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RESEARCH PAPER · Applied Materials Today · 2024

Band gap analysis in MOF materials: Distinguishing direct and indirect transitions using UV–vis spectroscopy

Pedro H. M. Andrade, Christophe Volkringer, Thierry Loiseau, Antonio Tejeda, Matthieu Hureau, Alain Moissette

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Band gap analysis in MOF materials: Distinguishing direct and indirect transitions using UV–vis spectroscopyOriginalEnhanced Catalytic Activity of Tio2 Nanotubes Decorated with Holmium: Investigation on Hydrogen Production and Photoelectrochemical Properties Prepared at Various Ph Conditions0Hydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials9Standardisation of Ag: DNA Base-Pairs Ratio for Optimum Fluorescence0Standardization of Ag: DNA Base-Pair Ratio for Optimum Fluorescence0Z-Scheme Heterojunction Pmov/Nh2–Mil-125 Electrostatic Self-Assembly for Enhancing Photocatalytic Nitrogen Fixation Performance: Constructing Built-In Electric Field and Synergistic Effect to Regulate Carrier Separation0Metal organic framework anchored onto biowaste mediated carbon material (rGO) for remediation of chromium (VI) by the photocatalytic process25Anatase TiO2/Defective UiO-66 porous octahedral S-scheme heterojunctions toward optimized photocatalytic performance6New Multifunctional Materials for Potential Applications in Molecular Electronics and Spintronics0Dielectric study and electrochemical detection of ascorbic acid using modified electrode treated with europium-doped tricalcium aluminate nanoparticles7Comprehensive Investigation of Perovskite Materials for Photocatalytic, Photovoltaic, and Optoelectronic Applications: Recent and Advance Challenges and Goals22Recent progress of NH2-MIL-125(Ti)-based photocatalytic system in energy production and environmental purification50The comparative study of the empirical and DFT theoretical properties of ZnSnO3 perovskite nanoparticles4(Co, S)-Codoped BiOBr as a novel signal probe coupled with LAMP (H+)-pH responsive photoelectrochemistry biosensor for ultrasensitive detection of microRNA13Investigating the role of Ag-doped ZnO thin films in UV photodetectors produced via laser assisted chemical bath growth technique14Exploration of deep UV-NLO responses of non-conjugated crystal systems by harnessing aprotic solvents: DFT vs experimental4Construction of cobalt-decorated Ag2WO4/g-C3N4 recombination-delayed nano-heterojunction for enhanced visible light photocatalytic activity33TiO2-loaded phosphogypsum-modified biochar for the removal of ofloxacin and Cu2+: Performance, mechanisms, and toxicity assessment23Advanced XPS-Based Techniques in the Characterization of Catalytic Materials: A Mini-Review40Theoretical calculations of nonlinear optical responses for interpreting nonconjugated molecular systems to affect non-optimal properties5Wet-chemical preparation and physicochemical characterization of nanostructured Zn-Bi2O3/CeO2 composite: A visible-light-driven catalyst for the annihilation of pharmaceutical pollutant15Enhanced UV photodetector using Mg-doped ZnO sub-micro tube films synthesized through laser-assisted chemical bath growth17Nanostructured codoped neodymium orthoferrite synthesized via the hydrothermal route for photocatalytic annihilation of crystal violet dye278-Anilino-1-naphthalenesulfonate-Conjugated Carbon-Coated Ferrite Nanodots for Fluoromagnetic Imaging, Smart Drug Delivery, and Biomolecular Sensing40Synthesis and Characterization of TiO2 Thin Films Modified with Anderson-Type Polyoxometalates (Ni, Co, and Fe)6Investigating the enhanced UV photoresponse of Cu-doped ZnO thin films synthesized via laser assisted chemical bath growth1Explore the physical properties of the synthesized UiO-66, Zn-BiOBr, and Zn-BiOBr/UiO-66 heterostructures for optical applications19Improving membrane fouling via high phyllosilicate properties of ZnO-Kaolin in pilot-scale hybrid membrane photocatalytic reactor (MPR) for superior river water treatment4Enhancing photocatalytic nitrogen fixation via electrostatic self-assembly Z-scheme PMoV/NH2–MIL-125 heterojunction: Improved carrier separation through built-in electric field and synergistic effects13High-efficiency river water treatment via pilot-scale low-pressure hybrid membrane photocatalytic reactor (MPR) utilizing ZnO-Kaolin photocatalyst11Fabrication of recoverable Bi2O2S/Bi5O7I/ZA hydrogel beads for enhanced photocatalytic Hg0 removal in the presence of H2O2164In situ synthesis of RGO and CNT-templated diamond-shaped Fe-based metal-organic frameworks: Exploring their remarkable photocatalytic and antioxidant properties12Preparation, characterization, and study of radiation shielding performance of YBa2Cu3Oy/WO3 ceramics exposed to different gamma rays doses5Integration of cobalt coordination polymer-based triboelectric nanogenerators as sustainable power sources for self-driven selective photocatalytic reactions12Experimental and theoretical investigations of crab shell-based CaO nanoparticles for the photodegradation of penicillin G in water2Recent developments in applications of G-CuO nanocomposites for photocatalytic dye removal4UTSA-16(Zn) for SO 2 detection: elucidating the fluorescence mechanism9Synthesis of Mg doped ZnO cauli-flower nanostructures using chemical spray and its investigation for ammonia gas sensing at room temperature17Enhancing the optical properties of chitosan-based biopolymer for optoelectronic applications using natural dye extracted from hollyhock waste flowers21Exfoliated two-dimensional bimetallic Ni 0.6 Co 0.4 -metal organic framework nanosheets with mixed ligands for enhanced acid electrocatalytic water oxidation20Effect of organic linker substituents on properties of metal–organic frameworks: a review23Enhancement of built-in electric field strength of BiOCl/NMT Z-scheme heterojunctions through photoinitiated defects for optimized photocatalytic performance2Formation of polysulfides as a smart strategy to selectively detect H 2 S in a Bi( iii )-based MOF material10Green Synthesis of Iron Oxide Nanoparticles Using Melastoma malabathricum Leaf Extract for Photocatalytic Degradation of Methylene Blue and Antibacterial Activity3Highly textured single-crystal-like perovskite films for large-area, high-performance photodiodes5Metal–organic frameworks built from a carborane linker isolating ideal one-dimensional large-spin chains of Co ( S = 3/2) or Ni ( S = 1)4NH 2 -MIL-125(Ti) and its functional nanomaterials – a versatile platform in the photocatalytic arena69Physical and structural properties of zeolite activated by iron atom docking: A DFT study0Physical characteristics of polymer composites based on PVA doped with Mn2+ metal complexes synthesized by green approach: insights to linear and optoelectronic optical properties18The influence of solvent and number of layers on the homogeneity and properties of ZnO thin films obtained by spin-coating method2Theoretical study of the mechanisms of activation/deactivation of luminescence in a UiO-66 type sensor modified with Ln 3+ (Eu and Tb) as dopant ions7Transition metal-based MOFs for Fenton-like photocatalytic degradation of organic pollutants: Performance, stability, and biocompatibility16Perspective Chapter: An 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single −doped and co-doped Ba0.5Sr0.5TiO3 phosphors for dynamic anti-counterfeiting and fingerprint recognition applications7Charge transfer in hybrid quantum dot / metal-organic framework systems: Current understanding and future challenges9Porous titanium nitride thin film for enhanced biosensing applications5Green hydrothermal synthesis of Mg-doped transition metal dichalcogenides using Camellia sinensis extract for enhanced energy storage9Construction and fabrication of Zn(In0.1Ga0.9)2O4/NH2-MIL-125(Ti-Zr) composite materials with S-scheme heterojunction for highly efficient photocatalytic degradation of organic pollutants1Obtaining and characterization of semiconductors ceramics based on barium titanate with graphene insertion1Role of Solvents in Iron Nanoparticle Synthesis: Analyzing Water and 1‑Methyl-2-Pyrrolidone with Green Tea Extract as a Reducing Agent1Piezoceramics Boosting Photocatalytic Hydrogen Evolution of Covalent Organic Frameworks16Benchmarking Selected Density 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freshwater and industrial wastewater using TiO2–CuO–clay soil nanocomposites6Crystal growth by chemical vapor transport method and photoelectric properties of SnS, Sn2S3, SnS24Improving Bandgap Determination by Optical Spectroscopy: Comparative Evaluation of ISARS, UV–vis, and Diffuse Reflectance12Exploring the structural, optoelectronic behavior and non-linear optical response of BaFe12O19 M-type hexaferrite material as a promising solar cell absorber9Metal–organic frameworks for high-performance removal of sunset yellow dye: Combined Box-Behnken design and theoretical insights into adsorption4Bandgap-engineered Mn-doped CdS photocatalysts for enhancing the photocatalytic hydrogen production activity12Fabrication of Ag(l) MOF nanoparticles and ultrathin g-C3N4 nanosheets Co-decorated with Ag3VO4: A versatile bifunctional catalyst for efficient green hydrogen production6pH-triggered Schottky heterojunctions for NIR-II-activated and tumor-specific pyroelectrodynamic and photothermal therapy3Rod-shaped copper-based metal-organic framework: An efficient UV-activated photocatalyst for Congo Red degradation6Strategic engineering of structural complexity in metal–organic frameworks18Highly Nonlinear Metal‐Organic Framework Microcrystal for Ultrabroadband and Multiwavelength Coherent Light Emission5First photocatalytic investigation on Cd–Mn–O nanocomposites for the degradation of Eriochrome Black T2MnCo2O4 nanostructures: hydrothermal and co-precipitation synthesis, first investigation and optimization for photocatalytic degradation of ES3Green Synthesis of Mn-MOFs with Tunable Optical and Structural Properties Through Ligand Functionality and Framework Design2Combined experimental and numerical approach for the optimization of double Cs2AgBiBr6 perovskite solar cells: Ab initio study, simulation and performance comparison6Graphene oxide-incorporated Iron based MOFs: A dual functional material for photocatalytic and antioxidant application3Enhanced Performance of Inverted Perovskite Solar Cells Employing NiOx and Cu-Doped NiOx Nanoparticle Hole Transport Layers4Tuning Ultra‐Narrow Direct Bandgap in α‐Sn Nanocrystals: A CMOS‐Compatible Approach for THz Applications0Photo-degradation of methylene blue using the stable rare-earth metal substituted oxygen-deficient BaFeO3-x perovskites2Ce-Zr@Nd-BTC MOF coatings: bridging green chemistry and high-efficiency solar panels0Three-dimensional nano-architecture of copper sulfide/nitrogen-doped titanium dioxide with dual heterojunction for efficient photocatalytic hydrogen generation5Green Synthesis of Titanium Dioxide Nanoparticles: Characterization and Evaluation of Their Potential for Photocatalytic and Dielectric Applications16Mini- Review on Metal Organic Frameworks for Electro Catalytic and Photo Catalytic Water Splitting0Development and comparative investigation of structural and functional properties of Ni-based metal–organic frameworks designed for photocatalytic hydrogen production0Dielectric characterization and morphology of 0.7BaTiO3-0.3BaZr0.5Ti0.5O3 thin films at various annealing temperatures for multilayer ceramic capacitor (MLCC)0Dominance of lattice strain over crystallite size in the band gap widening of microwave-sintered PtO2 (PnNm)/C nanocomposites0Effect of temperature and gamma irradiation on dielectric properties of FeGaInS 4 /PVA composites6Microtron electron beam enables post-synthetic defect engineering in ultrasmall ceria nanocrystals0Microwave-assisted synthesis, crystal structures, and photophysical properties of functionalized benzo[ b ]furans0Middle-temperature thermally stimulated transformations of Cu–Si–O films0Perylene functionalized fluorescent zirconium based metal–organic frameworks for selective sensing of Cu 2+ , Pb 2+ , and Fe 3+ ions0Synthesis, spectroscopic characterization and DFT calculations of two-dimensional monoclinic and orthorhombic phases of metal–organic frameworks based on BTC–2,2′-bipyridine and Cu( ii ) ions0The effect of pineapple peel extract and tantalum doping on the microstructure and composition of BT-BZT thin films at an annealing temperature of 700°C0Unlocking the potential of interface engineering in metal chalcogenides@ZIF-8 photocatalysts for enhanced biofuel production0An Organic–Inorganic Hybrid Ferroelastic Semiconductor with Thermochromic Effect2Structural and Electronic Insights into Titanium-Modified UiO-66: Probing Cation Substitution via Multi-Technique Characterization and High-Field (1.2 GHz) NMR3Impact of Nb2O5 on the Glass Structure and Quantum Efficiency of Eu3+–doped Phosphate Glasses0Development of a chloride-free dual-salt electrolyte based on Mg(NO3)2 and Mg(TFSI)2 for magnesium-sulfur batteries in a binary solvent system2Tailoring the Structural and Transport Properties of Ba 2 In 2 O 5 through Cr 6+ Substitution for Enhanced Oxygen Permeation0Plasma-Treated TiO 2 Nanostructures for Photocatalysis under Ultraviolet A and Visible Light Irradiation0Effect of Mn doping on the structure, morphology, composition, and optical properties of ZnO nanoparticles synthesized via a simple approach0Iron-doped UiO-66 for Rapid Removal of Tetracycline Antibiotic from Water3Thermochromic Hybrid Ferroelastic Semiconductor with Thermal/Electrical/Optical Switching Responses2De Novo Synthesis of Covalent Organic Frameworks: A Principle for Topology Selection and Profound π Electronic Effects0Modeling and experimental analyses for Chitosan/Zinc oxide nanocomposite13Covalent Organic Structures for Energy Storage and Catalysis: New Sustainable Developments and Progress2Tailoring the structure and morphology of hematite via Zn doping for superior photocatalytic degradation of Rhodamine B1Synergistic Effect of N Doping and Ag Loading on Photocatalytic Degradation Performance of Rhodamine B by ZnO Nanoarrays1Photoresponsive Metal–Organic Frameworks via Benzotrithiophene-Based Unique Double-Linker Walls0Strong Nature of the Melt in Under-Coordinated Se 80- x Te 20 Sb x Glasses0High-Accuracy Characterization of a Single Thin Film on a Substrate from One Transmittance Spectrum by an Advanced Envelope Method Addressing Voids, Tail Electron Transitions, and Deep-Level Electron Transitions in a-Si Films0

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