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RESEARCH PAPER · Coordination Chemistry Reviews · 2023

Photophysics of corroles and closely related systems for emergent solar energy, medicinal, and materials science applications

Xuan Zhan, Donghyeon Kim, Zakir Ullah, Woohyun Lee, Zeev Gross, David George Churchill

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Photophysics of corroles and closely related systems for emergent solar energy, medicinal, and materials science applicationsOriginalHighly Efficient β‐Functionalized Oxidomolybdenum(V) Corroles for Catalytic Oxidative Bromination of Phenols at Room Temperature11Turning on Singlet Oxygen Generation by Outer‐Sphere Microenvironment Modulation in Porphyrinic Covalent Organic Frameworks for Photocatalytic Oxidation200Turning on Singlet Oxygen Generation by Outer‐Sphere Microenvironment Modulation in Porphyrinic Covalent Organic Frameworks for Photocatalytic Oxidation16Exploring Nitric Acid's Role in Photo-Catalytic Conversion: Synergy with Phosphorus Corrole for Enhanced Mesitylene Transformation0Recent advances in the functionalization of formyl and acroleyl appended corroles3Structurally influenced optical nonlinearities and ultrafast dynamics in β-acroleyl- and β-dicyanobutadienyl-appended cobalt corroles6Cobalt corroles: Synthesis and applications27Synthesis and Regioselective Functionalization of Tetrafluorobenzo-[α]-Fused BOPYPY Dyes8Exploring nitric acid's role in photo-catalytic conversion: Synergy with phosphorus corrole for enhanced mesitylene transformation1Inverse Photoemission Spectroscopy of Coinage Metal Corroles: Comparison with Solution-Phase Electrochemistry2A photoelectrochemical immunosensor based on cobalt corrole sensitized carbon nitride for human norovirus detection5Corrole–chelated phosphorus complex: enabling dual C–H chlorination and H₂O₂ generation10Fluorenyl-corroles: Characterization, photophysical, photobiological, and DNA/BSA-binding properties of novel examples11Photophysics of Hydrophobic Corroles in the Aqueous Micellar Media and in the Presence of Graphene Oxide and Bioanalytes1Engineering Corrole and Porphyrin-Based Multivariate Metal–Organic Frameworks for Si–H Bond Insertion1A Numerical Simulation Study of the Impact of Kesterites Hole Transport Materials in Quantum Dot-Sensitized Solar Cells Using SCAPS-1D16A corrole-based derivative as an ultra-fast response and high selective fluorescent probe for Mg2+ and its application4Tuning Optical Properties of Organic Thin Films through Intermolecular Interactions – Fundamentals, Advances and Strategies23Numerical Simulation and Hole Transport Layers Optimization of a Lead Sulfide-Based Solar Cell with a Power Conversion Efficiency of Above 22%4A Universal Approach to Anchoring Chromophores onto Magnetic Scaffold for Achieving Easily Recyclable Heterogeneous Photocatalytic Systems7Comparison of the adsorption behavior of melphalan anti-cancer drug on MgS nano-cage: A DFT study3Exploring the Influence of Chalcogens on Metalloporphyrins: A DFT Study8Preparation and properties of stearic acid–palmitic acid-based shaped composite phase change materials13Electrocatalytic CO2 to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex15Engineering protonation-responsive NIR absorption in corrorin derivatives through meso-Substitution3Bioinspired copper corrole and porphyrin catalysts for oxidation and hydrocarboxylation of alkanes2Impact of Substitution Position on the Excited‐State Dynamics and Nonlinear Optical Properties of Tetraphenylethylene‐Corroles1Luminescent pyrrolyl-pyrimidine hybrids: Synthesis, structural characterization and photophysical evaluation0Machine Learning Accelerates Discovery of High-Performance Corrole Photosensitizers for Optical Imaging Diagnosis and Photodynamic Therapeutics of Nasopharyngeal Carcinoma47Glycofullerene–corrole hybrids: a new class of multifunctional nanomaterials with potential in targeted photodynamic therapy0Modulating photophysics and photochemistry of Sn( iv ) corroles through axial ligands0Synergistic enhancement of photocatalytic sulfide oxidation in porphyrin-based binary systems0Systematic evaluation of the photophysical properties, photosensitizing activity, and photostability of water-soluble cationic corrole and porphyrin0Supramolecularly Stabilized Corrole Complex Anchored onto Recyclable Magnetic Beads for Robust Photochemical Elimination of Multiple Antibiotics0Photocycloaddition in transition-metal complexes and their coordination frameworks: Design, reactivity, and structural insights1π-Extended Nonplanar NIR Absorbing Porphyrins: Synthesis, Spectral, Electrochemical, and DFT Studies and Their Excellent Nonlinear Optical Properties3Synthesis of phosphorus(V) complexes of dibenzo-5,10-diazacorroles via the meso -N extrusion of dibenzotriazaporphyrins0Synthesis, photo-luminescence, theoretical, electrochemical and preliminary optical sensor assays of novel corroles with oxazolyl units0Functionalization of β-Alkylcorrole Using Ag(I) Salts0

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  1. Highly Efficient β‐Functionalized Oxidomolybdenum(V) Corroles for Catalytic Oxidative Bromination of Phenols at Room Temperature

    European Journal of Inorganic Chemistry · 2023-09-19

    Inderpal Yadav, Ved Prakash, Ram Ratan Kaswan, Mannar Ram Maurya, Muniappan Sankar

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  2. Turning on Singlet Oxygen Generation by Outer‐Sphere Microenvironment Modulation in Porphyrinic Covalent Organic Frameworks for Photocatalytic Oxidation

    Angewandte Chemie International Edition · 2023-11-28

    Suleman Suleman, Yi Zhang, Yunyang Qian, Jinwei Zhang, Zhongyuan Lin, Önder Metin, Zheng Meng, Zheng Meng, Hai‐Long Jiang

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  3. Turning on Singlet Oxygen Generation by Outer‐Sphere Microenvironment Modulation in Porphyrinic Covalent Organic Frameworks for Photocatalytic Oxidation

    Angewandte Chemie · 2023-11-29

    Suleman Suleman, Yi Zhang, Yunyang Qian, Jinwei Zhang, Zhongyuan Lin, Önder Metin, Zheng Meng, Hai‐Long Jiang

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  4. Exploring Nitric Acid's Role in Photo-Catalytic Conversion: Synergy with Phosphorus Corrole for Enhanced Mesitylene Transformation

    SSRN Electronic Journal · 2024-01-01

    Zakir Ullah, Xuan Zhan

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  5. Recent advances in the functionalization of formyl and acroleyl appended corroles

    Chemical Communications · 2024-01-01

    Inderpal Yadav, Divyansh Dhiman, Muniappan Sankar

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  6. Structurally influenced optical nonlinearities and ultrafast dynamics in β-acroleyl- and β-dicyanobutadienyl-appended cobalt corroles

    Physical Chemistry Chemical Physics · 2024-01-01

    Inderpal Yadav, Jitendra Nath Acharyya, Gaddam Vijaya Prakash, Muniappan Sankar

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  7. Cobalt corroles: Synthesis and applications

    Coordination Chemistry Reviews · 2024-04-18

    Jyoti, Jongkeol An, Donghyeon Kim, David George Churchill, Anil Kumar

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  8. Synthesis and Regioselective Functionalization of Tetrafluorobenzo-[α]-Fused BOPYPY Dyes

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    Sebastian O. Oloo, Guanyu Zhang, Petia Bobadova‐Parvanova, Seleen Al Horani, Masa Al Horani, Frank Rolf Fronczek, Kevin M. Smith, M. Graça H. Vicente

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  9. Exploring nitric acid's role in photo-catalytic conversion: Synergy with phosphorus corrole for enhanced mesitylene transformation

    Molecular Catalysis · 2024-05-22

    Xuan Zhan, Zakir Ullah

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  10. Inverse Photoemission Spectroscopy of Coinage Metal Corroles: Comparison with Solution-Phase Electrochemistry

    ACS Organic & Inorganic Au · 2024-06-19

    L. Giovanelli, Y. Ksari, Hela Mrezguia, Eric Salomon, Marco Minissale, Abraham B. Alemayehu, Abhik Ghosh

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  11. A photoelectrochemical immunosensor based on cobalt corrole sensitized carbon nitride for human norovirus detection

    Sensors and Actuators B Chemical · 2024-07-26

    Junchao Qian, Yun Chen, Guifen Lu, Li Xu, Henan Li

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  12. Corrole–chelated phosphorus complex: enabling dual C–H chlorination and H₂O₂ generation

    Journal of Molecular Liquids · 2024-09-06

    Xuan Zhan, Donghyeon Kim, Zakir Ullah, David George Churchill

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  13. Fluorenyl-corroles: Characterization, photophysical, photobiological, and DNA/BSA-binding properties of novel examples

    Journal of Photochemistry and Photobiology A Chemistry · 2024-10-21

    Bruna Matiuzzi Rodrigues, Carlos C. Diniz, Mateus Henrique Köhler, Otávio Augusto Chaves, Bernardo Almeida Iglesias

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  14. Photophysics of Hydrophobic Corroles in the Aqueous Micellar Media and in the Presence of Graphene Oxide and Bioanalytes

    ChemPhysChem · 2024-11-26

    Antara Garai, Sanyukta Bhattacharjee, Debabrata Seth

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  15. Engineering Corrole and Porphyrin-Based Multivariate Metal–Organic Frameworks for Si–H Bond Insertion

    Inorganic Chemistry · 2024-12-06

    Huan Lin, Qijie Mo, Yufei Wang, Chunying Chen, Li Zhang

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  16. A Numerical Simulation Study of the Impact of Kesterites Hole Transport Materials in Quantum Dot-Sensitized Solar Cells Using SCAPS-1D

    Nanomaterials · 2024-12-15

    Sindisiwe Jakalase, Azile Nqombolo, Edson L. Meyer, Mojeed Adedoyin Agoro, Nicholas Rono

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  17. A corrole-based derivative as an ultra-fast response and high selective fluorescent probe for Mg2+ and its application

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2025-01-13

    Guifen Lu, Luyao Duan, Ting Dong, Sihan Ding, Yaohui Wang, Yiming Zhang

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  18. Tuning Optical Properties of Organic Thin Films through Intermolecular Interactions – Fundamentals, Advances and Strategies

    Chemistry - A European Journal · 2025-01-20

    Sarah Jasmin Finkelmeyer, Martin Presselt

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  19. Numerical Simulation and Hole Transport Layers Optimization of a Lead Sulfide-Based Solar Cell with a Power Conversion Efficiency of Above 22%

    Coatings · 2025-02-20

    Edson L. Meyer, Inam Vulindlela, Athandwe M. Paca, Mojeed Adedoyin Agoro, Nicholas Rono

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  20. A Universal Approach to Anchoring Chromophores onto Magnetic Scaffold for Achieving Easily Recyclable Heterogeneous Photocatalytic Systems

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    Xuan Zhan, Yikun Wang, Chenyang Sun, Yuchen Fang, Lihua Huang, Zakir Ullah, Qiang Chen, Xuejing Wang, Zheng Xing, Gangfeng Ouyang

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  21. Comparison of the adsorption behavior of melphalan anti-cancer drug on MgS nano-cage: A DFT study

    Results in Chemistry · 2025-04-17

    Shahnaz Azari gharelar, Shiva Masoudi, Nasrin Masnabadi, Mohammad Hadi Ghasemi

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  22. Exploring the Influence of Chalcogens on Metalloporphyrins: A DFT Study

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    Beenish Bashir, Andre Z. Clayborne

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  23. Preparation and properties of stearic acid–palmitic acid-based shaped composite phase change materials

    Journal of Energy Storage · 2025-05-28

    Mingzhi Zhao, Yingjie Liu, Chun Chang, Daorina Bao, Zheng Han, B. S. Rasakhodzhaev, Akhadou Jobir

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  24. Electrocatalytic CO2 to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex

    ACS Catalysis · 2025-06-12

    Afridi Zamader, Ajeet Singh, Bishnubasu Giri, Marcello Caruso, William Ryan Osterloh, Nicolas Desbois, Claude P. Gros, Marc Robert

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  25. Engineering protonation-responsive NIR absorption in corrorin derivatives through meso-Substitution

    Dyes and Pigments · 2025-08-05

    Yue Wang, Jiatong Yin, Longxiang Wang, Linxue Sang, Jianming Pan, Zhaoli Xue, Ru Feng

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  26. Bioinspired copper corrole and porphyrin catalysts for oxidation and hydrocarboxylation of alkanes

    Molecular Catalysis · 2025-09-17

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  27. Impact of Substitution Position on the Excited‐State Dynamics and Nonlinear Optical Properties of Tetraphenylethylene‐Corroles

    Chemistry - An Asian Journal · 2025-09-29

    Rahul Murali, Renikindi Sravani, Swathi Nenavath, Seelam Prasanthkumar, S. Venugopal Rao, Lingamallu Giribabu, Sai Santosh Kumar Raavi

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  28. Luminescent pyrrolyl-pyrimidine hybrids: Synthesis, structural characterization and photophysical evaluation

    Journal of Molecular Structure · 2025-10-24

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  29. Machine Learning Accelerates Discovery of High-Performance Corrole Photosensitizers for Optical Imaging Diagnosis and Photodynamic Therapeutics of Nasopharyngeal Carcinoma

    The Journal of Physical Chemistry Letters · 2025-11-30

    Kaihang Huang, Yubiao Yang, Huahua Huang, Yi Ping Tang, Wen Han, Jie Huang, Yiqian An, Jinchang Yin

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  30. Glycofullerene–corrole hybrids: a new class of multifunctional nanomaterials with potential in targeted photodynamic therapy

    Chemical Science · 2025-12-08

    Jennifer Patino-Alonso, Carla I. M. Santos, Adriana F. Cruz, Sandra Pinto, Justo Cabrera-González, M. Amparo F. Faustino, M. Graça P. M. S. Neves, Ermelinda M. S. Maçôas, Nazario Martı́n, Beatriz M. Illescas

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  31. Modulating photophysics and photochemistry of Sn( iv ) corroles through axial ligands

    Inorganic Chemistry Frontiers · 2026-01-01

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  32. Synergistic enhancement of photocatalytic sulfide oxidation in porphyrin-based binary systems

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    Han-Kang Zhong, Jing‐Ru Feng, Zhen-Hong Huang, Guo-Sheng Wang, Tian-Tian Wen, Yu-Xin Huo, Shuo-Yun Zheng, Xiaohui Liu, Can Xue, Xiantai Zhou

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  33. Systematic evaluation of the photophysical properties, photosensitizing activity, and photostability of water-soluble cationic corrole and porphyrin

    SSRN Electronic Journal · 2026-01-01

    Kazutaka Hirakawa, Rena Kaneko, hiroto Takeshita, Takahisa Ikeue, Atsuya Momotake, Shigetoshi Okazaki

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  34. Supramolecularly Stabilized Corrole Complex Anchored onto Recyclable Magnetic Beads for Robust Photochemical Elimination of Multiple Antibiotics

    ACS Nano · 2026-05-05

    Xuan Zhan, Chenyang Sun, Yikun Wang, Chen Xu, Lc Huang, Mai Gao, Xiushen Ye, X B Zheng, Gangfeng Ouyang

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  35. Photocycloaddition in transition-metal complexes and their coordination frameworks: Design, reactivity, and structural insights

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  36. π-Extended Nonplanar NIR Absorbing Porphyrins: Synthesis, Spectral, Electrochemical, and DFT Studies and Their Excellent Nonlinear Optical Properties

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  37. Synthesis of phosphorus(V) complexes of dibenzo-5,10-diazacorroles via the meso -N extrusion of dibenzotriazaporphyrins

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  38. Synthesis, photo-luminescence, theoretical, electrochemical and preliminary optical sensor assays of novel corroles with oxazolyl units

    Journal of Photochemistry and Photobiology A Chemistry · 2026-06-25

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  39. Functionalization of β-Alkylcorrole Using Ag(I) Salts

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