for kinetic energy harvesting and pervaporization applications9β-SiAlON phosphor-in-glass mechanoluminescent materials for high-frequency mechanical sensing4Thermal‐Adaptive Photonic MOFs for High‐Performance X‐ray Scintillator35Mechanoluminescence ZnS/CaZnOS:Mn2+/PVC composite film-based triboelectric nanogenerator for energy harvesting and intelligent sensing19Wearable Mechanoluminescent Triboelectric Sensors for Real-Time Monitoring of Nighttime Sports Activities18Trap‐Assisted Mechanoluminescence in Mn 2+ ‐Doped Transparent Amorphous Glass for Potential Stress Sensing3Non-destructive charged mechanoluminescence in transparent glass-ceramics5Self‐Recovering Multicolor Calcium Phosphate Mechanoluminescent Materials for Wearable Skin and Biomedical Applications12Defects in Inorganic Mechanoluminescent Phosphors: Insights and Impacts30Design, classification, and applications of organic, luminescent lanthanide-based photoresponsive materials: A review59Enhanced-response, stretchable, and self-powered strain sensor with exteroception-visualizing capability for physical signal monitoring0Downconversion mechanoluminescence from lanthanide codoped heterojunctions5Size and Structural Control of Mechanoluminescent ZnS:Mn2+ Nanocrystals for Optogenetic Neuromodulation25Self-Powered Mechanoluminescence-Based Mechanical Sensing Glove for Human-Machine Interaction33D Printing of Auxetic Self‐powered Mechanoluminescent Photonic Skins for Underwater Communication and Safety Monitoring11Photonic Film Based on Triboelectrificationinduced Electroluminescence for Self-Powered Visualization and Handwriting Recognition0High-Efficiency Organic Mechanophosphorescence from A Phenoselenazine Phosphor for Multiple Applications21Mechano‐Chemiluminescent Hydrogel for Sustained Stress Visualization Under Mechanical Equilibrium9Highly Repeatable and Cyclically Stable Mechanoluminescence of the Flexible Composite Elastomer38Advanced mechanoluminescence sensing of arm force using Pr3 + -doped Y3GaO6 for marathon performance monitoring research3Highly bright and ultra-stable cyan-emitting perovskite quantum dots encapsulated in zeolitic imidazolate framework-11 for advanced optoelectronic applications9Multifunctional mechanoluminescent material with enhanced interfacial synergistic effects: 2SrZn2S2O/ZnS heterojunction2Self-reduction-induced Mn heterovalent coexistence for Vis–NIR dual-emission16Discovery of Mechanoluminescence in an Antimony‐Based Organic–Inorganic Hybrid Metal Halide14Fully self-powered pipeline leakage detection and localization enabled by triboelectric nanogenerator9Visible droplet luminescence in daylight1Multi-stimulated far-UVC luminescence for solar-blind imaging29A Robust Core–Shell Structured Fabric with Integrated Personal Protection and Visualized Monitoring for Smart Protective Textiles9Sound, Force and Light Induced Emissions from Er3+‐Mn2+ Doped ZnS/CaZnOS Heterostructure for Remote Temperature Monitoring via Photo‐ and Mechanoluminescence51Force-light-heat stimulation-induced multicolor chromism and multifunctional applications of europium tungstate phosphor21Dual‐Mode Mechanoluminescence Induced by Triboelectricity and Frictional Heat in Transparent Fluoride Glass Ceramic3Creating mechanoluminescent materials with high repeatability and cyclic stability5Ultrasensitive Mechanoluminescence of Pr 3+ ‐Doped Perovskite Oxide for 3D Strain Sensing and Visualization15Interfacial Interaction Modulated Radiation Defects for Self‐Charging Persistent Mechanoluminescence10Self‐Powered Optical Communication: Opportunities, Challenges and Future Prospects7Breaking the Cross‐Sensitivity Limit: Simultaneous Stress and Temperature Dual‐Mode Sensing Via Colorimetric Mechanoluminescence in SrF 2 :Eu 2+ ,Sm 3+7Mechanoluminescence: Mechanisms, emerging applications, and future prospects26Self‐Charging Near‐Infrared Mechano‐Afterglow in Cr 3+ Activated Composites5Mechanoluminescent Aluminum Nitride Crystal for Super‐Sensitive Optical Manometry, Thermometry and Force Sensing10Enhancing Mn‐Activated Mechanoluminescence via Pressure‐Regulated Local Structure in Centrosymmetric BaZnOS for Dynamic Response Applications3Boosting Mechanoluminescence Performance in Doped CaZnOS by the Facile Self‐Reduction Approach11Spiral Electrodes‐Enhanced Triboelectrification‐Induced Electroluminescence in Nanocellulose Composites for Self‐Powered Visualized Acoustic Sensing0Multimodal luminescence of CaZnGe2O6:Mn2+,Yb3+ phosphors for anti-counterfeiting: dynamic photoluminescence, afterglow, photostimulated luminescence, thermostimulated luminescence and mechanoluminescence29Er 3+ Mediated Multicolor Tuning of Luminescence in Piezoelectric Ca 3 Ga 4 O 9 :Eu 3+ System: Non‐Pre‐Irradiated Mechanoluminescence and Multiplexed Photoluminescence5Controllable Synthesis of Gradient α/β-ZnS:Cu for Revealing the Mechanoluminescent Mechanisms6Visually encoded mechanoluminescence through hierarchical structuring with microscale patterns and nanoscale features7A Self‐Powered Tactile Sensor Resistant to Environmental Interference21Mechanoluminescence in borate transparent glass-ceramics: Crystallization of SrAl2B2O7 and rare-earth energy transfer in Eu3+/Tb3+ co-doped systems3Mechano-electro-optical conversion dynamics in mechanoluminescence and its application in remote human–robot interaction8Green‐Orange Bi‐Color Switchable Mechanoluminescent Fiber of Okra‐Like Structure for Visual Signaling2Photoluminescence properties and crystal field analysis of a deep-red-emitting K2SrGe8O18:Mn4+ phosphor for temperature sensing and plant cultivation applications1Stretchable Optical–Electrical Dual‐Responsive Photonic Skin and Its Intelligent Sensing Applications1Regulation of high pressure on mechanoluminescence: Summary and Prospects0Yolk‐Shell Nanoparticles with Shear Stress‐Triggered Triboluminescence for Dynamic Thrombus Imaging and Tribocatalytic‐Photodynamic Thrombolysis0Chromium-activated phosphors: from theory to applications23Circularly Polarized Mechanoluminescence for Force‐Insensitive Optical Information Decryption8A self-healing e-skin for quadruple-modal sensing3Accelerating the charge carrier release in mechanoluminescent material SrAl 2 O 4 :Eu 2+ ,Dy 3+ by local structural distortion0Mechanoluminescent materials: toward advanced optoelectronic sensing and biomedical applications0Self-powered mechanoluminescent elastomer for solar-blind ultraviolet emission4Multi-physics field coupled elastomers for enhanced mechanoluminescence and magneto-optical response0Inorganic–Organic Interfacial Engineering of Earth-Abundant Phytoliths for Multifunctional Hemostat0Self-recoverable broadband near-infrared mechanoluminescence in Cr3+-doped scandium borate endowing biological application4Breaking Spin-Forbidden Transition by an Antisite Defect Strategy for Enhancing Far-Red Emission of Cr 3+ -Activated Phosphors2Design of multimodal stimuli-distinct responsive dynamic luminescence for visualized mechanical sensing3Interfacial Fusion Engineering Enables Scalable Single-Step Continuous Fabrication of Durable and Highly Sensitive Mechanoluminescent Fiber1Thermally Activated Mechanoluminescence for Dynamic Multimodal Encryption and Intelligent Handwritten Digit Recognition0Cation-π interaction and π-delocalization coupled ionogel electrodes for triboelectric and bioelectronic interfaces2Superior mechanoluminescence of ZnS:Mn/ZnO heterostructure array chip boosted by type II electron transition0Na+-driven charge compensation and defect regulation in orange-red-emitting Sr2GaNbO6:Sm3+ phosphors2Synergistic co-doping strategy in KZn(PO3)3 for multimodal anti-counterfeiting, stress visualization, and self-powered lighting2Mechanoluminescence-Enhanced Ammonia Synthesis via Mechanochemical Nitrate Reduction1X‐Ray and Mechano‐Induced Valence Transition and Luminescence of Ln 3+ /Ln 2+ in CsCaCl 31X‐Ray and Mechano‐Induced Valence Transition and Luminescence of Ln 3+ /Ln 2+ in CsCaCl 31Continuously fabricable core-shell triboelectric fibers with silk fibroin shell and hydrogel core via interfacial engineering for self-powered physiological monitoring1Defect-engineered Sr3Sn2O7:Sm3+ for dual-channel visible and NIR luminescence in stress sensing applications0Dopant-localized mechanoluminescence in simple oxides1Turning sound and force into light with AlN:Mn 2+ mechanoluminescence4Stress and Temperature Dual-Mode Sensing Based on Sb3 + -Doped Cs2ZrCl60Self-recoverable multicolor mechanoluminescence in LaBO3-based composites toward self-powered optical platforms and multimode anticounterfeiting0Waterborne Polyurethane/Cellulose‐Reinforced Silica‐Based Aerogels for Efficient Thermal Insulation and Piezoresistive Sensing1Biomimetic Gradient Microstructures Enable Stable, High‐Sensitivity Pressure Sensing From Pa to MPa0Flexible light-emitting elastomeric sensors: Mechanisms, materials, device integration, and wearable applications0Quantifying contact electrification capability of phosphors to develop self-recoverable mechanoluminescence composites0Synergizing interfacial electronic structure and topological optimization for enhanced tribological performance0Multimodal modified VIS-NIR emission in Lu2CaAl4SiO12 with single activator Mn2+ for anti-counterfeiting application0

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  49. Highly bright and ultra-stable cyan-emitting perovskite quantum dots encapsulated in zeolitic imidazolate framework-11 for advanced optoelectronic applications

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  50. Multifunctional mechanoluminescent material with enhanced interfacial synergistic effects: 2SrZn2S2O/ZnS heterojunction

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