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RESEARCH PAPER · Advanced Functional Materials · 2023

Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in Air

Jianhui Wang, Lile Dong, Zeyu Lyu, Dashuai Sun, Taixing Tan, Hongpeng You

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Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in AirOriginalNovel highly efficient Bi 3+ -activated phosphors for warm WLEDs39Effective ratiometric optical thermometry based on inverse temperature dependent dual near infrared emission of Cr3+ doped BaAl4Sb2O12 phosphor18A Novel Cyan Phosphor (K,Rb) 3 GdSi 2 O 7 :Ce 3+ for Full‐Spectrum Lighting through Local Structure Tailoring48Moderate Trap Engineering for Enhanced Thermal Stability and High Efficiency in a Bi3+-Doped Phosphor45Tapping the Light Emitting Potential of Chalcogenide Perovskite SrHfS3 via Eu2+ Doping24High Output Power and High Quantum Efficiency in Novel NIR Phosphor MgAlGa0.7B0.3O4:Cr3+ with Profound FWHM Variation143Unveiling the Potential of Sunlight‐Driven Multifunctional Blue Long Persistent Luminescent Materials via Cutting‐Edge Trap Modulation Strategies24Crystal Field Engineering Yields New 3D Layered Solid Solution Phosphors (Ca/Sr)4MgAl2Si3O14:Eu2+ for White-Light-Emitting Diode Full-Spectrum Lighting17A novel extra-broadband visible-emitting garnet phosphor for efficient single-component pc-WLEDs6An efficient blue–violet phosphor: an advanced material designed for high-quality full-spectrum lighting11Crystal structure, Bi 3+ yellow luminescence, and high quantum efficiency of Ba 3 SbAl 3 Ge 2 O 14 :Bi 3+ phosphor for white light-emitting diodes31Development of a novel Eu 2+ activated oxonitridosilicate cyan phosphor for enhancing the color quality of a violet-chip-based white LED9Highly efficient blue-green dual-narrow-emission in RbAl 11 O 17 :Eu 2+ ,Mn 2+ toward wide-color-gamut human-centric backlights7Multimodal Dynamic Luminescence from Self-Activated Na2CaGe2O6 Phosphor via Defects Manipulation0Preparation of a novel violet-excitable Na 3 YSi 2 O 7 :Eu 2+ green phosphor via salt-flux assistance and its luminescence properties15Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42BaLiZn 3 (PO 4 ) 3 :Eu 2+ : Ultranarrow-Band Violet Emission in a Highly Symmetric Crystal Structure24Ba3Lu(BO3)3:Ce3+,Tb3+/Mn2+: Dual-Functional Material for WLEDs and Optical Pressure Sensing35Broadband Green-Yellow KGaSi2O6:Eu2+ Phosphor with Excellent Thermal Stability for Near Ultraviolet-Pumped White-Light-Emitting Diodes1Well-Performed Green Phosphor BaY 4 Si 5 O 17 :Ce 3+ ,Tb 3+ with High Quantum Efficiency and Thermal Stability23Manipulating cationic ordering toward highly efficient and zero-thermal-quenching cyan photoluminescence34Suppressing Self‐Oxidation of Eu 2+ in Li 2 CaSiO 4 for Full‐Spectrum Lighting and Accurate Temperature Sensing65Efficient Energy Transfer for Near-Perfect Quantum Efficiency and Thermal Stability10Crystallographic Engineering to Develop Ultra‐Narrow‐Band Cyan‐Emitting UCr 4 C 4 ‐Type Phosphor for Healthy LED Lighting and Display24Achieving Ultra‐Broadband Sunlight‐Like Emission in Single‐Phase Phosphors: The Interplay of Structure and Luminescence44Optimizations of luminescent materials for white light emitting diodes toward healthy lighting27Unlocking Chlorine Oxide‐Based Ultra‐Wideband Near‐Infrared Phosphor and Advancing Spectral Performance via Lattice Engineering43Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Single-Band Ratiometric Thermometry Strategy Based on the Completely Reversed Thermal Excitation of O 2– → Eu 3+ CTB Edge and Eu 3+ 4f → 4f Transition25A novel High-Efficiency cyan phosphor for Human-Centric lighting with 410 nm excited white LEDs49Achieving Eu 2+ Luminescence at Trivalent Lattice Site in Rb 3 Y(PO 4 ) 2 :Eu toward Multicolor Emissions by Carbon and Hydrogen Coreduction23Suppressed concentration quenching and tunable photoluminescence in Eu2+-activated Rb3Y(PO4)2 phosphors for full-spectrum lighting87Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator36Ultrabroadband Visible–Near-Infrared Phosphor CaY2Mg2Ge3O12:Ce3+/Cr3+ and Its Temperature Sensing4Tunable Optical Properties, Enhanced Photoluminescence, and Thermostability of CaO: Eu2+/3+ Phosphors by Codoping Cl– Ions5Ce3+-doped CaSrSiO4 blue phosphor prepared via a novel self-reduction strategy for high-CRI solid-state lighting and visible light communication11Bright electrospun white Y 2 Zr 2 O 7 :Tm 3+ /Dy 3+ nanotubes with excellent thermal quenching resistance and ultralow color shift1Colour tunable NaCaLa(MoO4)3: Tb3+, Eu3+ phosphors for LED and optical anti‑counterfeiting0Insight into temperature dependence of the photoluminescence properties of bright orange-red BaAl 4 Sb 2 O 12 :Bi 3+ phosphors for fluorescence thermometry2Optical and Structural Properties of the Polycrystalline Eu2+ Li2CaSiO4 and Li2SrxCa1-xSiO4:Eu0.0020Theoretically Guided Development of Excitation-Wavelength-Dependent Multifunctional Phosphor Based on Gallium Vacancy Perturbation10A novel phosphate-based phosphor for multifunctional applications realized by energy transmission and color change4Enhancing luminescence through cationic substitution: Synergistic effects of lattice distortion and rigidity augmentation in Sm3+-doped composite perovskite for versatile applications10Adsorption and detection of ofloxacin with Eu-doped Al-organic framework23A Novel Yellow Phosphor(Ba 3 Sc 2 (BO 3 ) 4 : Eu 2+ ) Suitable for Full‐Spectrum Lighting, Featuring Tunable Photoluminescence and Enhanced Luminous Thermal Stability23Chemical Pressure‐Induced FWHM Narrowing in Narrowband Green Phosphors for Laser Displays with Ultra‐High Saturation Thresholds9Development status of rare earth luminescence material19Site‐Selective Occupation of Mn 2+ Activators for Tunable Luminescence in Well‐Designed CaZnGe 2 O 6 Phosphors7A Zero‐Thermal Quenching Flexible Fiber for Visible Cellular Concentration Detection0A Mn 4+ -Doped Far-Red-Emitting Phosphor toward Full-Spectrum Lighting8Tunable Eu2+ red emission via carbon-hydrogen co-reduction and crystal-field engineering for versatile LED applications0High‐Performance Near‐Infrared Ba 3 MgSb 2 O 9 :Fe 3+ , Sn 4+ Phosphors with Elucidated Multifaceted Thermal Quenching Mechanisms14Lattice Site Competition Regulates the Luminescence Centers of Cr 3+ ‐Doped NIR Phosphor for Phonon Sidebands Ratiometric Thermometer and Night Vision2Waste to wealth: transforming Eu2+/Eu3+ co-activation from weak link to strength for advanced multifunctional lighting3Modulation of Lattice Strain‐Induced Eu 2+ Single Lattice Site Emission for Narrow‐Band Green Phosphors in High‐Performance Laser Displays2Color tunable NaCaLa(MoO4)3: Tb3+, Eu3+ phosphors for LED and optical anti-counterfeiting2Breaking Concentration Quenching for Excellent Highly Efficient and Stable Narrowband Luminescence by Structural Ordering and Defect Regulation2Efficient green emission via energy transfer in CaLuAlO4:Ce3+,Tb3+ phosphors for high-quality warm white lighting4Preparation of Ca 2 HfSi 4 O 12 :Ce 3+ , Tb 3+ green phosphor with high quantum efficiency and luminous thermal stability for WLED application3Eu 2+ Luminescence Stabilization at Ln 3+ Sites Promoted by Interstitial Alkali‐Metal Defects5Realizing intense deep-far-red broadband emission derived from mica ceramics through isomorphic cation substitution/doping for plant cultivation lighting and latent fingerprint identification3Environmentally Robust Sr 2‐x P 2 O 7 :xEu 3+ Red Phosphor for Multi‐Scenario Optoelectronic Applications1Aggregation-Controlled Cuprophilic Interactions Enable Blue-Excitable Zero-Dimensional Copper(I) Iodide Phosphors for Single-Component White Light-Emitting Diodes and Visible-Light Communication0Antithermal Quenching in Sm 3+ Doped Double Perovskite Phosphors2Self‐Reduced Eu 2+ /Eu 3+ Co‐Doped Phosphors for High‐Sensitivity Flexible Optical Fiber Sensing2In Situ Eu Redox in Cs 3 YCl 6 Enabling Colorful Scintillators for Multicolor Radiography and Real‐Time Dosimetry1In Situ Eu Redox in Cs 3 YCl 6 Enabling Colorful Scintillators for Multicolor Radiography and Real‐Time Dosimetry3Excitation‐Dependent Thermal Behavior of a New Type of Phosphors Ba 1‐x Sr 1+x Y 4 O 8 :Ce 3+0Giant luminescence enhancement in Li2MSiO4:Eu2+ (M = Sr, Ba) via two-step synthesis and charge compensation0Site-selective Eu2+ occupation in multi-polyhedral Ca3Al2O6 for tunable high-color-purity blue and red emission0Enhanced Photoluminescence Quantum Efficiency and Thermal Stability of Cyan‐Emitting Li 2 CaSiO 4 :Eu 2+ Phosphor via a Heterovalent Substitution Strategy0An Efficient Blue (Na, Li) 2 Ba 6 Si 4 O 15 :Ce 3+ Phosphor for Near‐Ultraviolet‐Excited White LEDs0

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  2. Effective ratiometric optical thermometry based on inverse temperature dependent dual near infrared emission of Cr3+ doped BaAl4Sb2O12 phosphor

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  3. A Novel Cyan Phosphor (K,Rb) 3 GdSi 2 O 7 :Ce 3+ for Full‐Spectrum Lighting through Local Structure Tailoring

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  4. Moderate Trap Engineering for Enhanced Thermal Stability and High Efficiency in a Bi3+-Doped Phosphor

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  5. Tapping the Light Emitting Potential of Chalcogenide Perovskite SrHfS3 via Eu2+ Doping

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  6. High Output Power and High Quantum Efficiency in Novel NIR Phosphor MgAlGa0.7B0.3O4:Cr3+ with Profound FWHM Variation

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  7. Unveiling the Potential of Sunlight‐Driven Multifunctional Blue Long Persistent Luminescent Materials via Cutting‐Edge Trap Modulation Strategies

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  8. Crystal Field Engineering Yields New 3D Layered Solid Solution Phosphors (Ca/Sr)4MgAl2Si3O14:Eu2+ for White-Light-Emitting Diode Full-Spectrum Lighting

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  14. Multimodal Dynamic Luminescence from Self-Activated Na2CaGe2O6 Phosphor via Defects Manipulation

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  15. Preparation of a novel violet-excitable Na 3 YSi 2 O 7 :Eu 2+ green phosphor via salt-flux assistance and its luminescence properties

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  16. Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting

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  17. BaLiZn 3 (PO 4 ) 3 :Eu 2+ : Ultranarrow-Band Violet Emission in a Highly Symmetric Crystal Structure

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  18. Ba3Lu(BO3)3:Ce3+,Tb3+/Mn2+: Dual-Functional Material for WLEDs and Optical Pressure Sensing

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  19. Broadband Green-Yellow KGaSi2O6:Eu2+ Phosphor with Excellent Thermal Stability for Near Ultraviolet-Pumped White-Light-Emitting Diodes

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  20. Well-Performed Green Phosphor BaY 4 Si 5 O 17 :Ce 3+ ,Tb 3+ with High Quantum Efficiency and Thermal Stability

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  32. Suppressed concentration quenching and tunable photoluminescence in Eu2+-activated Rb3Y(PO4)2 phosphors for full-spectrum lighting

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