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RESEARCH PAPER · Inorganic Chemistry · 2024

Sb4O5I2: Enhancing Birefringence through Optimization of Sb/I Ratio for Alignment of Stereochemically Active Lone Pairs

Jingyu Guo, Xiangtong Zhan, Jiating Lan, Xin Liu, Shuang Zhao, Xi Xu, Li‐Ming Wu, Ling Chen

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Sb4O5I2: Enhancing Birefringence through Optimization of Sb/I Ratio for Alignment of Stereochemically Active Lone PairsOriginalExploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence10A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties0Tin chalcohalide Sn 11 (PS 4 ) 4 I 10 obtained from structural-template-oriented synthesis: exhibiting balanced infrared nonlinear optical performance6Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal28The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation3Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals71Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals8From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14(C9H7BrN)BF4 and (C9H7BrN)2SiF6: Two Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions7A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5

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  1. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  2. Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence

    Inorganic Chemistry · 2024-06-04

    Han Luo, Yu Zhang, Tingyu Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

    Read original paper ↗ ·

  3. A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range

    Inorganic Chemistry · 2024-07-26

    Jie Song, Xianghao Kong, Conggang Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  4. First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties

    Physica Scripta · 2024-10-24

    Hongheng Chen, Mei Hu, Jialong Wang, Haiming Duan, Qun Jing, Zhaohui Chen

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  5. Tin chalcohalide Sn 11 (PS 4 ) 4 I 10 obtained from structural-template-oriented synthesis: exhibiting balanced infrared nonlinear optical performance

    Inorganic Chemistry Frontiers · 2024-12-19

    Cuier Deng, Xi Qing Xu, Yuhan Hu, Jingyu Guo, Li‐Ming Wu, Ling Chen

    Read original paper ↗ ·

  6. Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties

    Dalton Transactions · 2025-01-01

    Maqsood Iqbal, Jiazheng Zhou, Hongshan Wang, Juanjuan Lu, Shilie Pan, Junjie Li

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  7. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  8. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie · 2025-02-22

    Xinyang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  9. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

    Xin‐Yang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  10. The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation

    Chemical Physics Letters · 2025-02-22

    Jialong Wang, Enshen Wang, Xiuhua Cui, Peng Li, Qun Jing, Zhaohui Chen

    Read original paper ↗ ·

  11. Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals

    Angewandte Chemie International Edition · 2025-03-11

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

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  12. Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals

    Angewandte Chemie · 2025-03-11

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

    Read original paper ↗ ·

  13. From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect

    Laser & Photonics Review · 2025-04-30

    Qian‐Qian Chen, Ming‐Zhi Zhang, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  14. (C9H7BrN)BF4 and (C9H7BrN)2SiF6: Two Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions

    Crystal Growth & Design · 2025-06-26

    Yaoguo Shen, Mengqing Wu, Jiajia Xiong, Yingshi Lin, M.-R. Li

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  15. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

    Read original paper ↗ ·

  16. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

    Read original paper ↗ ·

  17. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  18. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

    Read original paper ↗ ·
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