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RESEARCH PAPER · Angewandte Chemie International Edition · 2024

Spontaneous Symmetry Breaking of Achiral Molecules Leading to the Formation of Homochiral Superstructures that Exhibit Mechanoluminescence

Zheng‐Fei Liu, Xin‐Yi Ye, Lihua Chen, Li‐Ya Niu, Wei Jun Jin, Shaodong Zhang, Qing‐Zheng Yang

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Spontaneous Symmetry Breaking of Achiral Molecules Leading to the Formation of Homochiral Superstructures that Exhibit MechanoluminescenceOriginalOn Sense and Deform: Molecular Luminescence for Mechanoscience18Perfluoroaryl⋯aryl interaction: The most important subset of π -hole⋯ π bonding40Dual-response signal under mechanical stimulation: Alkyl substituent effect on the fine-tuning of molecular packing1Mechanical stimulus-responsive luminescence: dynamic and durable mechanoluminescence based on PTZ derivatives0Symmetry breaking of rare earth Eu( iii ) complexes with an achiral aromatic ligand: achieving strong emission and ultra-narrowband circularly polarized luminescence6Mechanoluminescence from Organic–Inorganic Metal Halide Perovskite Derivative20Recent Progress of Mechanofluorochromism and Mechanoluminescence for Phenothiazine Derivatives and Analogues39Symmetry Breaking: Case Studies with Organic Cage-Racemates21Mechanoluminescence from Amorphous Organic Luminogens16Chiral Competition Reflected by Circularly Polarized Luminescence Signal Inversion in Supramolecular Assembly of Pyrene‐Amino Acid Derivatives and γ‐Cyclodextrin4Halogen bond-modulated solid-state reordering and symmetry breaking of azahelicenes8Boosting chiroptical activity of homochiral gold nanoparticles: iodide ion-assisted synthesis via citrate-reduction method4Probing Multilevel Chiroptical Activity in Organic Supramolecular Microcrystals for High‐Performance Circularly Polarized Lasing8Probing Multilevel Chiroptical Activity in Organic Supramolecular Microcrystals for High‐Performance Circularly Polarized Lasing0Spontaneous Symmetry Breaking in Liquid Crystalline Phase of platinum(II)-Based Bent-Shaped Achiral Metallomesogens2Symmetry‐Breaking Directed Assembly in Achiral Point Groups for Circularly Polarized Room‐Temperature Phosphorescence9Single-component-based multicolor emissions enabled by symmetry breaking10Shear Force Cropping Organic Molecular Crystals Based on Adaptive Hydrogen Bonding Network Reconstructions8Supramolecular Mechanoluminescence via Fluorine Interactions6Circularly polarized luminescence: an easy path from molecules to supramolecular systems and beyond4Mechanoluminescent materials: toward advanced optoelectronic sensing and biomedical applications0Unlocking spontaneous chiral resolution in silver clusters through steric and anionic control0Symmetry Breaking: Orchestrating Dynamics in Molecular Crystals1Engineering Chirality in the Solid State: Co‐Crystallization as a Strategy for Chiral Induction and Resolution3Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides4Supersaturation-controlled assembly pathway directs hierarchical chirality expression in ionic luminophores2High Performance and Circularly Polarized Mechanoluminescence From Noncentrosymmetric Crystals With Pronounced Macroscopic Polarity0

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27 direct citing papers saved.

  1. On Sense and Deform: Molecular Luminescence for Mechanoscience

    ACS Applied Optical Materials · 2024-06-03

    Yuichi Hirai

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  2. Perfluoroaryl⋯aryl interaction: The most important subset of π -hole⋯ π bonding

    Chemical Physics Reviews · 2024-07-09

    Weizhou Wang, Wen Xin Wu, Yu Zhang, Wei Jun Jin

    Read original paper ↗ ·

  3. Dual-response signal under mechanical stimulation: Alkyl substituent effect on the fine-tuning of molecular packing

    Journal of Luminescence · 2024-09-03

    Jianai Chen, Mingjiao Sun, Yujie Dong, Weijun Li, Fener Chen

    Read original paper ↗ ·

  4. Mechanical stimulus-responsive luminescence: dynamic and durable mechanoluminescence based on PTZ derivatives

    Journal of Materials Chemistry C · 2025-01-01

    Yun Yu, Jiaming Xie, Peihao Li, Biao Xiao, Can Wang, Renqiang Yang

    Read original paper ↗ ·

  5. Symmetry breaking of rare earth Eu( iii ) complexes with an achiral aromatic ligand: achieving strong emission and ultra-narrowband circularly polarized luminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Zhi Chen, Wenmin Xu, Chunhua Hu, Zhen Liu, Suwen Lin, Shaomeng Guo, Zhupin Chen, Mianling Huang, Zhen‐Qiang Yu, Weihong Zhu, Yue Wu

    Read original paper ↗ ·

  6. Mechanoluminescence from Organic–Inorganic Metal Halide Perovskite Derivative

    Advanced Science · 2025-01-14

    Hongyuan Zhao, Xinyu Yang, Yunfei Bai, Qichao Meng, Ziying Wen, Haibo Sun, Qilin Wei, Dan Ding Huang, William W. Yu, Feng Liu

    Read original paper ↗ ·

  7. Recent Progress of Mechanofluorochromism and Mechanoluminescence for Phenothiazine Derivatives and Analogues

    Chemistry - A European Journal · 2025-01-24

    He Zhao, Baiyang Fan, Siwen Hu, Xiaojing Liu, Xiaojing Liu, Pengchong Xue

    Read original paper ↗ ·

  8. Symmetry Breaking: Case Studies with Organic Cage-Racemates

    Accounts of Chemical Research · 2025-01-28

    Chenhao Chen, Shaodong Zhang

    Read original paper ↗ ·

  9. Mechanoluminescence from Amorphous Organic Luminogens

    Journal of the American Chemical Society · 2025-03-02

    Zongliang Xie, Huangjun Deng, Xiangyu Ge, Zhenguo Chi, Bin Liu

    Read original paper ↗ ·

  10. Chiral Competition Reflected by Circularly Polarized Luminescence Signal Inversion in Supramolecular Assembly of Pyrene‐Amino Acid Derivatives and γ‐Cyclodextrin

    Chemistry - A European Journal · 2025-03-11

    Yijun Zhang, Yihuan Sun, Huajing Li, Huanhuan Dong, Min Dou, Ting Li, Jing Liu, Jian Kong, Yuangang Li

    Read original paper ↗ ·

  11. Halogen bond-modulated solid-state reordering and symmetry breaking of azahelicenes

    Nature Communications · 2025-04-22

    Juncong Liang, Fuwei Gan, Guoli Zhang, Chengshuo Shen, Huibin Qiu

    Read original paper ↗ ·

  12. Boosting chiroptical activity of homochiral gold nanoparticles: iodide ion-assisted synthesis via citrate-reduction method

    Journal of Colloid and Interface Science · 2025-06-18

    Miao Zhang, Chenxin Sun, Baoxin Li

    Read original paper ↗ ·

  13. Probing Multilevel Chiroptical Activity in Organic Supramolecular Microcrystals for High‐Performance Circularly Polarized Lasing

    Angewandte Chemie International Edition · 2025-06-24

    Shizhe Ren, Zheng‐Fei Liu, Penghao Li, Kang Wang, Jiannian Yao, Qing‐Zheng Yang, Yong Sheng Zhao, Haiyun Dong

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  14. Probing Multilevel Chiroptical Activity in Organic Supramolecular Microcrystals for High‐Performance Circularly Polarized Lasing

    Angewandte Chemie · 2025-06-24

    Shizhe Ren, Zheng‐Fei Liu, Penghao Li, Kang Wang, Jiannian Yao, Qing‐Zheng Yang, Yong Sheng Zhao, Haiyun Dong

    Read original paper ↗ ·

  15. Spontaneous Symmetry Breaking in Liquid Crystalline Phase of platinum(II)-Based Bent-Shaped Achiral Metallomesogens

    Inorganic Chemistry · 2025-06-25

    Jinxin Jiang, Xueqing Ning, Rui Zeng, Guo Zou, Bo Yang, Haifeng Wang, Wenhao Yu, Jintong Song, Hao Geng, Kaijun Luo, Ping Hu, Hai‐Liang Ni, Shilin Zhang

    Read original paper ↗ ·

  16. Symmetry‐Breaking Directed Assembly in Achiral Point Groups for Circularly Polarized Room‐Temperature Phosphorescence

    Advanced Materials · 2025-08-11

    Qihuan Li, Yizhou Song, Jiaqi He, Junsheng Zhang, Guo Zou, Yixiang Cheng

    Read original paper ↗ ·

  17. Single-component-based multicolor emissions enabled by symmetry breaking

    Nature Communications · 2025-08-30

    Simin Lin, Xubin Wang, Hao Li, Jiancheng Zhou, Ruijuan Wen, Jun Ma, Shiwei Yin, Ling‐Ya Peng, Haonan Peng, Yu Fang

    Read original paper ↗ ·

  18. Shear Force Cropping Organic Molecular Crystals Based on Adaptive Hydrogen Bonding Network Reconstructions

    Journal of the American Chemical Society · 2025-09-23

    Hui‐Yao Lin, Le Li, Chengxi Zhao, Fei Tong, Qi Zhang, Chengyuan Yu, He Tian, Ben L. Feringa, Da‐Hui Qu

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  19. Supramolecular Mechanoluminescence via Fluorine Interactions

    Angewandte Chemie International Edition · 2025-12-12

    Weiguo Qiao, Kai Chang, Xinyu Yu, Zhenghe Zhao, Ningyuan Zhao, Bao Li, Qianqian Li, Zhong’an Li, Zhen Li

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  20. Circularly polarized luminescence: an easy path from molecules to supramolecular systems and beyond

    Chemical Society Reviews · 2026-01-01

    Francesco Bertocchi, Davide Giavazzi, Shahana Nizar, D. K. Andrea Phan Huu, Lorenzo Savi, Francesca Terenziani, Cristina Sissa, Anna Painelli

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  21. Mechanoluminescent materials: toward advanced optoelectronic sensing and biomedical applications

    Journal of Materials Chemistry C · 2026-01-01

    Jiaqiang Wang, Zhen Li

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  22. Unlocking spontaneous chiral resolution in silver clusters through steric and anionic control

    Chemical Science · 2026-01-01

    Jin Liu, Zi‐Ang Nan, Qing Yun Li, Chan-Qi Shen, Zuo-Bei Wang, Fulin Lin, Ting Chen, Luyao Liu, Zhuo-Zhou Xie, Zhu Zhuo, Wei Wang, You‐Gui Huang

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  23. Symmetry Breaking: Orchestrating Dynamics in Molecular Crystals

    Crystal Growth & Design · 2026-03-21

    Hui‐Yao Lin, Da‐Hui Qu, Fei Tong

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  24. Engineering Chirality in the Solid State: Co‐Crystallization as a Strategy for Chiral Induction and Resolution

    Chirality · 2026-04-19

    Ramamohana Reddy Maddike, Vivek Sharma, Viswanadha Srirama Rajasekhar Pullabhotla, Vinod Kumar Vashistha

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  25. Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides

    Angewandte Chemie International Edition · 2026-05-22

    Y Z Zhang, Yuchao Li, Y N Wu, Bing Teng, Hongting Lu, Xingxing Jiang, Shijia Sun, C Hu, Dongwei Zhai, Lifeng Cao, Jinkang Ma, R K Li, Degang Xu, Zheshuai Lin, Degao Zhong

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  26. Supersaturation-controlled assembly pathway directs hierarchical chirality expression in ionic luminophores

    Proceedings of the National Academy of Sciences · 2026-06-17

    Qiong Wang, Haidi Liu, Ruyuan Zhang, X X Xu, Youcai Han, J Yao, Yongli Yan

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  27. High Performance and Circularly Polarized Mechanoluminescence From Noncentrosymmetric Crystals With Pronounced Macroscopic Polarity

    Advanced Materials · 2026-06-25

    Qing Xiang Li, Xuan Chi Yu, Xuemin Lü, Wang Zhang Yuan, Qinghua Lu

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