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RESEARCH PAPER · Materials Horizons · 2023

Borohydride and halide dual-substituted lithium argyrodites

Ji-Hoon Han, Do Kyung Kim, Young Joo Lee, Young Joo Lee, Young-Su Lee, Young-Su Lee, Kyung‐Woo Yi, Young Whan Cho

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Borohydride and halide dual-substituted lithium argyroditesOriginalEnhancement of ionic conductivity in Li argyrodite solid electrolytes with bromide and borohydride anions for all-solid-state batteries13Unlocking the secrets of ideal fast ion conductors for all-solid-state batteries73Synthesis and Electrochemical Properties of Hydrosulfide Solid Electrolytes7Hydrogen-Rich Argyrodite Solid Electrolytes for NCM/Li All-Solid-State batteries14Wet Mechanochemical Synthesis of BH4‐Substituted Lithium Argyrodites8Diffusion mechanisms of fast lithium-ion conductors171Doping Strategies for Improving Performance of Li‐Argyrodite Solid‐State Electrolyte27Dual-functional enhancement of argyrodite solid electrolytes with borohydride for high ionic conductivity and lithium metal compatibility via AgCl addition1Ternary doping enhances the moisture and electrochemical stability of Li5.5PS4.5Cl1.5 solid-state electrolyte3Structural insights into BH4− and Cl− co-substituted argyrodite solid electrolytes for superior ionic conductivity6Hydride Ion Conductors with Polyanionic Complex Anions10Quantifying the interfacial contact of active material–solid electrolyte interfaces in all-solid-state lithium-ion batteries15Understanding the Role of Borohydride Doping in Electrochemical Stability of Argyrodite Li 6 PS 5 Cl Solid‐State Electrolyte14Highly Deformable, Ion‐Conductive Borohydride‐Substituted Sulfide Electrolyte for Superior Performance at Low Stack Pressure13Enhanced ionic conductivity and interfacial compatibility in BH4––based lithium argyrodite solid electrolytes via Cu+ doping2Recent advances and remaining challenges of solid-state electrolytes for lithium batteries22Atmospheric stability enhancement of borohydride-substituted sulfide solid electrolytes via porous silica incorporation3Ag-Substituted Borohydride Argyrodite Sulfide Electrolytes for Superior Interfacial Stability in All-Solid-State Batteries2Cluster-based materials: design and applications5Electrode potential control of Li–Si alloys for safe and high-energy-density all-solid-state Li–S batteries0Phase−stabilized hydrosulfide argyrodite solid electrolytes with enhanced ionic conductivity and electrochemical stability for lithium metal all−solid−state batteries0NMR study of electrolytes for Li rechargeable batteries: from liquid to solid electrolytes2Mechanochemical-induced halide segregation for highly stable all-solid-state lithium batteries1Aliovalent indium incorporation in borohydride argyrodite for fast ionic transport and stable Li metal interphase0Electrochemically Induced Interphase by Complex Hydride Anions in Argyrodite Solid Electrolytes for Stable Lithium Metal All‐Solid‐State Batteries4Enhancing Li + Ion Transport via Dynamic Coupling With Borohydride Reorientation in Li 6 PS 5 X Argyrodites0HCl‐Free Mechanochemical Synthesis of Lithium Niobium Oxychlorides0

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  1. Enhancement of ionic conductivity in Li argyrodite solid electrolytes with bromide and borohydride anions for all-solid-state batteries

    Journal of Materials Chemistry A · 2024-01-01

    Hyungeun Seo, Yong‐Jin Jang, Jaeseong Yoo, Ji-Hoon Han, Young‐Su Lee, Jae Yup Jung, Soeun Lee, Kyung‐Woo Yi, Young Whan Cho, Woosuk Cho, Jae‐Hun Kim

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  2. Unlocking the secrets of ideal fast ion conductors for all-solid-state batteries

    Communications Materials · 2024-07-19

    Kartik Sau, Shigeyuki Takagi, Tamio Ikeshoji, Kazuaki Kisu, Ryuhei Sato, Egon Campos dos Santos, Hao Li, Rana Mohtadi, Shin‐ichi Orimo

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  3. Synthesis and Electrochemical Properties of Hydrosulfide Solid Electrolytes

    Korean Journal of Chemical Engineering · 2024-08-02

    Taeseung Kim, Taegyoung Lee, Sangryun Kim

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  4. Hydrogen-Rich Argyrodite Solid Electrolytes for NCM/Li All-Solid-State batteries

    ACS Energy Letters · 2024-08-21

    Taegyoung Lee, H. K. Park, Seunghee Joo, Hyerim Kim, Jeonghyun Kim, Taeseung Kim, Wonrak Lee, Youngbok Kim, Ji Young Kim, Kyungsu Kim, Woosuk Cho, Sangryun Kim

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  5. Wet Mechanochemical Synthesis of BH4‐Substituted Lithium Argyrodites

    Small Methods · 2024-09-05

    Ji‐Hoon Han, Y. S. Shin, Young Joo Lee, Sangdoo Ahn, Young‐Su Lee, Kyung‐Woo Yi, Young Whan Cho

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  6. Diffusion mechanisms of fast lithium-ion conductors

    Nature Reviews Materials · 2024-09-12

    KyuJung Jun, Yu Chen, Grace Wei, Xiaochen Yang, Gerbrand Ceder

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  7. Doping Strategies for Improving Performance of Li‐Argyrodite Solid‐State Electrolyte

    Energy Technology · 2024-10-15

    Qianjin Huang, Yinglei Wu, Zhongyi He, Sirui Wang, Jinhui Zhu, Xiaodong Zhuang

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  8. Dual-functional enhancement of argyrodite solid electrolytes with borohydride for high ionic conductivity and lithium metal compatibility via AgCl addition

    Journal of Materials Chemistry A · 2025-01-01

    Yong‐Jin Jang, Hyunsuk Noh, Hyungeun Seo, Jae‐Hun Kim

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  9. Ternary doping enhances the moisture and electrochemical stability of Li5.5PS4.5Cl1.5 solid-state electrolyte

    Journal of Materials Science Materials in Electronics · 2025-03-01

    Chenglin Cai, Kongjun Zhu, Yu Rao, Zhihan Kong, Ziyun Li, Xiaorao Wu, Yuqing Yang, Miaomiao Huang, Heng Zhou, Kang Yan, Jing Wang, Feng Shi, Jun Guo

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  10. Structural insights into BH4− and Cl− co-substituted argyrodite solid electrolytes for superior ionic conductivity

    Journal of Energy Storage · 2025-04-05

    Hyungeun Seo, Yong‐Jin Jang, Jaeseong Yoo, Ji-Hoon Han, Young‐Su Lee, Jae Yup Jung, Soeun Lee, Kyung‐Woo Yi, Young Whan Cho, Woosuk Cho, Jae‐Hun Kim

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  11. Hydride Ion Conductors with Polyanionic Complex Anions

    Journal of the American Chemical Society · 2025-04-17

    T.-W. Kim, Taeseung Kim, Taegyoung Lee, Ye‐Eun Park, Jeonghyun Kim, Seoungjae Kang, Hyerim Kim, Seokjae Hong, Naoki Matsui, Hyungsub Kim, Sangryun Kim

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  12. Quantifying the interfacial contact of active material–solid electrolyte interfaces in all-solid-state lithium-ion batteries

    Journal of Colloid and Interface Science · 2025-05-12

    Shunsuke Kawaguchi, Hirofumi Yasuda, Wataru Ogihara, Hikaru Sano, Minoru Kuzuhara, Takuhiro Miyuki

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  13. Understanding the Role of Borohydride Doping in Electrochemical Stability of Argyrodite Li 6 PS 5 Cl Solid‐State Electrolyte

    Advanced Materials · 2025-07-15

    Yixian Wang, Vikalp Raj, Qianqian Yan, Cole D. Fincher, Yuanshun Li, Rohit Raj, Hugo Celio, Andrei Dolocan, Guang Hua Yang, Frédéric A. Perras, Yet‐Ming Chiang, John D. Watt, Hong Fang, Puru Jena, David Mitlin

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  14. Highly Deformable, Ion‐Conductive Borohydride‐Substituted Sulfide Electrolyte for Superior Performance at Low Stack Pressure

    Advanced Materials · 2025-07-21

    Shunsuke Kawaguchi, Naomi Fukiya, Kei Ehara, Tomoyuki Ichikawa, Manami Yoshimura, Eishi Iso, Yuji Sasaki, Yuhei Horisawa, Yoshiteru Mizukoshi, Masaki Shimada, Naoya Ishida, Minoru Kuzuhara, Koji Kawamoto, Takuhiro Miyuki

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  15. Enhanced ionic conductivity and interfacial compatibility in BH4––based lithium argyrodite solid electrolytes via Cu+ doping

    Electrochimica Acta · 2025-08-18

    Hyerin Hong, Jaeseong Yoo, Hyunsuk Noh, Sanghyeok Bae, Jin Young Kim, Jae‐Hun Kim

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  16. Recent advances and remaining challenges of solid-state electrolytes for lithium batteries

    Progress in Materials Science · 2025-08-30

    Qing An Qiao, Yingxue Li, Chang Song, Mariyam Niyaz, Yang Zhang, Songqiang Zhu, Tengfei Zhang, Weiming Teng, Hongge Pan, Xuebin Yu

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  17. Atmospheric stability enhancement of borohydride-substituted sulfide solid electrolytes via porous silica incorporation

    Journal of Energy Storage · 2025-10-01

    Seunghyeok Jang, Hyunsuk Noh, Hyungrae Kim, Sanghyeok Bae, Jae‐Hun Kim

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  18. Ag-Substituted Borohydride Argyrodite Sulfide Electrolytes for Superior Interfacial Stability in All-Solid-State Batteries

    ACS Applied Materials & Interfaces · 2025-10-13

    Hyunsuk Noh, Yong‐Jin Jang, Sanghyeok Bae, Hyungeun Seo, Jae‐Hun Kim

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  19. Cluster-based materials: design and applications

    Chemical Society Reviews · 2026-01-01

    Hong Fang, Qiang Sun, Puru Jena

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  20. Electrode potential control of Li–Si alloys for safe and high-energy-density all-solid-state Li–S batteries

    Journal of Materials Chemistry A · 2026-01-01

    Hiroshi Nagata, Kunimitsu Kataoka

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  21. Phase−stabilized hydrosulfide argyrodite solid electrolytes with enhanced ionic conductivity and electrochemical stability for lithium metal all−solid−state batteries

    SSRN Electronic Journal · 2026-01-01

    Taeseung Kim, Sangho Lee, Huijeong Oh, Seunghee Joo, Taehyun Kim, Taegyoung Lee, SeoungJae Kang, Ye-Eun Park, Sangryun Kim

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  22. NMR study of electrolytes for Li rechargeable batteries: from liquid to solid electrolytes

    Solid State Nuclear Magnetic Resonance · 2026-02-07

    Sojung Seo, Sukkyu Min, Sangdoo Ahn, Young Joo Lee

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  23. Mechanochemical-induced halide segregation for highly stable all-solid-state lithium batteries

    Energy storage materials · 2026-03-17

    Wanyue Cai, Ruizi Wang, Yuepeng Pang, Lanxun Li, Ziming Fang, Zeyi Wang, Xin Zhang, Wenping Sun, Mingxia Gao, Hongge Pan

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  24. Aliovalent indium incorporation in borohydride argyrodite for fast ionic transport and stable Li metal interphase

    Journal of Alloys and Compounds · 2026-03-30

    Nayeon Lee, Sanghyeok Bae, Hyunsuk Noh, Hyungrae Kim, Jae-Hun Kim, Jae‐Hun Kim

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  25. Electrochemically Induced Interphase by Complex Hydride Anions in Argyrodite Solid Electrolytes for Stable Lithium Metal All‐Solid‐State Batteries

    Advanced Science · 2026-05-09

    S P Lee, H. K. Park, Ye‐Eun Park, T.-W. Kim, Taegyoung Lee, Taeseung Kim, SeoungJae Kang, 채예림, Seunghee Joo, Jinkwang Hwang, KyungSu Kim, Kazuhiko Matsumoto, Woosuk Cho, Sangryun Kim

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  26. Enhancing Li + Ion Transport via Dynamic Coupling With Borohydride Reorientation in Li 6 PS 5 X Argyrodites

    Small · 2026-05-10

    Y. S. Shin, Ji‐Hoon Han, Ji Seon Kim, D J Kim, Sukkyu Min, Jung Woo Kang, Sangdoo Ahn, Sang Uck Lee, Young Whan Cho, Y N Lee

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  27. HCl‐Free Mechanochemical Synthesis of Lithium Niobium Oxychlorides

    Chemistry - Methods · 2026-08-01

    Ji‐Hoon Han, Y. S. Shin, Young Joo Lee, Sangdoo Ahn, Young‐Su Lee, Kyung‐Woo Yi, Young Whan Cho

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