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RESEARCH PAPER · Advanced Energy Materials · 2023

Structurally Dimensional Engineering in Perovskite Photovoltaics

Yulin Liu, Songyang Yuan, Huiqun Zheng, Min Wu, Shiting Zhang, Jing Lan, Wenzhe Li, Jiandong Fan

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Structurally Dimensional Engineering in Perovskite PhotovoltaicsOriginalBinary Cations Minimize Energy Loss in the Wide Bandgap Perovskite Towards Efficient All-Perovskite Tandem Solar Cells0Performance Enhancement and Stability Improvement in Perovskite Solar Cells via Interface Functionalization16Dehydration Induced a Structural Transformation into a One-Dimensional Hybrid Perovskite with Second Harmonic Generation and Dual Dielectric Switching15Critical role of post-treatment induced surface reconstruction for high performance inorganic tin-lead perovskite solar cells33Dimensionality Engineering of Organic–Inorganic Halide Perovskites for Next‐Generation X‐Ray Detector41The chemistry of the s- and p-block elements with 2,2′:6′,2′′-terpyridine ligands24Interfacial Rivet to Fill Structural Defects: A Spacer Engineering Gift for 3D Solar Cells10Top-down synthesis of high-performance lead-free double layer perovskite Cs4CuSb2Cl12 with large specific surface area and rich defects for efficient photocatalytic CO2 reduction13Exploiting halide perovskites for heavy metal ion detection19Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction4Promoting the formation of metal–carboxylate coordination to modulate the dimensionality of ultrastable lead halide hybrids13Regulating energy band alignment for high-performance broadband perovskite photodetectors20Research Progress and Application Prospect of Perovskite Solar Cells2Surface matrix regulation of perovskite quantum dots for efficient solar cells26Long-chain organic molecules enable mixed dimensional perovskite photovoltaics: a brief view10Perovskite solar cells with high-efficiency exceeding 25%: A review72Desirable candidates for high-performance lead-free organic–inorganic halide perovskite solar cells15Integration of One-Dimensional (1D) Lead-Free Perovskite Microbelts onto Silicon for Ultraviolet–Visible–Near-Infrared (UV-vis-NIR) Heterojunction Photodetectors19Achieving Low Cost and High Performance Flexible CsPbIBr 2 Perovskite Photodetectors Arrays with Imaging System via Dual Interfacial Optimization and Structural Design10Key Roles of Interfaces in Inverted Metal-Halide Perovskite Solar Cells52Polyfluorinated Organic Diammonium Induced Lead Iodide Arrangement for Efficient Two‐Step‐Processed Perovskite Solar Cells38Polyfluorinated Organic Diammonium Induced Lead Iodide Arrangement for Efficient Two‐Step‐Processed Perovskite Solar Cells10Anions Regulation of 1D Perovskite Intrusion-Behavior for Efficient and Stable Perovskite Solar Cells15Eliminating Hole Extraction Barrier in 1D/3D Perovskite Heterojunction for Efficient and Stable Carbon‐Based CsPbI 3 Solar Cells with a Record Efficiency59From lab to luminescence: Perovskite-based dimensional integrations pushing LED boundaries24A comprehensive review of organic frameworks: From synthesis to perovskite solar cells fabrication4Ionic liquid engineering enables 1D/3D perovskite photovoltaics with > 25 % efficiency: A real-time study exploring formation mechanism of 1D perovskites13Size Uniformity of CsPbBr3 Perovskite Quantum Dots via Manganese-Doping20Assembling the 2D–3D–2D Heterostructure of Quasi-2D Perovskites for High-Performance Solar Cells15Rational design of efficient boron-doped and nitrogen-deficient g-C3N4/lead-free Cs3Bi2Br9 perovskite nanocrystals Z-scheme heterojunction by optimised surface-active site and interfacial charge transfer10A new zero-dimensional hybrid antimony halide of (C25H46N)2SbCl5 with dual-emission and high quantum-efficiency for light-emitting application17The Crucial Role of Organic Ligands on 2D/3D Perovskite Solar Cells: A Comprehensive Review26Cation Engineering Perovskite Cathodes for Fast and Stable Anion Redox Chemistry in Zinc‐Iodine Batteries29Structure Evolution and Optical Tuning of One-Dimensional Post-perovskite (TDMP)PbBr4 under High Pressure4Loading Precursors into Self‐Assembling Contacts for Improved Performance and Process Control in Evaporated Perovskite Solar Cells14Decoupling Interlayer Spacing and Cation Dipole on Exciton Binding Energy in Layered Halide Perovskites5Boosting Efficiency to 22.73%: Unraveling the Role of Solvent Environment in Low‐Dimensional Perovskites Through Competitive Bonding Interactions27Fine-Tuning Self-Trapped Excitons via External Coordination of Perovskite Octahedra: Simultaneous Achievement of Significant Stokes Shifts and Enhanced Emission9Conformational Disordering of Organic Cations during Moisture-Induced Structural Collapse in Organic–Inorganic Hybrid Perovskites7Advances in Metal Halide Perovskite Memristors: A Review from a Co‐Design Perspective52Crown Ether-Modified 1D/3D Heterojunction for Efficient and Stable Carbon-Based CsPbI3 Perovskite Solar Cells42D/3D heterojunction carrier dynamics and interface evolution for efficient inverted perovskite solar cells15Chirality-driven dimensionality and broadband emission in lead bromide perovskites6Multifunctional small molecule interface management for efficient planar perovskite solar cells1Piezoelectricity in a mixture of chiral 1D hybrid lead bromide and iodide systems3Regulating the Charge Transport Ability of the TiO2/CsPbI2Br Perovskite Interface Layer by MoS2Nanoparticles for High-Performance Carbon-Based All-Inorganic Perovskite Solar Cells02D/3D Heterojunction Engineering for Hole Transport Layer‐Free Carbon‐Based Perovskite Solar Cells9Dopant-free hole-transporting material with passivation effect based on Benzo[1,2-b:4,3-b′]dithiophene for inverted perovskite solar cells5Mixed‐Halide Perovskites with Suppressed Phase Segregation for Large Modulation Depth and High‐Stability Terahertz Modulators11Enhancing Efficiency and Stability of Perovskite Solar Cells via Mixed Cation Passivation with GAI/BDAI on the 3D Perovskite Layer20Emerging low-dimensional perovskite photoferroelectrics: From crystallographic microstructure to applications8Enhancing Performance of NiO x ‐Based Inverted Perovskite Solar Cells: Advances in Buried Interface Material Modification Strategy42Micro-Nano Fractal Metal Grids as Transparent Conductive Electrodes for Highly Efficient and Stable Perovskite Solar Cells17Direct X-ray Detectors Based on Halide Perovskites2Switchable Behavior and Applications of Low‐Dimensional Halide Perovskites under External Environmental Stimuli13D/1D Perovskite Heterojunction for High‐Performance Direct X‐ray Detector8Editable Light Response in Halide Perovskites Encapsulated within Single-Walled Carbon Nanotubes6Low-Dimensional Ligand-Driven Design of 2D/3D Perovskite Heterojunctions: Achieving Mitigated Nonradiative Recombination and Robust Stability for Next-Generation Solar Cells8“Electricity”‐Assisted Catalytic Solar‐to‐Fuel Processes20“Electricity”‐Assisted Catalytic Solar‐to‐Fuel Processes0Interface Modulation by Macromolecules for Enhancing the Efficiency and Stability of Perovskite Solar Cells8CsPbI3 Nanorod Additive Engineering: Enhancing Efficiency and Stability in Mixed-Cation CsMAFAPbI3 Perovskite Solar Cells7Precisely Tuning 3D/Quasi‐2D Perovskite Heterojunctions in Wide‐Bandgap Perovskites for High‐Performance Tandem Solar Cells22Amidation‐Retarded Synthesis of Perovskite Quantum Dots with Low Defect Density and Enhanced Carrier Transport for Efficient Light Emitting Diodes and Solar Cells26Dicyandiamide-Driven Tailoring of the n-Value Distribution and Interface Dynamics for High-Performance ACI 2D Perovskite Solar Cells10Sustainable energy approaches using Perovskite materials: a comprehensive review of energy applications15Unprecedented Mixed Low‐Dimensional Metal Halide Double Perovskite for Stable and Efficient X‐Ray Detection8Direct Lead‐Iodide Scaffold Engineering via Macrocyclic Dual‐Function Coordination Breaks the Efficiency‐Stability Gap in 2D Perovskite Solar Cells10A Study on the Photovoltaic Conversion Mechanism of High-Efficiency Lead Halide Perovskite Solar Cells0Engineering Tin Oxide Electron Transport Layers for High‐Performance n‐i‐p Perovskite Solar Cells: Challenges, Strategies, and Prospects5In‐Depth Review of Multiphysics and Circuit Simulation Approaches for Perovskite Solar Cells4Diversified dimensionality of nanomaterials and their Fӧrster resonance energy transfer based applications3Regulating the charge transport ability of the TiO2/CsPbI2Br perovskite interface layer by MoS2 nanoparticles for high-performance carbon-based all-inorganic perovskite solar cells3Perovskite materials for multifaceted energy applications: From fundamental properties to industrialization challenges4Enhanced Thermal Stability in Perovskite Solar Cells via the Integration of a Nonionic Binary Compound6Vacancy-mediated electromagnetic loss tuning in Cr-doped lanthanum manganite perovskites for broadband and high-intensity microwave absorption16Engineering Chalcogenide-Containing Spacers: Modulating Internal Interactions for Enhanced Performance and Stability in Ruddlesden–Popper Perovskite Devices3Perovskite Solar Cells Enabled by the Synergy of Chlorine Additive and Scalable Rapid Photonic Annealing of Multiple Stacking Layers0Dimensionality-driven decoupling of electronic–ionic transport in a Cs 4 PbBr 6 /CsPbBr 3 heterojunction0Fully 2D heterojunction perovskite photovoltaics using chalcogenides2Halide perovskite scintillators for X-ray detection: from structure to engineering9Organo-sulfur chemistry in perovskite solar cells: fundamentals to functional strategies4The impact of mixed solvent on blade-coated surface passivation of perovskite films and their photovoltaic performance0Integrated Photon Ellipticity Recognition with Chiral Nanomaterials1Alkylammonium Spacer-Directed Charge-Transfer in 2D|3D Perovskite Solar Cells2Compositing halide perovskites for multifunctionalities beyond optoelectronics1High-efficiency (>27%) lead-free CsGeI3-based perovskite solar cells: A first-principles calculation, device simulation, and machine learning study0Synergistic Interface Engineering via a Dual-A-Site 1D Perovskite Bridge for Efficient All-Perovskite Tandems2Interface-driven modulation of structure and electronic properties in CNT-encapsulated CsPbI 3 and Cs4PbI5 1D perovskites0Peripherally Fluorinated Tetraphenylethene: New Electron Extraction Interlayers for n‐i‐p Perovskite Solar Cells2Investigation of the stable and non-toxic halide perovskite-inspired AgBiZ4 (Z = Cl, Br, I) for photovoltaic applications0Dimensional control of low-dimensional perovskite hybrids for photovoltaics61D/3D Heterojunction for High‐Efficiency Hole‐Transport Layer‐Free Carbon‐Based Wide‐Bandgap Perovskite Solar Cells1Vertically oriented 1D/3D heterojunction for efficient and stable inverted perovskite solar cells1System-level integration of halide perovskite optoelectronics for its commercial deployment6Perovskite Photodetectors at the Intelligence Frontier: From Tunable Materials to Adaptive Optoelectronic Systems2Quantifying hybrid lead halide perovskites from multiple viewpoints: a human-guided machine learning approach1Ligand engineering for Pb-based perovskite optoelectronic devices0Organophosphorus chemistry for emerging perovskite photovoltaics: fundamentals to functional strategies1Towards a Balance between Functionality and Stability: Energy‐Safety Synergistic Mechanisms and Prospects in Perovskite Energetic Materials0Synergy of Low‐ and High‐Polarity Cations for Stabilizing 2D Perovskites0

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  1. Binary Cations Minimize Energy Loss in the Wide Bandgap Perovskite Towards Efficient All-Perovskite Tandem Solar Cells

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  2. Performance Enhancement and Stability Improvement in Perovskite Solar Cells via Interface Functionalization

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  3. Dehydration Induced a Structural Transformation into a One-Dimensional Hybrid Perovskite with Second Harmonic Generation and Dual Dielectric Switching

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  4. Critical role of post-treatment induced surface reconstruction for high performance inorganic tin-lead perovskite solar cells

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  5. Dimensionality Engineering of Organic–Inorganic Halide Perovskites for Next‐Generation X‐Ray Detector

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  8. Top-down synthesis of high-performance lead-free double layer perovskite Cs4CuSb2Cl12 with large specific surface area and rich defects for efficient photocatalytic CO2 reduction

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  9. Exploiting halide perovskites for heavy metal ion detection

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  10. Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction

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  15. Long-chain organic molecules enable mixed dimensional perovskite photovoltaics: a brief view

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  17. Desirable candidates for high-performance lead-free organic–inorganic halide perovskite solar cells

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  19. Achieving Low Cost and High Performance Flexible CsPbIBr 2 Perovskite Photodetectors Arrays with Imaging System via Dual Interfacial Optimization and Structural Design

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  20. Key Roles of Interfaces in Inverted Metal-Halide Perovskite Solar Cells

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  21. Polyfluorinated Organic Diammonium Induced Lead Iodide Arrangement for Efficient Two‐Step‐Processed Perovskite Solar Cells

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  30. Rational design of efficient boron-doped and nitrogen-deficient g-C3N4/lead-free Cs3Bi2Br9 perovskite nanocrystals Z-scheme heterojunction by optimised surface-active site and interfacial charge transfer

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  34. Structure Evolution and Optical Tuning of One-Dimensional Post-perovskite (TDMP)PbBr4 under High Pressure

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  43. Chirality-driven dimensionality and broadband emission in lead bromide perovskites

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  44. Multifunctional small molecule interface management for efficient planar perovskite solar cells

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  45. Piezoelectricity in a mixture of chiral 1D hybrid lead bromide and iodide systems

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  46. Regulating the Charge Transport Ability of the TiO2/CsPbI2Br Perovskite Interface Layer by MoS2Nanoparticles for High-Performance Carbon-Based All-Inorganic Perovskite Solar Cells

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    Huang Zhaowei, Lin Gao, Fengli Liu, Xu Shihui, Chai Yaxuan, Jing Li, Qing Yao, Haozhen Deng, Liuxue Sun, Jihuai Wu, Zhang Lan

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  47. 2D/3D Heterojunction Engineering for Hole Transport Layer‐Free Carbon‐Based Perovskite Solar Cells

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    Lingcong Li, Yinlong Lai, Huashang Rao, Weizi Cai, Xinhua Zhong, Huishi Guo, Zhenxiao Pan

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  48. Dopant-free hole-transporting material with passivation effect based on Benzo[1,2-b:4,3-b′]dithiophene for inverted perovskite solar cells

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    Deling Zhang, Xiaochun Wei, Bo Yu, Hanlun Wu, Hanlun Wu, Hao Tang, Lingyun Wang, Huangzhong Yu, Derong Cao

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  49. Mixed‐Halide Perovskites with Suppressed Phase Segregation for Large Modulation Depth and High‐Stability Terahertz Modulators

    Small Structures · 2025-01-28

    Xunjun He, Binchao Sun, Guangjun Lu, Zhaoxin Geng, Ying Zhang

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  50. Enhancing Efficiency and Stability of Perovskite Solar Cells via Mixed Cation Passivation with GAI/BDAI on the 3D Perovskite Layer

    ACS Applied Energy Materials · 2025-02-02

    Karthikeyan Embrose, Manasa Hamsiga Prakash, Thangaraji Vasudevan, Lung‐Chien Chen

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