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RESEARCH PAPER · Interdisciplinary materials · 2024

Metallosalen covalent organic frameworks for heterogeneous catalysis

Wei Zhou, Wei Deng, Xing Qiang Lü

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Metallosalen covalent organic frameworks for heterogeneous catalysisOriginalCovalent Organic Frameworks: Synthesis and Applications for Photocatalysis23Designing Salen‐Based Porous Organic Polymers for Enhanced Electrolytic Water Splitting into Oxygen27Metallosalen Covalent Organic Frameworks with Integrated Organic–Inorganic Active Sites for Enhanced Li Storage23Dead Ends and Detours Towards a Rigid Hexasalicylic Aldehyde Precursor for Triptycene‐Based Porous Materials0Investigation of NiMoSe/Ti3C2Tx on Carbon Cloth as an Effective Electrocatalyst for the Hydrogen Evolution Reaction in an Acidic Medium10Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review3An Adaptive Palladium Single-Atom Catalyst Enabling Reactivity Switching between Borylation and C–C Coupling49Self-Standing Chiral Copper-Coordinated Covalent-Organic Framework Nanochannel Membrane for Enantioselective Sensing of Reducing Amino Acids11When covalent organic frameworks meet metals: From opportunities toward applications73A Highly Stable CM@Co 3 O 4 Photocatalyst for the Sustainable Synthesis of α‐Amino Acetals via Base‐Assisted C(sp 3 )‐H Functionalization0Metal–Covalent Organic Frameworks: Synthetic Strategies and Catalytic Applications in Organic Transformations2Dual‐Site Single‐Atom Ni Catalysts for Highly Efficient Ethylene Oligomerization to 1‐Hexene4Covalent organic frameworks for electrochemical water splitting0Designing Nonheme Single Atom Catalysts for Oxygen Reduction Reaction by High-Throughput Screening3Covalently Bonded S‐Scheme Polymer Heterojunction for Highly Efficient Solar Hydrogen Evolution3Programming Charge Dynamics in Photocatalytic Covalent Organic Frameworks through Heterometallic Symmetry Breaking11Electrochemically Assisted Biodiesel Production over a Nanoporous Benzobisthiazole-Based Sulfonated Covalent Organic Polymer at Room Temperature1Lanthanide ions embedded hydrazone-linked covalent organic frameworks for Catalyzing the Cyanosilylation and the synthesis of 2,3-Dihydroquinazolin-4(1H)-one derivatives0Advancing Cu‐Based Electrocatalysts for Efficient Hydrogen Evolution Reaction2Controlled Axial Growth and Morphological Evolution of Three-Dimensional Covalent Organic Frameworks Unveiled by Single-Crystal X-ray Diffraction1Single‐Atom Engineering on Transition Metal Dichalcogenides for Advanced Catalytic Applications1Synthesis of Hierarchical ZSM-5 Zeolite Mesocrystals with Controllable Macropores toward Enhanced Catalytic Performance0Simultaneous Electronic and Crystallographic Modulation of Cs 3 Bi 2 Br 9 by Single‐Element Sn Substitution for Enhanced CO 2 Photoreduction0Electrochemically In Situ Formed Active and Stable Surface Gradient Layer on Amorphous Ni‐La‐S‐O Catalyst for Efficient Hydrogen Evolution From Alkaline Seawater0Regulating the Second Coordination Sphere of Cu-Salen–Covalent Organic Frameworks via Substituent Engineering for Electrocatalytic CO2 Reduction to CO0Aliovalent Cl Substitution Modulates Oxygen‐Vacancy‐Related Defect States in Bi 2 O 2 S Toward Efficient Photocatalytic CO 2 ‐to‐CO Conversion0Br‐Mediated Interfacial Microenvironment Engineering Triggers Dual‐Site Oxide Pathway Mechanism for Stable Oxygen Evolution0

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  1. Covalent Organic Frameworks: Synthesis and Applications for Photocatalysis

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    Misbah Shahid, Aziz ur Rehman, Tayyaba Najam, Hammad Majeed, Marwan Shalash, Salah M. El‐Bahy, Muhammad Sufyan Javed, Syed Shoaib Ahmad Shah, Muhammad Altaf Nazir

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  2. Designing Salen‐Based Porous Organic Polymers for Enhanced Electrolytic Water Splitting into Oxygen

    Advanced Functional Materials · 2024-08-22

    Hiranmoy Pal, Arun Karmakar, Arnab Sadhukhan, Kalipada Koner, Shayan Karak, Rahul Kumar Sharma, Manasi Ghosh, Krishna Kishor Dey, Biswarup Pathak, Subrata Kundu, Rahul Banerjee

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  3. Metallosalen Covalent Organic Frameworks with Integrated Organic–Inorganic Active Sites for Enhanced Li Storage

    Advanced Functional Materials · 2025-01-07

    Hao Zhang, Xiandi Ma, Dong Lai Guo, Menggai Jiao, Yiyang Liu, Yongzheng Fang, M.C. Wu, Zhen Ping Zhou

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  4. Dead Ends and Detours Towards a Rigid Hexasalicylic Aldehyde Precursor for Triptycene‐Based Porous Materials

    ChemistryEurope · 2025-03-18

    Dennis Reinhard, Sven M. Elbert, Wen‐Shan Zhang, Frank Röminger, Rasmus R. Schröder, Michael Mastalerz

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  5. Investigation of NiMoSe/Ti3C2Tx on Carbon Cloth as an Effective Electrocatalyst for the Hydrogen Evolution Reaction in an Acidic Medium

    Energy & Fuels · 2025-03-18

    Nitish Srivastava, Mohammad Saquib, Pratham Arora, Amit C. Bhosale

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  6. Molecular Hybrid Photocatalysts for CO2 Photoreduction by Hybridization of Molecular Catalysts and Photoactive Covalent Organic Frameworks – A Review

    Chemistry - A European Journal · 2025-04-17

    Wenjing Li, Fan Ma, Bruno M. Aramburu-Trošelj, Jia‐Wei Wang, Gangfeng Ouyang

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  7. An Adaptive Palladium Single-Atom Catalyst Enabling Reactivity Switching between Borylation and C–C Coupling

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  8. Self-Standing Chiral Copper-Coordinated Covalent-Organic Framework Nanochannel Membrane for Enantioselective Sensing of Reducing Amino Acids

    Analytical Chemistry · 2025-06-24

    Chen‐Yan Zheng, Haoze Li, Hai‐Long Qian, Cheng Yang, Xiu‐Ping Yan

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  9. When covalent organic frameworks meet metals: From opportunities toward applications

    Progress in Materials Science · 2025-07-21

    Deyu Wu, Hao Wang, Yingxia Nie, Haifei Wan, Shuai Liu, Song Yang, Hui Li, Heng Zhang, Chengzhou Zhu, Tianyi Ma

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  10. A Highly Stable CM@Co 3 O 4 Photocatalyst for the Sustainable Synthesis of α‐Amino Acetals via Base‐Assisted C(sp 3 )‐H Functionalization

    ChemCatChem · 2025-11-26

    Jiaxin Yang, Liang Zhou, Liang Zhou, Xiaoju Zhang, Qingqing Pan, Yun Zhu, Li Qin, Limei Zhou, Limei Zhou

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  11. Metal–Covalent Organic Frameworks: Synthetic Strategies and Catalytic Applications in Organic Transformations

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    Qingqing Shao, Guoqing Huang, Tong Wang, Ming Yuan Yang, Daoshan Yang, Xiubin Bu, Xiaobo Yang, Zhen Zhao

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  12. Dual‐Site Single‐Atom Ni Catalysts for Highly Efficient Ethylene Oligomerization to 1‐Hexene

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  13. Covalent organic frameworks for electrochemical water splitting

    EnergyChem · 2026-02-27

    Sujan Mondal, Sayantan Chongdar, Santu Ruidas, Javeed Mahmood, Thien S. Nguyen, Dalal Alezi, Asim Bhaumik, Cafer Tayyar Yavuz

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  14. Designing Nonheme Single Atom Catalysts for Oxygen Reduction Reaction by High-Throughput Screening

    ACS Applied Materials & Interfaces · 2026-03-02

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  15. Covalently Bonded S‐Scheme Polymer Heterojunction for Highly Efficient Solar Hydrogen Evolution

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  16. Programming Charge Dynamics in Photocatalytic Covalent Organic Frameworks through Heterometallic Symmetry Breaking

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    Tiantian Wen, Xiaohui Liu, Jingru Feng, Hankang Zhong, Wei Huang, Siming Huang, Can Xue, Guosheng Chen, Xiantai Zhou, Gangfeng Ouyang

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  17. Electrochemically Assisted Biodiesel Production over a Nanoporous Benzobisthiazole-Based Sulfonated Covalent Organic Polymer at Room Temperature

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    Arati Samal, Anushree Jain, Lalita Wagh, Apurba Kr. Das

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  18. Lanthanide ions embedded hydrazone-linked covalent organic frameworks for Catalyzing the Cyanosilylation and the synthesis of 2,3-Dihydroquinazolin-4(1H)-one derivatives

    Inorganica Chimica Acta · 2026-05-18

    Kexin Wang, Liang Zhao, Rui Yang, Cheng He

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  19. Advancing Cu‐Based Electrocatalysts for Efficient Hydrogen Evolution Reaction

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    Shenhua Qian, Bo Chen, Wenshu Chen, Shiquan Zhang, Yongping Du, Guoqiang Luo, Qiang Shen, Jian Zhang

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  20. Controlled Axial Growth and Morphological Evolution of Three-Dimensional Covalent Organic Frameworks Unveiled by Single-Crystal X-ray Diffraction

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  21. Single‐Atom Engineering on Transition Metal Dichalcogenides for Advanced Catalytic Applications

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  23. Simultaneous Electronic and Crystallographic Modulation of Cs 3 Bi 2 Br 9 by Single‐Element Sn Substitution for Enhanced CO 2 Photoreduction

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  25. Regulating the Second Coordination Sphere of Cu-Salen–Covalent Organic Frameworks via Substituent Engineering for Electrocatalytic CO2 Reduction to CO

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  27. Br‐Mediated Interfacial Microenvironment Engineering Triggers Dual‐Site Oxide Pathway Mechanism for Stable Oxygen Evolution

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