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RESEARCH PAPER · Chemical Society Reviews · 2023

Comproportionation and disproportionation in nickel and copper complexes

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Comproportionation and disproportionation in nickel and copper complexesOriginalPossibility of Nickel(I) complex in Suzuki-Miyaura coupling using pincer-type 1,2,3-triazolylidene Nickel(II) complex1Photoredox/copper-catalyzed formal cyclopropanation of olefins8An Organocopper(III) Fluoride Triggering C−CF3 Bond Formation15An Organocopper(III) Fluoride Triggering C−CF3 Bond Formation6Rate Equations for Reversible Disproportionation Reactions and Fitting to Time-Course Data3The development of cage phosphine ‘DalPhos’ ligands to enable nickel-catalyzed cross-couplings of (hetero)aryl electrophiles25Light Activation and Photophysics of a Structurally Constrained Nickel(II)–Bipyridine Aryl Halide Complex19Advances in understanding comproportionation and disproportionation in nickel catalysis6Alkyl Cyclopropyl Ketones in Catalytic Formal [3 + 2] Cycloadditions: The Role of SmI 2 Catalyst Stabilization32Water and Air Stable Copper(I) Complexes of Tetracationic Catenane Ligands for Oxidative C−C Cross‐Coupling2Water and Air Stable Copper(I) Complexes of Tetracationic Catenane Ligands for Oxidative C−C Cross‐Coupling15Mechanistic Insights on the Challenging Trifluoromethylation of Ni(II)3Electrocatalytic Formal C(sp 2 )−H Alkylations via Nickel‐Catalyzed Cross‐Electrophile Coupling with Versatile Arylsulfonium Salts34Elektrokatalytische formale C(sp2)−H Alkylierung via Nickel‐katalysierter elektrophiler Kreuzkupplung mit vielseitigen Arylsulfoniumsalzen0Mechanisms of Photoredox Catalysis Featuring Nickel–Bipyridine Complexes80Dynamic stereomutation of vinylcyclopropanes with metalloradicals33Overcoming Electron Bias in Hydroarylation of Phenylpropiolic Acid Derivatives To Enable Highly Reversed Regio- and Stereoselectivity via Steric and Transient Post Addition Coordination9On the Existence and Relevance of Copper(III) Fluorides in Oxidative Trifluoromethylation3Late-Stage C( sp 2 )–C( sp 3 ) Diversification via Nickel Oxidative Addition Complexes12Aerobic Oxysulfonylation of Olefins Using N -Sulfonylaminophthalimides as Sulfonyl Radical Precursors8Bis(benzimidazolin-2-ylidenes): Exploring the Impact of Ligand Properties in the Nickel-Catalyzed Suzuki–Miyaura Coupling5Ni-catalysed remote C(sp3)–H functionalization using chain-walking strategies60Nickel-Catalyzed Photoredox Allenylation of Alkyl Halides7Revealing the complexation of 3-N,N-dimethylaminodithiocarbamoyl-1-propanesulfonic acid (DPS) with cuprous ion and its contribution to Cu electrodeposition5Synthesis of allenones via nickel-catalyzed reductive coupling of propargyl esters with acyl chlorides0A nickel metalloradical bearing a phenalenyl-based tridentate ligand3Formal 1,1-Hydrocyanation Reaction of Alkynyl Halides with Isocyanides Enabled by Dual Nickel/Base Catalysis Relay5Nickel-Catalyzed Asymmetric Homobenzylic Hydroamidation of Vinylarenes: A Strategy for Chiral β-(Hetero)arylethylamides0Bulk depolymerization of PMMA using difunctional pyromellitic or monofunctional phthalimidic ATRP initiators20Synthesis and characterization of alkali metal salts bearing a phenalenyl-based tridentate ligand2Cationic nickel(II) complexes bearing a phenalenyl-based tridentate ligand1Hydrometallurgical recycling of steel grinding swarf via oxidative leaching using ferric chloride1In Situ Stm Study of Ni-Modified Pt(111) Electrodes: Structural Evolution and Hydrogen Evolution Activity in Koh0Insight into copper coordination in O 2 reduction by water-soluble cytochrome c oxidase models5New reactivity of late 3d transition metal complexes in catalytic reactions of alkynes33Visible-light-driven copper( ii ) catalysis for 2,3-disubstituted quinazolinone synthesis via Ullmann N -arylation and C–H oxidative amidation3Copper-Catalyzed Annulation of α,β-Unsaturated Ketoximes with Dialkyl Acetylenedicarboxylates for the Synthesis of Highly Substituted Pyridines7Electrochemical Nickel-Catalyzed C(sp2)-H Functionalization of Tropones with Aldehydes6Intercepting Ketone α-Arylation Intermediates in the DalPhos/Ni-Catalyzed Synthesis of Decorated Benzofurans and NH-Indoles2Nickel-Catalyzed Asymmetric Homobenzylic Hydroamidation of Aryl Alkenes to Access Chiral β-Arylamides27Soft Copper Nanoimprinting via Solid-State Electrochemical Etching for Flexible Optoelectronics10Nickel catalyzed C-N coupling of haloarenes with B2N4 reagents10Selective Open-Shell Nickel Catalysis Driven by Redox-Transmetalation1Unraveling a Complex Mechanistic Picture of Photochemical Nickel-Catalyzed THF Arylation through Product Enantioselectivity Analysis0Cu-Catalyzed Coupling of Aryl Halides Utilizing Ammonia and Hydroxypicolinamide Ligands9Roadmap to the Synthesis of Nickel Bisoxazoline Aryl Halide Complexes2Rapid Methylation of Aryl Bromides Using Air‐Stable DABCO‐Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis0Rapid Methylation of Aryl Bromides Using Air‐Stable DABCO‐Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis9Ar–X Coupling Reactions of Cationic Aryl Copper(II) Complexes with Organic Substrates: What Role Do Radicals Play?0Advances in Copper and Nickel C─N and C─O Cross‐Couplings of (Hetero)Aryl Chlorides Enabled by Ancillary Ligand Development10Deposition of Tin Catalysts from Thiolated Precursor Organic Solutions for CO2 Reduction to Formate: A Potential‐Dependent Mechanism Study1Discovery of Ni(I) Complexes for CO2 Insertion Enabled by a Machine Learning-Computational-Selection Sequence12Nickel-Catalyzed Cross-Dehydrogenative Coupling of Aldehydes and Alkenes toward Skipped Enones15Unraveling the Dichotomy Exerted by Boron Reagents in Site-Selective Functionalization of C(sp2)– and C(sp3)–OMe Bonds1Cu(II)-Catalyzed Hydrofunctionalization of Unactivated Alkynes via π-Lewis Acid Activation11Surveying the Homogeneity of a Molecular Electrocatalyst Embedded in a Metal‐Organic Framework Using Operando Characterization0Pseudohalide‐Guided Redox Control Enables Electrochemical Auto‐Tandem Nickel Catalysis for Butafulvene Synthesis.3Pseudohalide‐Guided Redox Control Enables Electrochemical Auto‐Tandem Nickel Catalysis for Butafulvene Synthesis.0Atomic-Resolution Visualization of Ni Transformation on Pt(111) during Hydrogen Evolution in Alkaline Media3Dinuclear Ni enabled reductive diarylation of dienes: Intramolecular comproportionation as the key mechanistic driver1Metallic electrocatalyzed C–N bond formation: new catalytic modes and technologies2Advances in NiI/NiIII-Catalyzed C(sp2)–Heteroatom Cross-Couplings15An Integrated 12 C/ 13 C Exchange Platform for Accessing Isotopically-Labeled Ketones via Dual Catalytic C–C Bond-Functionalization10Decoding the Nested, Multicycle Mechanism of Ni-Catalyzed Redox-Neutral Cross-Coupling through Temperature Scanning Reaction Calorimetry15Interfacial electronic modulation in electrochemically reconstructed CoOOHCuO@CeO 2 for efficient electrooxidation of 5-hydroxymethylfurfural4Origin of Red Emission in Protein-Stabilized Copper Nanoparticles: Evidence for Cu I -Metallothionein-Like Cluster Formation0Integrating {Cu x I y } Modules into a Series of Alkaline Earth Metal Based Metal–Organic Frameworks for NO 2 Chemiresistive Sensing1Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling6Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling1Nickel-Catalyzed α-Arylation and Alkenylation of α-Trifluoromethyl Amines via 1,2-HAT Assisted by DMSO5Fluorocarbon-Free Hierarchical Slippery Copper Surfaces via Solid-State Electrochemical Etching1NiH‐Catalyzed Enantioconvergent α ‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation2NiH‐Catalyzed Enantioconvergent α ‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation0Electronickel‐Catalyzed Stereoselective Synthesis of Butafulvenes2Transition-Metal Hydride Catalysis Meets Nitrenoid Transfer: Design Principles for Precision C–N Bond Formation9Electronickel‐Catalyzed Stereoselective Synthesis of Butafulvenes0Controlling the Redox Speciation of N,C,N–Bi Complexes Using the Anion Coordination Index0Investigation of electrocatalytic semi-hydrogenation catalyzed by nickel complexes0Metal-Catalyzed Reductive Coupling of Aryl Halides beyond Premetalated Reagents or Metallic Reductants: Biaryl Formation3Oxygen‐Radical Capture Enabled Nickel‐Catalyzed Carbon(sp 2 )‐Heteroatom Coupling of Two Nucleophiles0Oxygen‐Radical Capture Enabled Nickel‐Catalyzed Carbon(sp 2 )‐Heteroatom Coupling of Two Nucleophiles0Well‐Defined Nickel Precatalysts: Form, Function, and Application0Confining copper (I) iodide (CuI) modules in metal organic frameworks (MOFs): Structures and applications of CuI-MOFs1Visible‐Light‐Initiated, Nickel‐Catalyzed Aminocarbonylation of Alkynyl Iodides to 2‐Ynamides0Elucidating the Mechanism of Electrocatalytic Halide Activation by Low-Coordinate Manganese and Iron Complexes through Voltammetric Analysis and Density Functional Theory0Electrochemical Reductive β‐Arylation and Alkenylation of α‐Branched Acroleins by Primary Amine/Nickel Dual Catalysis0

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  5. Rate Equations for Reversible Disproportionation Reactions and Fitting to Time-Course Data

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  6. The development of cage phosphine ‘DalPhos’ ligands to enable nickel-catalyzed cross-couplings of (hetero)aryl electrophiles

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  7. Light Activation and Photophysics of a Structurally Constrained Nickel(II)–Bipyridine Aryl Halide Complex

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  16. Dynamic stereomutation of vinylcyclopropanes with metalloradicals

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  17. Overcoming Electron Bias in Hydroarylation of Phenylpropiolic Acid Derivatives To Enable Highly Reversed Regio- and Stereoselectivity via Steric and Transient Post Addition Coordination

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  18. On the Existence and Relevance of Copper(III) Fluorides in Oxidative Trifluoromethylation

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  19. Late-Stage C( sp 2 )–C( sp 3 ) Diversification via Nickel Oxidative Addition Complexes

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