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RESEARCH PAPER · Advanced Optical Materials · 2023

Chemical Group Substitution Enables Highly Efficient Mn4+ Luminescence in Heterovalent Systems

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Chemical Group Substitution Enables Highly Efficient Mn4+ Luminescence in Heterovalent SystemsOriginalA Na 2 MoO 2 F 4 :Mn 4+ phosphor with red luminescence peaking at 625 nm and a ZPL/ v 6 intensity ratio of 243%23Exploring dual-emission properties in Mn 4+ distinctively activated BaTaF 7 red emitting phosphor21Optical enhancement of highly efficient organic–inorganic oxyfluoride red phosphors via the cation co-doping strategy8Mn4+-doped organometallic hafnium hexafluoride phosphors: Achieving near-unity quantum yield to elevate LED performance13Charge compensating effect of cation doping on the enhanced luminescent and stability of La2LiTaO6:Mn4+ red phosphor21Illuminating the path to high-precision dual-mode optical thermometry: A Mn4+-activated oxyfluoride single crystal for a portable optical fiber thermometric platform51Structure‐Based Machine Learning Enables Discovery of Mn 4+ ‐Activated Red‐Light Fluorides for Ultrawide‐Gamut Mini‐Light‐Emitting Diodes27Machine-Learning-Driven Discovery of Mn 4+ -Doped Red-Emitting Fluorides with Short Excited-State Lifetime and High Efficiency for Mini Light-Emitting Diode Displays32Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Realizing Stable Luminescence in Antimony Doped Hybrid Tin(IV) Chloride toward Full Spectrum WLED and Anticounterfeiting Applications6Enhancing Hydrophobicity in Mn 4+ ‐Doped Organometallic Fluoride with High Quantum Efficiency through the Utilization of Trimethylsulfoxide Cation7Kinetics‐Tunable Photochromism and Dual‐Mode Luminescence Modulation in BaTiO 3 ‐Based Phosphors for Dynamic Anti‐Counterfeiting Application12Novel red-emitting Mn4+ activated Mg4Ta2O9 phosphors for flexible display and anti-counterfeiting applications12Photoluminescence enhancement of Mn 4+ -doped Rb 2 NaAlF 6 single-crystal phosphors via heterovalent co-doping for wide gamut displays19Realizing Antithermal Quenching Red Emission in Mn4+‐Activated Rb2NaVF6 for Optical Thermometry Sensor Application0Emerging 0D Hybrid Metal Halide Luminescent Glasses112High-efficiency and thermally stable Cr3+-doped BaSiF6 fluoride phosphors for broadband near-infrared LED applications5Alleviating wavelength efficiency trade-offs in Cr3+-activated garnet phosphors by high entropy engineering4Theoretical Prediction‐Assisted Synthesis of Narrow‐Band Red‐Emitting Fluoride Phosphors with High Film‐Forming Ability for Mini Light‐Emitting Diode Displays1Surface-passivated (GA)xK2-xSiF6: Mn4+ organic-inorganic hybrid red phosphor: Enhanced stability and promising utilization in WLEDs0A novel Cr3+ -activated Rb2KWO3F3 oxyfluoride phosphor with enhanced broadband near-infrared emission via energy transfer engineering0Novel solid solution organic-inorganic hybrid GA3Al0.3Ga0.7F6:Mn4+ red phosphor with dual stability: Crystal field optimization, fluorescence enhancement and application in warm white LED0Boosting Mn 4+ Luminescence Through Hybrid Single‐Crystal Engineering Suppressing Energy Migration and Defect‐Related Quenching0Enhanced far-red emission via charge compensation for plant-growth lighting0K+ and Ce3+ co-doped Ba2.96P4O13:0.04Eu2+ white light emitting phosphor: Crystal phase transformation analysis and luminescence properties0High‐Quality Photoplethysmography Signal Enabled by Narrowband Red Phosphor Converted Light‐Emitting Diodes for Accurate Blood‐Pressure Monitoring0Luminescent Properties and 3-Bit Ternary-Coding Optical Anti-Counterfeiting of Mg4Al4.5Ga2.45B1.05O16:Mn2 + /Mn4 +0

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  1. A Na 2 MoO 2 F 4 :Mn 4+ phosphor with red luminescence peaking at 625 nm and a ZPL/ v 6 intensity ratio of 243%

    Journal of Materials Chemistry C · 2023-01-01

    Qiao Qu, Konglan Chen, Yayun Zhou, Jinsheng Li, Haipeng Ji

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  2. Exploring dual-emission properties in Mn 4+ distinctively activated BaTaF 7 red emitting phosphor

    Journal of Materials Chemistry C · 2023-01-01

    Konglan Chen, Shiyu Jia, Zifan Shao, Xinxin Han, Jian Yuan, Yayun Zhou, Tingting Deng

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  3. Optical enhancement of highly efficient organic–inorganic oxyfluoride red phosphors via the cation co-doping strategy

    Dalton Transactions · 2023-01-01

    Xiaoyi Liu, Haiming Cheng, Hu Wang, Wen Jun Zhu, Guixia Liu, Shengda Liu, Dan Li, Jinxian Wang, Wensheng Yu, Xiangting Dong

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  4. Mn4+-doped organometallic hafnium hexafluoride phosphors: Achieving near-unity quantum yield to elevate LED performance

    Ceramics International · 2023-10-21

    Xinhua Liu, Xinhua Liu, Peiqing Cai, Yanlin Huang, Xipeng Pu, Junjie Si, Junjie Si, Xin Jian Yao, Gongxun Bai, Zugang Liu

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  5. Charge compensating effect of cation doping on the enhanced luminescent and stability of La2LiTaO6:Mn4+ red phosphor

    Journal of Alloys and Compounds · 2023-10-26

    Yanan Li, Hu Wang, Guixia Liu, Shengda Liu, Jinxian Wang, Wensheng Yu, Xiangting Dong

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  6. Illuminating the path to high-precision dual-mode optical thermometry: A Mn4+-activated oxyfluoride single crystal for a portable optical fiber thermometric platform

    Chemical Engineering Journal · 2023-11-07

    Konglan Chen, Zifan Shao, Chuang Zhang, Shiyu Jia, Tingting Deng, Rongfu Zhou, Yayun Zhou, Yayun Zhou, Enhai Song

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  7. Structure‐Based Machine Learning Enables Discovery of Mn 4+ ‐Activated Red‐Light Fluorides for Ultrawide‐Gamut Mini‐Light‐Emitting Diodes

    Advanced Functional Materials · 2023-12-22

    Yuanjing Wang, Wenyu Tang, Chuang Zhang, Мaxim S. Моlokeev, Hong Ming, Yayun Zhou, Shuai Peng, Enhai Song, Qinyuan Zhang

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  8. Machine-Learning-Driven Discovery of Mn 4+ -Doped Red-Emitting Fluorides with Short Excited-State Lifetime and High Efficiency for Mini Light-Emitting Diode Displays

    ACS Materials Letters · 2024-04-03

    Hong Ming, Yayun Zhou, Мaxim S. Моlokeev, Chuang Zhang, Lin Huang, Yuanjing Wang, Hong‐Tao Sun, Enhai Song, Qinyuan Zhang

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  9. Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review

    Laser & Photonics Review · 2024-08-09

    Hongling Wang, Lefu Mei, Ke Su, Jingyi Liu, Qi Wang, Zhaojie Wu, Qingfeng Guo, Libing Liao

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  10. Realizing Stable Luminescence in Antimony Doped Hybrid Tin(IV) Chloride toward Full Spectrum WLED and Anticounterfeiting Applications

    Inorganic Chemistry · 2024-09-10

    Han Ma, Enbei Yang, Fengsong Tan, Qiang Zhou, Tao Yang, Huaijun Tang, Jing Wan, Long Jiang, Zhengliang Wang

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  11. Enhancing Hydrophobicity in Mn 4+ ‐Doped Organometallic Fluoride with High Quantum Efficiency through the Utilization of Trimethylsulfoxide Cation

    Advanced Optical Materials · 2024-11-18

    Yuxin Zhan, Peiqing Cai, Boya Li, Xipeng Pu, Guanghua Wang, Jie Zhang, Zugang Liu

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  12. Kinetics‐Tunable Photochromism and Dual‐Mode Luminescence Modulation in BaTiO 3 ‐Based Phosphors for Dynamic Anti‐Counterfeiting Application

    Advanced Optical Materials · 2024-12-16

    Shasha Fu, Anjun Huang, Heping Zhao, Yingzhu Zi, Xue Bai, Ziwen Gao, Asif Ali Haider, Yue Liu, Yangke Cun, Zhiguo Song, Jianbei Qiu, Tatiana Grigorievna Cherkasova, Zhengwen Yang

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  13. Novel red-emitting Mn4+ activated Mg4Ta2O9 phosphors for flexible display and anti-counterfeiting applications

    Ceramics International · 2024-12-20

    Weiwei Xiang, Jae Su Yu

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  14. Photoluminescence enhancement of Mn 4+ -doped Rb 2 NaAlF 6 single-crystal phosphors via heterovalent co-doping for wide gamut displays

    Inorganic Chemistry Frontiers · 2025-01-01

    Zhen Chen, Chuang Zhang, Yuanjing Wang, Hong Ming, Yayun Zhou, Enhai Song, Qinyuan Zhang

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  15. Realizing Antithermal Quenching Red Emission in Mn4+‐Activated Rb2NaVF6 for Optical Thermometry Sensor Application

    Luminescence · 2025-01-01

    Hui Min Jia, Hanrui Liao, Weilun Zhang, Wei Wang, Jinxuan Sun, Wei Li, Yi Wei

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  16. Emerging 0D Hybrid Metal Halide Luminescent Glasses

    Advanced Materials · 2025-01-02

    Bohan Li, Yuzhen Wang, Yan Shen Xu, Zhiguo Xia

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  17. High-efficiency and thermally stable Cr3+-doped BaSiF6 fluoride phosphors for broadband near-infrared LED applications

    Journal of Luminescence · 2025-01-17

    Wei Wan, Man Li, Jingyan Jiang, Yifei Zhao, Yayun Zhou

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  18. Alleviating wavelength efficiency trade-offs in Cr3+-activated garnet phosphors by high entropy engineering

    Journal of Alloys and Compounds · 2025-06-24

    Lipeng Jiang, Jing Wang, Zhongxiang Shi, Junji Zhang, Junji Zhang, Guojun Li, Hongbo Yu, Wei Si, Liangliang Zhang, Liangliang Zhang, Yanjing Su

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  19. Theoretical Prediction‐Assisted Synthesis of Narrow‐Band Red‐Emitting Fluoride Phosphors with High Film‐Forming Ability for Mini Light‐Emitting Diode Displays

    Laser & Photonics Review · 2025-11-05

    Zhen Chen, Hong Ming, Chuang Zhang, Renhua Guo, Ziang Peng, Enhai Song, Qinyuan Zhang

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  20. Surface-passivated (GA)xK2-xSiF6: Mn4+ organic-inorganic hybrid red phosphor: Enhanced stability and promising utilization in WLEDs

    Journal of Luminescence · 2026-02-07

    Wenjing Han, Ying Jin, Xiaoyi Liu, Zhe Qiu, Shengda Liu, Jiayin Zhan, Jinxian Wang, Xiangting Dong, Guixia Liu

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  21. A novel Cr3+ -activated Rb2KWO3F3 oxyfluoride phosphor with enhanced broadband near-infrared emission via energy transfer engineering

    Journal of Alloys and Compounds · 2026-03-18

    Xixiang Pan, Min Liu, Songbin Liu, Songbin Liu, Wanfang Zou, Xinyu Zhang, Jiaqing Peng, Fengli Yang, Chunpei Yan, Junjun Tan, Xinyu Ye

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  22. Novel solid solution organic-inorganic hybrid GA3Al0.3Ga0.7F6:Mn4+ red phosphor with dual stability: Crystal field optimization, fluorescence enhancement and application in warm white LED

    Ceramics International · 2026-07-01

    Jin Zhou, Haiqing Su, Chengyue Wang, Jiaping Yu, Jiajun Liao, Feng Hong, Shuang Yan, Jingjing Zhang, Hai Lin

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  23. Boosting Mn 4+ Luminescence Through Hybrid Single‐Crystal Engineering Suppressing Energy Migration and Defect‐Related Quenching

    Advanced Optical Materials · 2026-07-17

    Zhen Chen, Hong Ming, Chuang Zhang, Renhua Guo, Ziang Peng, Enhai Song, Qi Zhang

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  24. Enhanced far-red emission via charge compensation for plant-growth lighting

    Ceramics International · 2026-08-01

    Kexin Wang, Jingyi Zhang, Hongbo Yu, Wei Si, Lipeng Jiang, Jing Wang, Li Zhang

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  25. K+ and Ce3+ co-doped Ba2.96P4O13:0.04Eu2+ white light emitting phosphor: Crystal phase transformation analysis and luminescence properties

    Journal of Rare Earths · 2026-08-01

    Zhan‐Chao Wu, Chang Liu, Jingxing Cao, Jixin Sun, Yuning Zhang, Jie Liu, Zhanchao Wu

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  26. High‐Quality Photoplethysmography Signal Enabled by Narrowband Red Phosphor Converted Light‐Emitting Diodes for Accurate Blood‐Pressure Monitoring

    Advanced Materials · 2026-08-06

    Renhua Guo, Weiyang Gong, Enhai Song, Chuang Zhang, Yuanjing Wang, Hong Ming, Zhen Chen, Ziang Peng, Zhicai He, Qinyuan Zhang

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  27. Luminescent Properties and 3-Bit Ternary-Coding Optical Anti-Counterfeiting of Mg4Al4.5Ga2.45B1.05O16:Mn2 + /Mn4 +

    Inorganic Chemistry · 2026-09-11

    Peng Liao, Ye Jin, Haojie Sun, Wen Liu, Li Ma, Xiaojun Wang

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