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RESEARCH PAPER · Inorganic Chemistry · 2023

Anhydrous Aluminum Carbonates and Isostructural Compounds

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Anhydrous Aluminum Carbonates and Isostructural CompoundsOriginalTwisted [C 2 O 5 ] 2− -groups in Ba[C 2 O 5 ] pyrocarbonate17High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ]19Synthesis and crystal structure of acentric anhydrous beryllium carbonate Be(CO 3 )12Thermodynamic stability of Li-pyrocarbonate at atmospheric and high pressures106-Fold-Coordinated Beryllium in Calcite-Type Be[CO3]13Ca3[C2O5]2[CO3] is a pyrocarbonate which can be formed at p, T-conditions prevalent in the Earth’s transition zone6High-Pressure Synthesis of an Iron Carbonate, Fe2[CO3]310Synthesis and Characterization of Lithium Pyrocarbonate (Li 2 [C 2 O 5 ]) and Lithium Hydrogen Pyrocarbonate (Li[HC 2 O 5 ])1Synthesis and Characterization of Lithium Pyrocarbonate (Li 2 [C 2 O 5 ]) and Lithium Hydrogen Pyrocarbonate (Li[HC 2 O 5 ])14Single crystal diffraction study of Ba[H 4 C 4 O 10 ][H 3 C 4 O 10 ][H 2 CO 3 ][HCO 3 ], a hydrous mixed sp 2 /sp 3 -carbonate3Bioremediation of multiple heavy metals through biostimulation of microbial-induced calcite precipitation at varying calcium-to-urea concentrations26Cr3+-Containing Carbonates and Cr2O3-Pbcn at Extreme Conditions8K2C2O5─The First Finding of Pyrocarbonate Stable at Ambient Pressure2Crystal Structure of Carbonic Acid (H2CO3) at Elevated Pressures from Single‐Crystal Diffraction4B[μ-H(CO3)2]: An Acentric Boron Hydrogencarbonate with [μ-H(CO3)2]3– Complex Anions4Synthesis and Crystal Structure of Anhydrous Di-iodyl Carbonate (IO 2 ) 2 [CO 3 ], Hosting I 5+ -Cations10Synthesis and Characterization of Ti 4+ Containing Carbonates Ti[CO 4 ] and Ti 2 O 3 [CO 3 ]2High-pressure crystal structure and phase transitions in B 2 O 31High-pressure synthesis of U2[CO3]3 and U[CO3]2 as potential host phases for uranium in the Earth’s mantle4Inorganic Tricarbonate: High-Pressure Synthesis and Structure of K 2 C 3 O 70Silicon carbonate, Si[CO 3 ] 2 , is a potential carbon host in the deep Earth3Synthesis and Crystal Structure of Sb 2 O 2 [CO 3 ] with Stereochemically Active Lone Electron Pairs at Elevated Pressures1Isostructural Tin and Germanium Carbonates (Sn[CO 3 ] 2 and Ge[CO 3 ] 2 )0Stereochemically Active Lone Electron Pairs in the Chalcogen Oxide-Carbonates Te[CO3]O and Te4O7[CO3] at Elevated Pressures0

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  1. Twisted [C 2 O 5 ] 2− -groups in Ba[C 2 O 5 ] pyrocarbonate

    Chemical Communications · 2023-01-01

    Dominik Spahr, Lkhamsuren Bayarjargal, Eiken Haussühl, Rita Luchitskaia, Alexandra Friedrich, Victor Milman, Timofey Fedotenko, Björn Winkler

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  2. High-pressure synthesis of acentric sodium pyrocarbonate, Na 2 [C 2 O 5 ]

    Dalton Transactions · 2023-12-06

    Dominik Spahr, Lkhamsuren Bayarjargal, Maxim Bykov, Lukas Brüning, Tim H. Reuter, Victor Milman, Hanns‐Peter Liermann, Björn Winkler

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  3. Synthesis and crystal structure of acentric anhydrous beryllium carbonate Be(CO 3 )

    Chemical Communications · 2024-01-01

    Dominik Spahr, Lkhamsuren Bayarjargal, Elena A. Bykova, Maxim Bykov, Tim H. Reuter, Lukas Brüning, Pascal L. Jurzick, Lena Wedek, Victor Milman, Björn Wehinger, Björn Winkler

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  4. Thermodynamic stability of Li-pyrocarbonate at atmospheric and high pressures

    Inorganic Chemistry Communications · 2024-07-03

    Dinara N. Sagatova, Nursultan E. Sagatov, Pavel N. Gavryushkin

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  5. 6-Fold-Coordinated Beryllium in Calcite-Type Be[CO3]

    Inorganic Chemistry · 2024-10-09

    Dominik Spahr, Lkhamsuren Bayarjargal, Е. Быкова, Maxim Bykov, Lukas Brüning, Valentin N. Kovalev, Victor Milman, Jonathan Paul Wright, Björn Winkler

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  6. Ca3[C2O5]2[CO3] is a pyrocarbonate which can be formed at p, T-conditions prevalent in the Earth’s transition zone

    Communications Chemistry · 2024-10-21

    Dominik Spahr, Lkhamsuren Bayarjargal, Maxim Bykov, Lukas Brüning, Pascal L. Jurzick, Yu Wang, Victor Milman, Keith Refson, Mohamed Mézouar, Björn Winkler

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  7. High-Pressure Synthesis of an Iron Carbonate, Fe2[CO3]3

    Inorganic Chemistry · 2024-10-28

    Lkhamsuren Bayarjargal, Dominik Spahr, Elena A. Bykova, Yu Wang, Nico Giordano, Victor Milman, B. Winkler

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  8. Synthesis and Characterization of Lithium Pyrocarbonate (Li 2 [C 2 O 5 ]) and Lithium Hydrogen Pyrocarbonate (Li[HC 2 O 5 ])

    Angewandte Chemie · 2024-11-06

    Dominik Spahr, Lkhamsuren Bayarjargal, Maxim Bykov, Lukas Brüning, Pascal L. Jurzick, Victor Milman, Nico Giordano, Mohamed Mézouar, B. Winkler

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  9. Synthesis and Characterization of Lithium Pyrocarbonate (Li 2 [C 2 O 5 ]) and Lithium Hydrogen Pyrocarbonate (Li[HC 2 O 5 ])

    Angewandte Chemie International Edition · 2024-11-06

    Dominik Spahr, Lkhamsuren Bayarjargal, Maxim Bykov, Lukas Brüning, Pascal L. Jurzick, Victor Milman, Nico Giordano, Mohamed Mézouar, B. Winkler

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  10. Single crystal diffraction study of Ba[H 4 C 4 O 10 ][H 3 C 4 O 10 ][H 2 CO 3 ][HCO 3 ], a hydrous mixed sp 2 /sp 3 -carbonate

    Chemical Communications · 2024-12-03

    Dominik Spahr, Elena A. Bykova, Lkhamsuren Bayarjargal, Victor Milman, Hanns‐Peter Liermann, B. Winkler

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  11. Bioremediation of multiple heavy metals through biostimulation of microbial-induced calcite precipitation at varying calcium-to-urea concentrations

    Journal of Hazardous Materials · 2025-02-21

    Carla Comadran Casas, Cise Unluer, Adrian Michael Bass, John MacDonald, Elmira Khaksar Najafi, Liene Spruženiece, Caroline Gauchotte‐Lindsay

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  12. Cr3+-Containing Carbonates and Cr2O3-Pbcn at Extreme Conditions

    Inorganic Chemistry · 2025-03-04

    Yu Wang, Lkhamsuren Bayarjargal, Maxim Bykov, Е. Быкова, Dominik Spahr, Konstantin V. Glazyrin, Victor Milman, B. Winkler

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  13. K2C2O5─The First Finding of Pyrocarbonate Stable at Ambient Pressure

    Crystal Growth & Design · 2025-05-23

    Maksim V. Banaev, Dinara N. Sagatova, Nursultan E. Sagatov, Pavel N. Gavryushkin

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  14. Crystal Structure of Carbonic Acid (H2CO3) at Elevated Pressures from Single‐Crystal Diffraction

    Chemistry - A European Journal · 2025-06-25

    Dominik Spahr, Elena A. Bykova, Lkhamsuren Bayarjargal, Maxim Bykov, Lukas Brüning, Valentin N. Kovalev, Victor Milman, Nico Giordano, Hanns‐Peter Liermann, Björn Winkler

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  15. B[μ-H(CO3)2]: An Acentric Boron Hydrogencarbonate with [μ-H(CO3)2]3– Complex Anions

    Inorganic Chemistry · 2025-09-16

    Dominik Spahr, Tim H. Reuter, Elena A. Bykova, Lkhamsuren Bayarjargal, Lukas Brüning, Valentin N. Kovalev, Maxim Bykov, Lena Wedek, Victor Milman, Jonathan Paul Wright, B. Winkler

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  16. Synthesis and Crystal Structure of Anhydrous Di-iodyl Carbonate (IO 2 ) 2 [CO 3 ], Hosting I 5+ -Cations

    JACS Au · 2025-10-14

    Dominik Spahr, Lkhamsuren Bayarjargal, Lukas Brüning, Valentin N. Kovalev, Elena A. Bykova, Maxim Bykov, Victor Milman, Mohamed Mézouar, B. Winkler

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  17. Synthesis and Characterization of Ti 4+ Containing Carbonates Ti[CO 4 ] and Ti 2 O 3 [CO 3 ]

    Inorganic Chemistry · 2025-10-27

    Lkhamsuren Bayarjargal, Dominik Spahr, Victor Milman, Nico Giordano, Konstantin V. Glazyrin, B. Winkler

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  18. High-pressure crystal structure and phase transitions in B 2 O 3

    Chemical Communications · 2026-01-01

    Dominik Spahr, Sean S. Sebastian, Lukas Brüning, Pascal L. Jurzick, Ninel Sharapova, Lkhamsuren Bayarjargal, Elena A. Bykova, Maxim Bykov, Victor Milman, Björn Winkler

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  19. High-pressure synthesis of U2[CO3]3 and U[CO3]2 as potential host phases for uranium in the Earth’s mantle

    Communications Chemistry · 2026-01-30

    Dominik Spahr, Lkhamsuren Bayarjargal, Elena A. Bykova, Maxim Bykov, Gabriel L. Murphy, Philip Kegler, Victor Milman, Nico Giordano, Björn Winkler

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  20. Inorganic Tricarbonate: High-Pressure Synthesis and Structure of K 2 C 3 O 7

    Journal of the American Chemical Society · 2026-03-24

    Andrey Aslandukov, Alena A. Aslandukova, Fariia Iasmin Akbar, Yuqing Yin, Ridvan Akilli, Gastón Garbarino, Dominik Spahr, B. Winkler, Maxim Bykov, Natalia Dubrovinskaia, Leonid Dubrovinsky

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  21. Silicon carbonate, Si[CO 3 ] 2 , is a potential carbon host in the deep Earth

    Science Advances · 2026-05-29

    Dominik Spahr, Lkhamsuren Bayarjargal, Valentin Kovalev, Ninel Sharapova, Lukas Brüning, Pascal L. Jurzick, Sean S. Sebastian, Maxim Bykov, Victor Milman, Konstantin V. Glazyrin, Elena A. Bykova, Björn Winkler

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  22. Synthesis and Crystal Structure of Sb 2 O 2 [CO 3 ] with Stereochemically Active Lone Electron Pairs at Elevated Pressures

    Zeitschrift für anorganische und allgemeine Chemie · 2026-06-22

    Dominik Spahr, Lkhamsuren Bayarjargal, Lukas Brüning, Elena A. Bykova, Maxim Bykov, Victor Milman, Nico Giordano, Björn Winkler

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  23. Isostructural Tin and Germanium Carbonates (Sn[CO 3 ] 2 and Ge[CO 3 ] 2 )

    Crystal Growth & Design · 2026-07-01

    Lkhamsuren Bayarjargal, Dominik Spahr, Elena A. Bykova, Valentin Kovalev, Victor Milman, Nico Giordano, B. Winkler

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  24. Stereochemically Active Lone Electron Pairs in the Chalcogen Oxide-Carbonates Te[CO3]O and Te4O7[CO3] at Elevated Pressures

    Inorganic Chemistry · 2026-07-17

    Dominik Spahr, Lkhamsuren Bayarjargal, Ninel Sharapova, Valentin Kovalev, Andrey Aslandukov, Fariia Iasmin Akbar, Elena A. Bykova, Maxim Bykov, Victor Milman, Nico Giordano, B. Winkler

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