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RESEARCH PAPER · Journal of the American Chemical Society · 2024

A Robust Anti-Thermal-Quenching Phosphor Based on Zero-Dimensional Metal Halide Rb3InCl6:xSb3+

Baowei Zhang, Yi Ru, Jiaqian Zhou, Jing-Tao Jia, Haoqiang Song, Zhongyi Liu, Linlin Zhang, Xuying Liu, Guiming Zhong, Xue Yong, Iyyappa Rajan Panneerselvam, Liberato Manna, Siyu Lu

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A Robust Anti-Thermal-Quenching Phosphor Based on Zero-Dimensional Metal Halide Rb3InCl6:xSb3+OriginalHigh-efficiency tunable self-trapped exciton emission in one-dimensional β-Cs 3 Cu 2 Br 5 via Ag alloying for optoelectronic applications2Understanding charge transport and dielectric relaxation properties in lead-free Cs 2 ZrCl 6 nanoparticles33Thermally Enhanced Self‐Trapped Exciton Emission Based on Thermochromic Ag + doping 0D Zinc‐Based Halides24Multimode Luminescence Tailoring in PMA 4 Na(In,Sb)Cl 8 Organic–inorganic Hybrid Metal Halide via Rigid Benzene Ring Induced Local Lattice Distortion58Multimode Luminescence Tailoring in PMA4Na(In,Sb)Cl8 Organic–inorganic Hybrid Metal Halide via Rigid Benzene Ring Induced Local Lattice Distortion2Efficient blue light emission induced by the Cu-doping in Cs2ZnI4 for white light-emitting diodes3Antithermal-Quenching All-Inorganic Perovskite Crystals with Green Ultralong Persistent Luminescence for Advanced Anticounterfeiting Applications14High‐Efficiency Luminescence and Robust Thermal Quenching Resistance in Organic–Inorganic Hybrid Indium‐Based Metal Halides26Gradient Luminescence Enhancement in Organic Metal Halide Perovskites via the Suppression of [SbCln]3–n Unit Distortion5Cr 3+ –Cr 3+ pairing and multi-site engineering in Sr 2 ZnAl 22 O 36 phosphors for broadband near-infrared emissions14Crystal Structure and Photoluminescence Properties of Ca3(PO4)2:Eu3+ Phosphors With High Emission Efficiency2Magnesium halides as a lead-free family with unique optoelectronic properties2Structural transformation in isomeric 0D copper( i ) iodide hybrids and their utilization as water-stable luminophores for furaltadone detection6Pb2+ and Mn2+ Codoped Cs2CdCl4 Nanocrystals with Tunable Emission8Component/Stimulus‐Dependent Multi‐Exciton Emission in Zr(IV)‐Based Organic Metal Halides Triggered by Supramolecular Assembly and Antimony Doping22Embedding Te(IV) into a Robust Sn(IV)-Based Metal Halide for Deep-Red Emission7Efficient UV Emission with Anti‐Thermal Quenching from Ce 3+ ‐Activated 0D All‐Inorganic Zinc Halides19Stimuli-responsive luminescence in doped inorganic crystals5Sb3+ doped Cs3YCl6 metal halides with highly efficient broad-band green emission for light-emitting diode and X-ray imaging6Multiphoton-Excited Upconversion Luminescence and Amplified Spontaneous Emission from Te 4+ -Doped Cs 2 SnCl 6 Nanocrystals12Phase Engineering for Achieving Full‐Color Tunable Emission from Blue to Red and Multi‐Level Information Security in Isomeric Hybrid Copper Halides6Phase Engineering for Achieving Full‐Color Tunable Emission from Blue to Red and Multi‐Level Information Security in Isomeric Hybrid Copper Halides46Ultrabroadband (Vis‐NIR) Emission in Single‐Component Perovskite LEDs via Tailored Multi‐Exciton Energy Transfer Pathways26Mechanism of dual-band emission in Sb-doped rare-earth phosphates1A narrow-band Bi³ ⁺-activated blue phosphor with high thermal stability for multiple applications1Reversible Phase Transformation of Thermal Quenching and Anti‐Thermal Quenching in Cu(I) Halides for Anti‐Counterfeiting15Intense upconverted ultraviolet emission of Er3+ through confined energy transfer in Yb3+/Er3+ co-doped Rb3InCl630Stepwise Unlock Full‐Spectrum Emission with Abnormal Anti‐Thermal Quenching in Indium‐Based Metal Halides by Tailoring Their Crystal Structure Engineering10Multi‐Color Switchable Luminescence in Organic‐Inorganic Metal Halides via Local Polyhedron Regulation Under Light and Temperature Stimuli16Multi‐Color Switchable Luminescence in Organic‐Inorganic Metal Halides via Local Polyhedron Regulation Under Light and Temperature Stimuli1Customizable Superior Performance via Managing Defect and Self‐Trapped Exciton Interactions in Zinc‐Based Metal Halides for Multifunctional Applications7Near-Unity PLQY in Lead-Free Halide Perovskites and Perovskite-Inspired Halides for Light-Emitting Diode Applications18Gadolinium and Europium Doped Chiral Perovskite Films with Magnetic Circular Dichroism and Circularly Polarized Luminescence for Information Encryption Applications5Gadolinium and Europium Doped Chiral Perovskite Films with Magnetic Circular Dichroism and Circularly Polarized Luminescence for Information Encryption Applications30Recent advances of theoretical investigation on lead-free metal halide perovskites4A Multiple-fold interpenetrating 3D hydrogen-bonded organic framework (TCBPE-DPNDI): Enhanced stability and luminescent properties for LED application1Compositional Design of Mn 2+ ‐Activated Phosphors: Toward Narrow‐Band Green Emission for Wide Color Gamut Displays11Enhancing Abnormal Thermal Quenching Characteristics of Y 1– x La x NbO 4 :Pr 3+ Phosphors through Energy Transfer Enhancement and Intervalence Charge Transfer Modulation Synergistic Strategy0Thermal‐Robust and Glass‐Compatible K 1.3 Al 9 Ga 2 O 17.15 :Eu for Laser‐Driven Lighting and Underwater Optical Communication3Sb 3+ ‐Activated 0D Cs 3 LuCl 6 : A Cyan–Green Phosphor with Near‐Unity Quantum Yield for Ultrahigh‐CRI Full‐Spectrum White LEDs8Leveraging structural rigidity for thermal robust scintillation in rare-earth halide perovskites10Anti‐Thermal Quenching of Sb‐Doped Cs 2 ZnCl 4 : Electronic Mechanism and Device Applications3Pb 2+ /Mn 2+ co-doping enables blue-to-white luminescence tuning in Rb₃Cd₂Cl₇ metal halide perovskites0Modulating Ultraviolet‐Visible‐Near Infrared Emission in Hybrid Metal Halides via ns 2 Ion Doping17Non‐invasive deep‐tissue temperature monitoring via high‐performance optical nano‐thermometer0Anti-Thermal-Quenching Phosphors Based on Metal Halides16Primitive Ligands Drive 1D CsPbI 3 Nanostructures with Strongly Polarized Photoluminescence3Primitive Ligands Drive 1D CsPbI 3 Nanostructures with Strongly Polarized Photoluminescence0A synergistic strategy of defect engineering and composite structure to achieve thermal quenching resistance and high-brightness cyan-green LuASG:Ce phosphor ceramics3Enhancing Anti-Thermal Quenching Performance in a Broadband Blue-Emitting Ba2ZnSi2O7: Bi3+ Phosphor via Increasing Zinc vacancy Concentration0Highly efficient luminescent I − -doped CsCdCl 3 perovskite with exceptional deliquescence resistance for multi-scale anti-counterfeiting0Recent Advances in Cation-Engineered A 3 BX 6 Metal Halide Perovskite for Enhanced Radiative Transition12全无机金属卤化物纳米晶复合玻璃与光纤的研究进展（特邀）0A robust anti-thermal quenching red phosphors: Cs 2 ZrCl 6 :Sb 3+2Achieving Antithermal Quenching Orange Photoluminescence in Sb 3+ -Doped CsCd 5 Cl 11 All-Inorganic Halides1Defect‐Assisted Self‐Trapped Exciton Emission in Zero‐Dimensional K 3 InCl 6 Perovskite: Reversible Hydration Switching Toward Multimodal Anti‐Counterfeiting1Intrinsically Thermally Robust Nanocrystals for High‐Flux Photonics9Multimode Luminescence Tailoring and Antithermal Quenching Effect in Cs 2 NaLuCl 6 via Sb 3+ /Ho 3+ /Yb 3+ Multidoping for Color‐Coded Encryption and Real‐Time Temperature Responses3Achieving High Photoluminescence Quantum Yield in Sb‐Doped Indium‐Based Hybrid Halides for Single‐Component Warm White LEDs6Polarity‐Gated Anti‐Thermal Luminescence in a Reentrant Luminescent Ferroelectric: (3,3‐difluoropyrrolidinium) 2 SbCl 5 with Dual Curie Points0Hydrochloric Acid-Assistant Powder-to-Powder Strategy for Synthesis of High-Quality Te 4+ -Doped Cs 2 ZrCl 6 Perovskite Microcrystals for X-ray Imaging1Synergistic Multi‐Strategy Engineering of Temperature‐Responsive Self‐Trapped Excitons in Tin‐Based Double Perovskite Nanocrystals Enables High‐Sensitivity Fluorescence Thermometry0Multiphonon Relaxation Inhibition and Photon Cutting Multiplication in Cs 2 NaYCl 6 : Ho 3+ /Er 3+ for Information Encryption and NIR Bioimaging0Enhancing anti-thermal quenching performance in a broadband blue-emitting Ba2ZnSi2O7: Bi3+ phosphor via increasing zinc vacancy concentration0Ultrafast dual-pathway room-temperature synthesis of 0D inorganic metal halides K3SbCl6 with near-unity photoluminescence quantum yield0A Zero‐Thermal Quenching Near‐Infrared La 3 SbO 7 :Nd 3+ Phosphor Based on High‐Symmetry Coordination Site0Tunable thermally enhanced lasers based on 727 nm-emitting aqueous carbon dots3Multi-wavelength NIR-II luminescence in lanthanide-doped Rb3InCl6 nanocrystals via Sb3+ sensitization0Novel Organic–Inorganic Hybrid Cu(I)‐Based Metal Halides: Anti‐Thermal Quenching, Interconvertible Structure and Encryption Application0Jahn–Teller Effect Dominates the Left‐Hand Rule: Magneto‐Optics in Metal Halide Lattice0Jahn–Teller Effect Dominates the Left‐Hand Rule: Magneto‐Optics in Metal Halide Lattice0Synergistic Effects of Lattice Stability and Frenkel Defects Designed for Anti‐Thermal Quenching X‐Ray Scintillators1The Anti‐Thermal Quenching Phosphor Landscape: Mechanisms, Materials, and Applications0Bright Red Self-Trapped Exciton Emission with Highly Linear Polarization in Bi-Doped Wide Bandgap In-Plane Anisotropic GaPS40Luminescence properties and ns2-related mechanism of Sb3+-activated Sr2YTaO6 red phosphors0Integrating Fluorescence from Self-Trapped Excitons and Phosphorescence in Zero-Dimensional Metal Halides for Time-Resolved Dynamic Information Encryption0Near‐Unity Linear Polarization of Self‐Trapped Exciton Emission in Cu 3 PS 4 With Highly Anti‐Thermal‐Quenching for Sensitive Optical Thermometry0Enhanced Anti-thermal Quenching of 3,8-Dibromo-1,10-phenanthroline-Based MOFs for Phosphor-Converted LED0Crystal‐Field Engineering of Excited‐State Dynamics in Sb 3+ ‐Doped Metal Halides for Versatile Optoelectronic Applications0

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  49. A synergistic strategy of defect engineering and composite structure to achieve thermal quenching resistance and high-brightness cyan-green LuASG:Ce phosphor ceramics

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  50. Enhancing Anti-Thermal Quenching Performance in a Broadband Blue-Emitting Ba2ZnSi2O7: Bi3+ Phosphor via Increasing Zinc vacancy Concentration

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