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RESEARCH PAPER · Nature Communications · 2023

Heterogenous electromediated depolymerization of highly crystalline polyoxymethylene

Yuting Zhou, Joaquín Rodríguez‐López, Jeffrey S. Moore

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Heterogenous electromediated depolymerization of highly crystalline polyoxymethyleneOriginalFormation of highly oriented crystalline structure for polyoxymethylene fiber enables superior intrinsic thermal conductivity14Electrochemical recycling of polymeric materials56Selective Recovery of Para-Xylene from Polyethylene Terephthalate Plastic26Selective Electrochemical Modification and Degradation of Polymers1Selective Electrochemical Modification and Degradation of Polymers34Chemically recyclable polythioesters prepared by ring-opening polymerization of dithiolactone and monothiodilactone monomers6Electrocatalysis‐driven sustainable plastic waste upcycling33Syngas production through CO2-mediated pyrolysis of polyoxymethylene9Polyoxymethylene Upcycling into Methanol and Methyl Groups Catalyzed by a Manganese Pincer Complex18Electrochemically Generated Carbocations in Organic Synthesis27Electrochemically Generated Carbocations in Organic Synthesis3Electrocatalytic upcycling of plastic waste: Progress, challenges, and future53One-Step Upcycling the Engineering Plastic of Polyoxymethylene toward a Flowing Telechelic Polyester: From Poly(A) to Poly(A-alt-B)4Electrochemical Postpolymerization Modification and Deconstruction of Macromolecules23Recent advances in chemical recycling of polyoxymethylene waste6Valorization of polyoxymethylene (POM) waste as a C 1 synthon for industrially relevant dialkoxymethanes and cyclic aminals11Chemical Recycling: Monomers and Intermediates from Depolymerization Processes for the Chemical and Plastics Industry1Exceptional class of semicrystalline and amorphous nanocomposite polymers for specific needs0Heterogeneous tandem upcycling of polyoxymethylene into methanol and methylene derivatives2Co-upcycling of polyethylene terephthalate and polyoxymethylene into valuable chemicals13Photo‐Driven Direct Construction of Imidazolidines from Anilines and Paraformaldehyde and Its Application in Polyoxymethylene Plastics Usage2Harnessing Non-Thermal External Stimuli for Polymer Recycling23Upcycling Polyoxymethylene via H2O2‐Mediated Selective Oxidation6A catalytic approach to the valorization of polyesters and biogenic waste for the production of amines9Electrochemical Upgrading Plastic to Organosulfurs Through Fe‐N 3 Single Atom Catalyst Under Ambient Conditions7Electrochemical Upgrading Plastic to Organosulfurs Through Fe‐N 3 Single Atom Catalyst Under Ambient Conditions26Dissipation of the carbon resource embedded in end-of-life plastics: exploring the limits of chemical recycling to monomer1Catalytic Upcycling of PET: From Waste to Chemicals and Degradable Polymers48Dual C–H functionalization of polyolefins for covalent adaptable network formation via cooperative electrolysis11Electrochemical C–H Phosphonylation of Dissolved Conjugated Polymers via Direct Electron Transfer at the Electrode7Electro-organic hydrodehalgenation of organic waste and their mechanistic understandings1Photothermal conversion of polyoxymethylene into syngas over supported alloyed nanocrystals2Electrochemical upcycling of polyolefins into adaptable networks0Electrochemical depolymerization of polycarbonates under catalyst-free conditions0Upcycling waste polyoxymethylene to value-added chemicals using reusable polymeric acid catalysts at ppm levels2Electrochemically Initiated Depolymerization of Poly(Methyl Methacrylate)14Recovery technology for waste plastics based on electrocatalytic reforming: From mechanism understanding to catalyst design2Recent polymer modification strategies for reducing plastic waste and enhancing recyclability1Proton‐Exchanged Montmorillonite With Interlayer Accessibility as a Solid Acid Catalyst for the Upcycling of Polyoxymethylene0Selective depolymerization of polyolefin copolymer via high-entropy alloy catalyzed pyrolysis in a double-layered ultrafast heating reactor0Waste plastic recycling and upgrading via electro- and photocatalytic C−X bond coupling1Implementable and Sustainable Upcycling of Medical Plastic Waste to Liquid Highly Branched Alkanes via Tandem Catalytic Cracking-Hydrogenation Strategy0Electrochemical Postfunctionalization of Polymers: Versatile Strategies for Macromolecular Transformation0

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  1. Formation of highly oriented crystalline structure for polyoxymethylene fiber enables superior intrinsic thermal conductivity

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  2. Electrochemical recycling of polymeric materials

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  3. Selective Recovery of Para-Xylene from Polyethylene Terephthalate Plastic

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    Li Jiang, Zhidong An, Yue Kong, Le Zhang, Jinqi Yang, Xiaojing Wang, Jiatian Wang, Delong Duan, Qi Zhang, Ran Long, Dionisios G. Vlachos, Zhenxing Li

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  4. Selective Electrochemical Modification and Degradation of Polymers

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  6. Chemically recyclable polythioesters prepared by ring-opening polymerization of dithiolactone and monothiodilactone monomers

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  7. Electrocatalysis‐driven sustainable plastic waste upcycling

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  8. Syngas production through CO2-mediated pyrolysis of polyoxymethylene

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  9. Polyoxymethylene Upcycling into Methanol and Methyl Groups Catalyzed by a Manganese Pincer Complex

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  10. Electrochemically Generated Carbocations in Organic Synthesis

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  11. Electrochemically Generated Carbocations in Organic Synthesis

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  13. One-Step Upcycling the Engineering Plastic of Polyoxymethylene toward a Flowing Telechelic Polyester: From Poly(A) to Poly(A-alt-B)

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  14. Electrochemical Postpolymerization Modification and Deconstruction of Macromolecules

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  15. Recent advances in chemical recycling of polyoxymethylene waste

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  16. Valorization of polyoxymethylene (POM) waste as a C 1 synthon for industrially relevant dialkoxymethanes and cyclic aminals

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  17. Chemical Recycling: Monomers and Intermediates from Depolymerization Processes for the Chemical and Plastics Industry

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  18. Exceptional class of semicrystalline and amorphous nanocomposite polymers for specific needs

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  19. Heterogeneous tandem upcycling of polyoxymethylene into methanol and methylene derivatives

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  20. Co-upcycling of polyethylene terephthalate and polyoxymethylene into valuable chemicals

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  21. Photo‐Driven Direct Construction of Imidazolidines from Anilines and Paraformaldehyde and Its Application in Polyoxymethylene Plastics Usage

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  22. Harnessing Non-Thermal External Stimuli for Polymer Recycling

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  23. Upcycling Polyoxymethylene via H2O2‐Mediated Selective Oxidation

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  24. A catalytic approach to the valorization of polyesters and biogenic waste for the production of amines

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  34. Electrochemical depolymerization of polycarbonates under catalyst-free conditions

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