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RESEARCH PAPER · Chemical Engineering Journal · 2023

A notable reversible thermochromic (3,3-difluoropyrrolidinium)2[CuCl4] with ferroelectricity and ferroelasticity

Shulin Jiao, Zheng Tang, Dong Li, Cuiping Xu, Yang Zhu, Peng Chen, Xiaofan Sun, Hong‐Ling Cai, Xiaoshan Wu

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A notable reversible thermochromic (3,3-difluoropyrrolidinium)2[CuCl4] with ferroelectricity and ferroelasticityOriginalMolecular orientation dynamics triggers ferroelectricity and ferroelasticity in an organic–inorganic halide material23Reversible phase transition and thermochromic response in hybrid copper-based perovskites18Thermo-mechanical behavior and thermochromic properties of 3D-printed PLA polymer5Advances in the modulation engineering of ferroelectrics and multiferroics with non-chemical agents and factors: a review10Hydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials9Halide Anions Tuning of Lead‐Free Perovskite‐Type Ferroelectric Semiconductors with Inverse High‐Temperature Symmetry Breaking11Crystal Structure and Optical Properties Characterization in Quasi-0D Lead-Free Bromide Crystals (C6H14N)3Bi2Br9·H2O and (C6H14N)3Sb3Br128B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics15Three-Step Ferroelastic Transitions from Hexagonal to Triclinic Phases in a Hybrid Perovskite: (1-Fluoromethyl-1-methylpyrrolidine)[CdCl3]8High-Contrast Thermochromism in Room-Temperature Transparent Layered Perovskite PEA 2 PbBr 4 with a High Temperature-Induced Bandgap Change Rate of 0.8 meV/K30A stable and sensitive organic–inorganic hybrid reversible thermochromic material: [1-(2-fluoroethyl)piperazine] 2 [CuCl 4 ]2Hydrogen-Bonding-Driven Design of Organic–Inorganic Hybrid Ferroelastics with Reversible Photoisomerization6Low-cost and easily prepared rewritable silica photonic crystal pigment used for paper and textile0Structural Phase Transition‐Associated Ferroelectricity and Piezoelectric Energy Harvesting in 0D Halogenozincate Hybrid via Cation's Terminal Group Lengthening4Halogen-substitution-induced magnetic-phase transition photoelectric synergy in l-valine crown ether inclusion complexes3Dual-functional copper( i ) halides with solvent-induced rapid luminescence switching toward information encryption and white-light emission0An Organic–Inorganic Hybrid Ferroelastic Semiconductor with Thermochromic Effect2Polycrystalline ferroelectricity in a molecular crystal for piezoelectric sensing3Thermochromic Hybrid Ferroelastic Semiconductor with Thermal/Electrical/Optical Switching Responses2Dynamic order–disorder transition enabling ferroelastic and dielectric switching in a zero-dimensional Zr4+-based perovskite3H/F substitution strategy for molecular ferroelectrics: From design principles to emerging materials0Translational-Symmetry-Breaking Ferroelasticity with Domain Switching and Thermochromism in a Copper(II) Organic–Inorganic Hybrid1

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  1. Molecular orientation dynamics triggers ferroelectricity and ferroelasticity in an organic–inorganic halide material

    Inorganic Chemistry Frontiers · 2023-01-01

    Hao‐Fei Ni, Jiahe Lin, Changfeng Wang, Qing-Feng Luo, Pei‐Zhi Huang, Zhi‐Xu Zhang, Da‐Wei Fu, Yi Zhang

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  2. Reversible phase transition and thermochromic response in hybrid copper-based perovskites

    Journal of Materials Chemistry C · 2023-01-01

    Gele Teri, Qiang‐Qiang Jia, Qing-Feng Luo, Hao‐Fei Ni, Da‐Wei Fu, Qiang Guo

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  3. Thermo-mechanical behavior and thermochromic properties of 3D-printed PLA polymer

    Sadhana · 2023-11-01

    Naserddine Ben Ali, Antoine Le Duigou

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  4. Advances in the modulation engineering of ferroelectrics and multiferroics with non-chemical agents and factors: a review

    Journal of Materials Chemistry A · 2023-11-22

    Xinqiu Deng, Yuying Wu, Zhangran Gao, Gang Zhou

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  5. Hydrogen-bond engineering induced ferroelastic phase transition in copper-based organic–inorganic hybrid thermochromic materials

    Chemical Communications · 2024-01-01

    Xin Deng, Lin Zhou, Xin Yan, Yanjuan Wang, Wen-Li Yang, Hui‐Peng Lv, Yuan‐Yuan Tang

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  6. Halide Anions Tuning of Lead‐Free Perovskite‐Type Ferroelectric Semiconductors with Inverse High‐Temperature Symmetry Breaking

    Small · 2024-02-11

    Shulin Jiao, Xiaofan Sun, Min Zhao, Peng Chen, Zheng Tang, Dong Li, Zilong Zhou, Tingfeng Li, Wentao Zhang, Yanzhou Lu, Yizhang Wu, Kongmeng Ye, Libo Xu, Qi You, Hong‐Ling Cai, Xiaoshan Wu

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  7. Crystal Structure and Optical Properties Characterization in Quasi-0D Lead-Free Bromide Crystals (C6H14N)3Bi2Br9·H2O and (C6H14N)3Sb3Br12

    Inorganic Chemistry · 2024-02-27

    Hao Tang, Pengfei Zheng, Zhifeng Xiao, Kejia Yuan, Hanwen Zhang, Xiaochen Zhao, Wei Zhou, Shouyu Wang, Weifang Liu

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  8. B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics

    Chinese Chemical Letters · 2024-03-04

    Hao‐Fei Ni, Jiahe Lin, Gele Teri, Qiang‐Qiang Jia, Pei‐Zhi Huang, Hai‐Feng Lu, Changfeng Wang, Zhi‐Xu Zhang, Da‐Wei Fu, Yi Zhang

    Read original paper ↗ ·

  9. Three-Step Ferroelastic Transitions from Hexagonal to Triclinic Phases in a Hybrid Perovskite: (1-Fluoromethyl-1-methylpyrrolidine)[CdCl3]

    Inorganic Chemistry · 2024-04-15

    Shuai Chen, Ding‐Chong Han, Le Ye, Wei‐Xiong Zhang

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  10. High-Contrast Thermochromism in Room-Temperature Transparent Layered Perovskite PEA 2 PbBr 4 with a High Temperature-Induced Bandgap Change Rate of 0.8 meV/K

    Journal of the American Chemical Society · 2024-08-21

    Xiaoyu Song, Xinsheng Liu, Danwen Zhang, Jingyan Liao, Siqi Zhu, Wei Zheng

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  11. A stable and sensitive organic–inorganic hybrid reversible thermochromic material: [1-(2-fluoroethyl)piperazine] 2 [CuCl 4 ]

    CrystEngComm · 2025-01-01

    Kang Zuo, Ruisi Yu, Wei Bao, Shuai Shao, Qing-Ling Cao, Hao Du, Linna Tian, Jia-Jia Zhao, Li-Zhuang Chen

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  12. Hydrogen-Bonding-Driven Design of Organic–Inorganic Hybrid Ferroelastics with Reversible Photoisomerization

    Inorganic Chemistry · 2025-01-23

    Luis Verissimo, Zijun Fang, Wei‐Jian Xu, José M. G. Martinho, Wei Yuan, Wei‐Xiong Zhang, Andréi L. Kholkin, João Rocha

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  13. Low-cost and easily prepared rewritable silica photonic crystal pigment used for paper and textile

    Industrial Crops and Products · 2025-04-08

    Cheng Chen, Jing Zhang, Yuanyuan Xie, Yutong Wang, Yufei Chen, Ruilai Wang, Zhi‐wei Zhang, Kaige Lin, Jiang Li

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  14. Structural Phase Transition‐Associated Ferroelectricity and Piezoelectric Energy Harvesting in 0D Halogenozincate Hybrid via Cation's Terminal Group Lengthening

    Small Methods · 2025-05-24

    Caihong Shi, Caihong Shi, Si‐Yu Deng, Jun‐Yi Li, Hao‐Ran Chen, Qing‐Ling Cao, Wen‐He Zhong, Jieyu Zhu, Shuai Shao, Wei Bao, Hao Du, Li-Zhuang Chen, Chao Yi Shi, Chao Yi Shi, Jiajia Zhao

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  15. Halogen-substitution-induced magnetic-phase transition photoelectric synergy in l-valine crown ether inclusion complexes

    Chinese Chemical Letters · 2025-07-03

    Na Wang, Hongzhi Hu, Qiang‐Qiang Jia, Yang Liu, Zunqi Liu, Da‐Wei Fu

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  16. Dual-functional copper( i ) halides with solvent-induced rapid luminescence switching toward information encryption and white-light emission

    Chemical Communications · 2026-01-01

    Bo Wang, Yani Li, Lin Yang, Xinxiang Gao, Yan Xu

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  17. An Organic–Inorganic Hybrid Ferroelastic Semiconductor with Thermochromic Effect

    Inorganic Chemistry · 2026-01-20

    Miao Wang, Hao Yuan, Feng-Ying Gu, Wei Hu, Yuan‐Yuan Tang, Xian‐Jiang Song

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  18. Polycrystalline ferroelectricity in a molecular crystal for piezoelectric sensing

    Chemical Engineering Journal · 2026-02-12

    Gele Teri, Jing-Song Tang, Peng-Cheng Zhuge, Jia‐Qi Luo, Hao-fei Ni, Lei Pan, Qiang-Qiang Jia, Yan Zhang, Da‐Wei Fu, Zhi-Xu Zhang

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  19. Thermochromic Hybrid Ferroelastic Semiconductor with Thermal/Electrical/Optical Switching Responses

    Inorganic Chemistry · 2026-03-02

    Yan-Juan Wang, Ye Du, Xiao-Yu Zhang, Yan‐Ran Weng, Yan Qin, Lin Zhou, Yuan‐Yuan Tang

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  20. Dynamic order–disorder transition enabling ferroelastic and dielectric switching in a zero-dimensional Zr4+-based perovskite

    Inorganic Chemistry Communications · 2026-03-26

    Rong-Jie Hao, Zheng-Hui Hu, Hongfei Zhao, Qiulan Tan, Yu‐Hui Tan, Nan Ma, Chao Shi, Yun-Zhi Tang

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  21. H/F substitution strategy for molecular ferroelectrics: From design principles to emerging materials

    Coordination Chemistry Reviews · 2026-06-13

    H Y Chen, Yuqin Susan Xiong, Hailong Zhang

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  22. Translational-Symmetry-Breaking Ferroelasticity with Domain Switching and Thermochromism in a Copper(II) Organic–Inorganic Hybrid

    Inorganic Chemistry · 2026-07-23

    Jun‐Chao Liu, Han Shu-qi, Xinyi Yang, Wan-ying Zhang, Ping‐Ping Shi

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